• 제목/요약/키워드: helium gas

검색결과 318건 처리시간 0.037초

Triple-bed Adsorbent Tube를 이용한 가스상 극미량 복합 악취 및 휘발성 유기화합물의 동시 분석 (Simultaneous Analyses for Trace Multi-Odorous and Volatile Organic Compounds in Gas using a Triple-bed Adsorbent Tube)

  • 서용수;이제근
    • Korean Chemical Engineering Research
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    • 제48권2호
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    • pp.244-252
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    • 2010
  • 본 연구에서는 Triple-bed 흡착튜브를 제작하여 열탈착장치와 GC-MS로써 다성분 복합 악취성물질 및 휘발성유기 화합물을 동시분석 가능성을 평가하고자 하였다. Triple-bed 흡착튜브는 하나의 튜브에 Tenax-TA와 소량의 Carbopack B 및 Carbosieve SIII 흡착제를 흡착강도 순으로 3단 배열된 것이다. GC-MS의 분석조건은 mass range 20~350 m/z, 불순물 1 ppm 이하의 헬륨을 운반가스로 하여 저비점 저분자량 물질의 분리동정에 효과적일 수 있도록 하고, 목적이온 추출을 통하여 정량하였다. 그 결과 ppbv 수준의 $C_1{\sim}C_5$의 알콜(4), 알데히드(6), 케톤(2) 그리고 황화합물(2)을 포함한 14종의 물질 모두 99%이상의 회수율과 양호한 재현성 및 직진성으로 동시분석이 가능하였다. 비교적 휘발성이 강하고 분자량이 낮은 물질인 메틸알콜, 아세트알데히드는 상대습도 45% 이하, 흡착유속 50 mL/min, 흡착량 2 L 이하에서 높은 회수율로 보다 안정적으로 정량분석이 가능하였다. 또한 목적이온 추출은 물질피크가 겹쳐 나타난 경우에도 다성분 물질을 각각 정량 가능하였다.

Investigation of thermal hydraulic behavior of the High Temperature Test Facility's lower plenum via large eddy simulation

  • Hyeongi Moon ;Sujong Yoon;Mauricio Tano-Retamale ;Aaron Epiney ;Minseop Song;Jae-Ho Jeong
    • Nuclear Engineering and Technology
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    • 제55권10호
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    • pp.3874-3897
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    • 2023
  • A high-fidelity computational fluid dynamics (CFD) analysis was performed using the Large Eddy Simulation (LES) model for the lower plenum of the High-Temperature Test Facility (HTTF), a ¼ scale test facility of the modular high temperature gas-cooled reactor (MHTGR) managed by Oregon State University. In most next-generation nuclear reactors, thermal stress due to thermal striping is one of the risks to be curiously considered. This is also true for HTGRs, especially since the exhaust helium gas temperature is high. In order to evaluate these risks and performance, organizations in the United States led by the OECD NEA are conducting a thermal hydraulic code benchmark for HTGR, and the test facility used for this benchmark is HTTF. HTTF can perform experiments in both normal and accident situations and provide high-quality experimental data. However, it is difficult to provide sufficient data for benchmarking through experiments, and there is a problem with the reliability of CFD analysis results based on Reynolds-averaged Navier-Stokes to analyze thermal hydraulic behavior without verification. To solve this problem, high-fidelity 3-D CFD analysis was performed using the LES model for HTTF. It was also verified that the LES model can properly simulate this jet mixing phenomenon via a unit cell test that provides experimental information. As a result of CFD analysis, the lower the dependency of the sub-grid scale model, the closer to the actual analysis result. In the case of unit cell test CFD analysis and HTTF CFD analysis, the volume-averaged sub-grid scale model dependency was calculated to be 13.0% and 9.16%, respectively. As a result of HTTF analysis, quantitative data of the fluid inside the HTTF lower plenum was provided in this paper. As a result of qualitative analysis, the temperature was highest at the center of the lower plenum, while the temperature fluctuation was highest near the edge of the lower plenum wall. The power spectral density of temperature was analyzed via fast Fourier transform (FFT) for specific points on the center and side of the lower plenum. FFT results did not reveal specific frequency-dominant temperature fluctuations in the center part. It was confirmed that the temperature power spectral density (PSD) at the top increased from the center to the wake. The vortex was visualized using the well-known scalar Q-criterion, and as a result, the closer to the outlet duct, the greater the influence of the mainstream, so that the inflow jet vortex was dissipated and mixed at the top of the lower plenum. Additionally, FFT analysis was performed on the support structure near the corner of the lower plenum with large temperature fluctuations, and as a result, it was confirmed that the temperature fluctuation of the flow did not have a significant effect near the corner wall. In addition, the vortices generated from the lower plenum to the outlet duct were identified in this paper. It is considered that the quantitative and qualitative results presented in this paper will serve as reference data for the benchmark.

