• 제목/요약/키워드: heptofuranose nucleosides

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Synthetic Studies Related to Antibiotics Containing Higher-carbon Sugars

  • Kim, Kwan-Soo
    • 생약학회지
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    • 제16권4호
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    • pp.239-242
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    • 1985
  • The anion of $6-benzenesulfonyl-3-O-benzyl-6-deoxy-1,2-O-isopropylidene-{\alpha}-d-glucofuranose$ was stable and reacted with carbon electrophiles to give higher-carbon sugars. Reactions of uridine 5'-aldehyde with phosphoranes afforded heptofuranose nucleosides.

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Synthetic Studies Related to Ezomycins and Octosyl Acids. Synthesis of Heptofuranose Nucleosides

  • Kim, Kwan-Soo;Kang, Shang-Mo;Kim, Sung- Jung;Jung, Kyu-Seong;Hahn, Chi-Sun
    • Bulletin of the Korean Chemical Society
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    • 제6권6호
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    • pp.350-354
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    • 1985
  • 1-[Ethyl (E)-5,6-dideoxy-2,3-O-isopropylidene-$\beta$-D-ribo-hept-5-enofuranosyluronate] uracil(12) was synthesized. Other various heptofuranose uncleosides were also synthesized from uridine and adenosine by two-carbon chain extension using Witting reaction.