• 제목/요약/키워드: hexaferrite

검색결과 48건 처리시간 0.029초

제일원리 계산을 이용한 스트론튬 페라이트의 자기적 특성 전산모사 (First-principles study of the magnetic properties of the strontium hexaferrite $SrFe_{12}O_{19}$)

  • 육영진;정용재;이영진;임종인
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.201-201
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    • 2006
  • 영구자석은 크게 Hard ferrite와 희토류계 자석, 그리고 Alnico 주조자석으로 구별되어진다. 그동안 Hard ferrite는 산업적으로 전자기 응용제품 또는 각종 구동 모터에 응용되어 왔지만, 최근 Nd계 희토류 자것이 고성능 모터의 소재로 급격히 대체되고 있다. 하지만, 희토류계 원료에 비해 동일 중량 대비 40~60배 가량 저렴한 Hard ferrite의 사용은 현재까지도 꾸준히 유지되고 있으며, 최근 자동차 고성능 모터용 Sr ferrite의 개발이 연구 중이다.[2] 본 연구에서는 제일원리 전산모사를 통하여 HCP 구조의 기본 Unit Cell 64개 원자를 가진 Sr-ferrite의 격자상수를 계산하여 기존 연구결과와 비교하였으며, 자화에너지와 자기모멘트를 계산하였다. 또한 향후 각종 첨가물의 영향에 대한 연구를 위해 기본 구조 및 치환 구조에 대해 고찰하였다. 그 결과 가장 안정한 에너지를 갖는 격자상수는 a=5.88, b=23.03으로 계산되어 Kimura et al의 측정 결과와 유사한 결과를 얻을 수 있었으며, $E_F$가 3.9171, $M_B$는 46.6481로 계산되었다. 항후 Sr-ferrite의 구조에서 Fe atom의 일부를 동일주기 원소인 Cr, Mn, Co, Ni, Cu로 치환하여 자기적 특성을 계산하여 본 연구결과와 비교하고자 한다.

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Fabrication and magnetic properties of hexagonal BaFe12O19 ferrite obtained by magnetic-field-assisted hydrothermal process

  • Zhang, Min;Dai, Jianming;Liu, Qiangchun;Li, Qiang;Zi, Zhenfa
    • Current Applied Physics
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    • 제18권11호
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    • pp.1426-1430
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    • 2018
  • High magnetic field effects on the microstructure and magnetic properties of $BaFe_{12}O_{19}$ hexaferrites synthesized hydrothermal method have been investigated. The obtained results indicate that the lattice constant decreases gradually as the magnetic field strength increases, which may be attributed to the lattice distortion resulted from the high magnetic field. Polycrystalline $BaFe_{12}O_{19}$ samples prepared under magnetic field strength at zero and 5 T are single phase. It is found that application of external magnetic field during synthesis can induce orientated growth of the hexaferrite crystals along the easy magnetic axis. The magnetic properties can be effectively regulated by an application of high magnetic fields. It is observed that the $BaFe_{12}O_{19}$ prepared under a 5 T magnetic field exhibits a higher room-temperature saturation magnetization (66.3 emu/g) than that of the sample (43.6 emu/g) obtained without magnetic field. The results can be explained as the enhanced crystalline, improvement of $Fe^{3+}$ ions occupancy and the oriented growth induced by the external magnetic field. The growing orientation of particles gives rise to increased coercivity due to the enhancement in shape anisotropy. It is expected that an application of magnetic field during the formation of magnetic nanoparticles could be a promising technique to modify magnetic properties with excellent performance.

스핀 스프레이 방식으로 제조된 바륨계 페라이트 박막의 EMI (Electromagnetic Interference) 차폐 특성 (EMI (Electromagnetic Interference) Shielding Properties of Barium-Based Ferrite Thin Films Prepared by Spin Spray Method)

  • 오혜령;박연주;이우성;유찬세;유명재;서인태
    • 한국전기전자재료학회논문지
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    • 제37권2호
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    • pp.195-201
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    • 2024
  • The low-temperature deposition of BaNi(2-x)CoxFe16O27 thin films with a Ba hexaferrite structure for electromagnetic shielding was studied. The BaNi(2-x)CoxFe16O27 thin films produced through the spin spray process were suitable for thin film deposition on a flexible substrate because it crystallized well at low temperature below 90℃. The change in shielding characteristics depending on the Co content of the BaNi(2-x)CoxFe16O27 thin film was investigated, and excellent shielding characteristics with S21 of -1 dB were obtained in a wide frequency range of 26~40 GHz when the Co content was 0.4 or more. The purpose of this study is to analyze changes in shielding properties caused by change in Co content in relation to phase changes in BaNi(2-x)CoxFe16O27 and obtain basic data for developing excellent flexible electromagnetic wave shielding materials.

단순화된 분무열분해법을 이용한 Sr-ferrite 제조와 자기특성 (Formulation and Magnetic properties of Sr-ferrite powders by Modified spray co-roasting)

  • 김효준;조태식;남효덕;양충진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.49-52
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    • 1998
  • Preparation of hexagonal strontium-ferrite by modified spray co-roasting(MSC:H) which is expected to shorkn the length of the process and to elevate the magnetic properties of hard ferrite was studied. We prapared $Fe_2O_3/SrCO_3$ mixture powders by MSCR after stirring ionized $FeCI_2$ in distilled water with solid state $SrCO_3$. And then calcined the mixture powders up to $1150^{\circ}C$ for Sr-ferrite powders It is possible to prepare hexaferrite powders with high saturation magnetization (Ms > 69 emu/g) , coercivity (Hc > 4000 Oe) The nlagnetic values of saturation magnetization iire higher than those achieved by the conventional technique.

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Preparation and Magnetic Properties of Ba-Ferrite Particles Using the Supercritical Water Crystallization Method

  • Nam, Sung-Chan;Kim, Kun-Joong;Park, Sang-Do
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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    • pp.433-440
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    • 2000
  • Barium ferrite particles were synthesized from Ba(NO$_3$)$_2$, Fe(NO$_3$)$_3$ and KOH mixed solutions using hydrothermal crystallization in supercritical water. The experimental apparatus for production of barium ferrite is a flow-type apparatus. Fine barium ferrite particles were produced because supercritical water causes the metal hydroxides to be rapidly dehydrated before significant growth takes place. The effects of Fe/Ba ratio and reaction time on the formation, particle size, and magnetic properties of barium ferrite were studied. When Fe/Ba ratio were varied from 0.5 to 12, single-phase barium ferrite powder was only produced in the range of 0.5〈Fe/Ba〈2. Also, with elevating reaction time, the BaO.6Fe$_2$O$_3$ particle size grew smaller. Especially, uniform barium hexaferrite particles of size 100-200nm were obtained at 80sec. In this study, therefore, single-phase barium ferrite particles are highly stable and can be produced continuously in a reaction time of less then 2min.

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