호남지역 저온형 온천수의 수리지화학적 및 안정동위원소 특성과 영족기체의 기원에 관한 연구 (Hydrochemical and Isotopic Characteristics, and Origin of Noble Gas for Low-temperature Hot Spring Waters in the Honam Area)

  • 정찬호;허현성;;김규한
    • 자원환경지질
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    • 제40권5호
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    • pp.635-649
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    • 2007
  • 이 연구에서는 호남지역에 분포하는 5개 온천(죽림, 변산, 지리산, 덕산, 화순)에서 9개 온천시료와 인근의 지하수 시료 3개를 채취하여 수질화학 성분과 안정동위원소 $({\delta}^{18}O,\;{\delta}D,\;{\delta}^{34}S)$ 및 영족기체(He, Ne, Ar) 동위원소 분석을 통하여 온천수의 지화학적 특성, 지화학적 진화, 그리고 황, 헬륨, 아르곤의 기원을 해석하고자 하였다. 호남지역 온천수의 수온은 $23.0{\sim}30.5^{\circ}C$ 범위로 저온형 온천특성을 보이고 pH는 $7.67{\sim}9.98$ 범위로 알카리성의 특성을 보여주었다. 전기전도도는 $153{\sim}746{\mu}S/cm$ 범위로 지역에 따라서 큰 차이를 보여주었다. 온천주변 지하수의 수질특성은 온천수보다 낮은 pH와 전기전도도의 특성을 보여주었다. 온천수와 지하수의 지화학적 성분은 파이퍼도상에서 크게 3개의 유형으로 구분된다($Na-HCO_3$ 유형, Na-Cl 유형, $Ca-HCO_3$ 유형). 온천수의 지화학적 진화과정을 보면 초기에 $Ca-HCO_3$ 유형에서 출발하여 $Ca(Na)-HCO_3$ 유형을 거쳐 $Na-HCO_3$ 유형으로 진화하였으며, 일부 온천수는(JR1)의 경우 pH 9.98의 알카리성으로, $Na-HCO_3$ 유형의 종말점까지 도달하여 지화학적 진화의 최종단계에 도달되었음을 보여준다. 온천수의 산소 및 수소동위원소 조성은 순환수선을 따라 도시되며 지역에 따라 위도효과를 보인다. 황산염에 대한 황동위원소 대부분 화성기원을 보인다. 그러나 JR1 온천은 고염수에서 기원한 것으로 보이는 해양성기원을 보인다. 온천수의 $^3He/^4He$ 비와 $^4He/^{20}Ne$ 비는 $0.0143{\times}10^{-6}{\sim}0.407{\times}10^{-6}$ 범위와 $6.49{\sim}584{\times}10^{-6}$ 범위를 각각 보여주어 대기와 지각성분의 혼합선상에 도시된다. 이는 온천수내 헬륨가스의 대부분이 지각기원임을 의미한다. 죽림온천(JR1)의 경우 맨틀기원의 헬륨가스의 혼합율이 다른 온천에 비해 다소 높은 비율을 보여준다. 이들 동위원소비와 온천수의 pH와는 대체적으로 정의 상관관계가 확인되었다. 아울러 $^{40}Ar/^{36}Ar$비가 $292.3{\times}10^{-6}{\sim}304.1{\times}10^{-6}$ 범위로 대기기원임을 지시한다.

COATED PARTICLE FUEL FOR HIGH TEMPERATURE GAS COOLED REACTORS

  • Verfondern, Karl;Nabielek, Heinz;Kendall, James M.
    • Nuclear Engineering and Technology
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    • 제39권5호
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    • pp.603-616
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    • 2007
  • Roy Huddle, having invented the coated particle in Harwell 1957, stated in the early 1970s that we know now everything about particles and coatings and should be going over to deal with other problems. This was on the occasion of the Dragon fuel performance information meeting London 1973: How wrong a genius be! It took until 1978 that really good particles were made in Germany, then during the Japanese HTTR production in the 1990s and finally the Chinese 2000-2001 campaign for HTR-10. Here, we present a review of history and present status. Today, good fuel is measured by different standards from the seventies: where $9*10^{-4}$ initial free heavy metal fraction was typical for early AVR carbide fuel and $3*10^{-4}$ initial free heavy metal fraction was acceptable for oxide fuel in THTR, we insist on values more than an order of magnitude below this value today. Half a percent of particle failure at the end-of-irradiation, another ancient standard, is not even acceptable today, even for the most severe accidents. While legislation and licensing has not changed, one of the reasons we insist on these improvements is the preference for passive systems rather than active controls of earlier times. After renewed HTGR interest, we are reporting about the start of new or reactivated coated particle work in several parts of the world, considering the aspects of designs/ traditional and new materials, manufacturing technologies/ quality control quality assurance, irradiation and accident performance, modeling and performance predictions, and fuel cycle aspects and spent fuel treatment. In very general terms, the coated particle should be strong, reliable, retentive, and affordable. These properties have to be quantified and will be eventually optimized for a specific application system. Results obtained so far indicate that the same particle can be used for steam cycle applications with $700-750^{\circ}C$ helium coolant gas exit, for gas turbine applications at $850-900^{\circ}C$ and for process heat/hydrogen generation applications with $950^{\circ}C$ outlet temperatures. There is a clear set of standards for modem high quality fuel in terms of low levels of heavy metal contamination, manufacture-induced particle defects during fuel body and fuel element making, irradiation/accident induced particle failures and limits on fission product release from intact particles. While gas-cooled reactor design is still open-ended with blocks for the prismatic and spherical fuel elements for the pebble-bed design, there is near worldwide agreement on high quality fuel: a $500{\mu}m$ diameter $UO_2$ kernel of 10% enrichment is surrounded by a $100{\mu}m$ thick sacrificial buffer layer to be followed by a dense inner pyrocarbon layer, a high quality silicon carbide layer of $35{\mu}m$ thickness and theoretical density and another outer pyrocarbon layer. Good performance has been demonstrated both under operational and under accident conditions, i.e. to 10% FIMA and maximum $1600^{\circ}C$ afterwards. And it is the wide-ranging demonstration experience that makes this particle superior. Recommendations are made for further work: 1. Generation of data for presently manufactured materials, e.g. SiC strength and strength distribution, PyC creep and shrinkage and many more material data sets. 2. Renewed start of irradiation and accident testing of modem coated particle fuel. 3. Analysis of existing and newly created data with a view to demonstrate satisfactory performance at burnups beyond 10% FIMA and complete fission product retention even in accidents that go beyond $1600^{\circ}C$ for a short period of time. This work should proceed at both national and international level.

Modern Paper Quality Control

  • Olavi Komppa
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2000년도 제26회 펄프종이기술 국제세미나
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    • pp.16-23
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    • 2000
  • The increasing functional needs of top-quality printing papers and packaging paperboards, and especially the rapid developments in electronic printing processes and various computer printers during past few years, set new targets and requirements for modern paper quality. Most of these paper grades of today have relatively high filler content, are moderately or heavily calendered , and have many coating layers for the best appearance and performance. In practice, this means that many of the traditional quality assurance methods, mostly designed to measure papers made of pure. native pulp only, can not reliably (or at all) be used to analyze or rank the quality of modern papers. Hence, introduction of new measurement techniques is necessary to assure and further develop the paper quality today and in the future. Paper formation , i.e. small scale (millimeter scale) variation of basis weight, is the most important quality parameter of paper-making due to its influence on practically all the other quality properties of paper. The ideal paper would be completely uniform so that the basis weight of each small point (area) measured would be the same. In practice, of course, this is not possible because there always exists relatively large local variations in paper. However, these small scale basis weight variations are the major reason for many other quality problems, including calender blacking uneven coating result, uneven printing result, etc. The traditionally used visual inspection or optical measurement of the paper does not give us a reliable understanding of the material variations in the paper because in modern paper making process the optical behavior of paper is strongly affected by using e.g. fillers, dye or coating colors. Futhermore, the opacity (optical density) of the paper is changed at different process stages like wet pressing and calendering. The greatest advantage of using beta transmission method to measure paper formation is that it can be very reliably calibrated to measure true basis weight variation of all kinds of paper and board, independently on sample basis weight or paper grade. This gives us the possibility to measure, compare and judge papers made of different raw materials, different color, or even to measure heavily calendered, coated or printed papers. Scientific research of paper physics has shown that the orientation of the top layer (paper surface) fibers of the sheet paly the key role in paper curling and cockling , causing the typical practical problems (paper jam) with modern fax and copy machines, electronic printing , etc. On the other hand, the fiber orientation at the surface and middle layer of the sheet controls the bending stiffness of paperboard . Therefore, a reliable measurement of paper surface fiber orientation gives us a magnificent tool to investigate and predict paper curling and coclking tendency, and provides the necessary information to finetune, the manufacturing process for optimum quality. many papers, especially heavily calendered and coated grades, do resist liquid and gas penetration very much, bing beyond the measurement range of the traditional instruments or resulting invonveniently long measuring time per sample . The increased surface hardness and use of filler minerals and mechanical pulp make a reliable, nonleaking sample contact to the measurement head a challenge of its own. Paper surface coating causes, as expected, a layer which has completely different permeability characteristics compared to the other layer of the sheet. The latest developments in sensor technologies have made it possible to reliably measure gas flow in well controlled conditions, allowing us to investigate the gas penetration of open structures, such as cigarette paper, tissue or sack paper, and in the low permeability range analyze even fully greaseproof papers, silicon papers, heavily coated papers and boards or even detect defects in barrier coatings ! Even nitrogen or helium may be used as the gas, giving us completely new possibilities to rank the products or to find correlation to critical process or converting parameters. All the modern paper machines include many on-line measuring instruments which are used to give the necessary information for automatic process control systems. hence, the reliability of this information obtained from different sensors is vital for good optimizing and process stability. If any of these on-line sensors do not operate perfectly ass planned (having even small measurement error or malfunction ), the process control will set the machine to operate away from the optimum , resulting loss of profit or eventual problems in quality or runnability. To assure optimum operation of the paper machines, a novel quality assurance policy for the on-line measurements has been developed, including control procedures utilizing traceable, accredited standards for the best reliability and performance.

제주도 서귀포지역 천연탄산수의 기원과 수리화학특성 (Origin and Hydrochemical Characteristics of Natural Carbonated Water at Seoqwipo, Jeju Island)

  • 정찬호;이용천;이유진;최현영;고기원;문덕철;정차연;조시범
    • 지질공학
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    • 제26권4호
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    • pp.515-529
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    • 2016
  • 본 연구에서는 제주 서귀포지역에서 산출되는 온천수 2지점과 탄산수 2지점에 대한 화학성분, CFCs (Chlorofluorocarbons) 동위원소, ${\delta}^{18}O$, ${\delta}D$, ${\delta}^{13}C$ 동위원소, 영족기체(He, Ne) 동위원소 분석을 통하여 탄산온천수와 탄산수의 수리화학적 특성, 생성연령, 영족기체의 기원과 $CO_2$ 가스의 기원을 해석하였다. 연구지역의 탄산수의 pH는 6.21~6.84의 범위의 약산성과 매우 높은 전기전도도 값($1,928{\sim}4,720{\mu}S/cm$)의 특성을 보인다. 화학적 유형은 $Mg(Ca,Na)-HCO_3$ 내지는 $Na(Ca,Mg)-HCO_3$ 유형을 보인다. 환경추적자인 CFCs 농도를 이용하여 지하수 연령측정결과, 탄산수는 약 47.5~57.2년, 지하수는 약 30.3~49.5년으로 추정되었다. 탄산수의 ${\delta}^{13}C$값은 -1.77~-7.27‰의 범위를 보여 $CO_2$ 가스의 기원은 심부기원과 일부 심부-무기기원의 혼합 기원으로 도시되었지만, 영족기체 조성비($^3He/^4He$, $^4He/^{20}Ne$)에서 헬륨가스가 심부기원의 농도가 절대적으로 높은 값을 보여 화산활동과 관련한 심부 마그마 기원임을 보여준다.

반복적인 막 추출과 GC-MS를 이용한 물 중 BTEX의 분석 (Solvent-free determination of BTEX in water using repetitive membrane extraction followed by GC-MS)

  • 김희갑;김세영;이수형
    • 분석과학
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    • 제24권5호
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    • pp.352-359
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    • 2011
  • 용매를 사용하지 않고 반복적으로 막 추출한 후 저온농축과 GC-MS로 물 중 BTEX를 분석하는 방법을 시도하였다. 물로부터 비공성막의 silicone 막을 투과한 BTEX를 He 기체를 통해 $-100^{\circ}C$의 저온 농축장치로 보낸 후 열 탈착과 GC-MS로 분석하였다. 물 시료(30 mL)는 10 mL/min로 흘려주었고, 한 번 추출된 시료는 다시 되돌려서 두 번 더 추출하였다. Benzene에 대한 회수율은 가장 높아 약 80%인 반면에, ethylbenzene과 xylenes에 대한 회수율은 3.5-10%로 낮은 편이었다. 그렇지만, RSD는 모두 10% 미만이었고 검량선의 직선성($r^2$)도 0.9976-0.9997로 높은 편이었으며, 방법검출한계도 1.8 ${\mu}g$/L 이었다. 이 방법은 짧은 추출 시간, 용매의 미사용 및 분석의 편의성의 장점을 갖고 있다.

The Characteristics for BNCT facility in Hanaro Reactor

  • Soheigh Suh;Lee, Dong-Han;Ji, Young-Hoon;Lee, Dong-Hoon;Yoo, Seong-Yul;Rhee, Chang-Hun;Rhee, Soo-Yong;Jun, Byung-Jin
    • 한국의학물리학회:학술대회논문집
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    • 한국의학물리학회 2002년도 Proceedings
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    • pp.161-163
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    • 2002
  • The BNCT(Boron Neutron Capture Therapy) facility has been developed in Hanaro(High-flux Advanced Neutron Application Reactor), a research reactor of Korea Atomic Energy Research Institute. A typical tangenial beam port is utilized with this BNCT facility. Thermal neutrons can be penetrated within the limits of the possible maximum instead of being filtered fast neutrons and gamma rays as much as possible using the silicon and bismuth single crystals. In addition to, the liquid nitrogen (LN$_2$) is used to cool down the silicon and bismuth single crystals for the increase of the penetrated thermal neutron flux. Neutron beams for BNCT are shielded using the water shutter. The water shutter was designed and manufactured not to interfere with any other subsystem of Hanaro when the BNCT facility is operated. Also, it is replaced with conventional beam port plug in order to cut off helium gas leakage in the beam port. A circular collimator, composed of $\^$6/Li$_2$CO$_3$ and polyethylene compounds, is installed at the irradiation position. The measured neutron flux with 24 MW reactor power using the Au-198 activation analysis method is 8.3${\times}$10$\^$8/ n/cm$^2$ s at the collimator, exit point of neutron beams. Flatness of neutron beams is proven to ${\pm}$ 6.8% at 97 mm collimator. According to the result of acceptance tests of the water shutter, the filling time of water is about 190 seconds and drainage time of it is about 270 seconds. The radiation leakages in the irradiation room are analyzed to near the background level for neutron and 12 mSv/hr in the maximum for gamma by using BF$_3$ proportional counter and GM counter respectively. Therefore, it is verified that the neutron beams from BNCT facility in Hanaro will be enough to utilize for the purpose of clinical and pre-clinical experiment.

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Synthesis of High Purity Multiwalled and Singlewalled Carbon Nanotubes by Arc-discharge

  • Kim, Keun-Soo;Park, Young-Soo;An, Kay-Hyeok;Jeong, Hee-Jin;Kim, Won-Seok;Choi, Young-Chul;Lee, Seung-Mi;Moon, Jeong-Mi;Chung, Dong-Chul;Bae, Dong-Jae;Lim, Seong-Chu;Lee, Young-Seak;Lee, Young-Hee
    • Carbon letters
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    • 제1권2호
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    • pp.53-59
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    • 2000
  • The synthetic methods for high yield of multiwalled carbon nanotube (MWNT) and singlewalled carbon nanotube (SWNT) with high purity by arc discharge have been investigated. MWNTs were synthesized under different pressures of helium and the gas mixture of argon and hydrogen. Relatively high pressure of 300-400 torr was required for high yield MWNTs synthesis at low bias voltage of about 20 V and 55 A, whereas low pressure of about 100 torr was required for SWNTs. The introduction of hydrogen gases during the synthesis of MWNTs improved the yield and purity of the samples. The SWNTs were synthesized by the assistance of a small amount of mixture of transition metals, which played as a catalyst during the formation process. The purity and yield of SWNTs were higher at a lower pressure and enhanced by mixing more components of the transition metals.

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저열유속에서 상변화를 수반하는 메탄의 유동거동특성 (The Flow Behavior Characteristics of Methane with Phase Change at Low Heat Flux)

  • 최부홍
    • 해양환경안전학회지
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    • 제20권1호
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    • pp.96-103
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    • 2014
  • 극저온 액체 상태의 LNG는 주거용과 산업용으로 공급되기 전에 가스 상태로 변환된다. 이러한 재가스화 과정 중에 LNG는 $83.7{\times}10^4$ kJ/kg 정도의 많은 냉열에너지를 제공한다. 이 냉열에너지를 일부 선진국들에서는 질소, 수소, 헬륨과 같은 극저온 유체들의 액화, 제빙 및 냉방시스템에 이용하고 있다. 따라서 우리나라에서도 인천, 평택 및 통영 LNG 인수기지 주변에 LNG의 냉열에너지를 이용한 냉열에너지 회수시스템을 설립할 필요가 있다. 여기서는 저열유속상태에서 상변화를 동반하는 LNG의 유동거동 특성을 파악하기 위해 LNG의 85 %를 차지하는 메탄을 작동유체로 사용하였다. 또한 본 논문은 극저온 열교환기 내부를 흐르는 메탄과 질소, 프로판, R11 및 R134a의 유동경계에 영향을 주는 관 직경, 관의 경사각도 및 포화압력의 효과를 보여준다. 또한 여기서 얻어진 이론적 연구결과와 기존의 실험 데이터와도 비교 되었다. 그리고 메탄의 유동경계에 주는 파이프의 경사각도의 영향은 매우 큼을 알 수 있었다.