• 제목/요약/키워드: heavy-metal

검색결과 3,485건 처리시간 0.035초

Engineering Characteristics of CLSM with Regard to the Particle Size of Bottom Ash (저회의 입도변화에 따른 CLSM의 공학적특성)

  • Lee, Yongsoo;Kim, Taeyeon;Lee, Bongjik
    • Journal of the Korean GEO-environmental Society
    • /
    • 제21권10호
    • /
    • pp.5-10
    • /
    • 2020
  • As the demand for the recycling of industrial by-products increases due to various environmental restrictions including the prohibition of ocean disposal, various studies regarding the recycling of industrial by-products are currently being carried out. One of the industrial by-product, coal ash is produced from thermal power generation; studies on the recycling of fly ash have been actively carried out and it is currently recycled in various fields. In the case of bottom ash, however, only a portion of the total amount generated is primarily processed into a particle size of 2~4mm or less than 2mm to be used for gardening purpose and light weight aggregate and so on. The remaining amount is buried at ash disposal sites. Therefore, various studies are needed to develop measures to use bottom ash. This study aimed at identifying the optimal particle size and mixing ratio of bottom ash to be used as CLSM aggregate. To this end, it evaluated the usability of bottom ash as CLSM aggregate, by investigating the flowability and strength change characteristics of CLSM produced with regard to the mixing ratio of weathered granite soil and bottom ash, particle size of bottom ash to be mixed and soil binder addition rate and conducting a heavy metal leaching test.

Analysis of Heavy Metal Element and Microorganism by Manufacture of Particulate Matter Sampler for Science Project of Secondary School (중등학교에서 사용 가능한 미세먼지 포집 장치 제작을 통한 대기 중 중금속 및 미생물 분석)

  • Kwon, Woo-Jin;Kim, Young-Jae;Byeon, Jung-Ho
    • Journal of the Korean earth science society
    • /
    • 제36권1호
    • /
    • pp.125-135
    • /
    • 2015
  • The purpose of this study were to sample particulate matter and analyze its elements and microorganisms for secondary school science project. The particulate matter was sampled on the rooftop a four-store building at a university in Chungju province. A simplified capturing system was developed with the parts, motor-pump, innet, $1.0{\mu}m$ teflon filter, filter-holder, etc. Using the system, this study had sampled particulate matter during Dec., 2013-Jun., 2014. Then, this study analyzed the elements and microorganisms of the sampled particulate matter. Results have been shown that the particulate matter derived China urban area is mainly consisted of the artificial pollutant, such as Cu, Zn, Cd, Ni, Pb. In addition, this study has been shown that microorganisms, such as bacteria and fungi, are included in the particulate matter. Therefore, this study suggests a new systemic investigation and monitoring about the particulate matter, specially originated from China. Also, this study provides a sample for secondary school science experiment.

Correlation between Hair Mercury Concentration and Blood Total Mercury in Several Area Residents (일부 지역 주민들의 모발 수은 농도와 혈중 수은 농도와의 상관성)

  • Kim, Gyeong-Yeon;Seo, Jeong-Wook;Kim, Byoung-Gwon;Kim, Yu-Mi;Kim, Rock-Bum;Kim, Dae-Seon;Kim, Jung-Man;Kim, Choon-Jin;Hong, Young-Seoub
    • Journal of Environmental Health Sciences
    • /
    • 제39권2호
    • /
    • pp.117-129
    • /
    • 2013
  • Background: This study was carried out for the purpose of comprehensively evaluating the mercury exposure level of residents in several areas and the correlation between hair mercury concentration and blood mercury concentration. Method: One thousand one hundred ninety seven subjects were sampled from 30 sites using random assignment sampling. We performed a questionnaire survey and measured the level of total mercury in hair and blood samples from all subjects. Results: The geometric mean concentrations of hair and blood mercury in all subjects were 1.27 mg/kg [95% confidence interval (CI): 1.23-1.32 mg/kg] and 5.24 ${\mu}g/L$ [95% CI: 5.07-5.41 ${\mu}g/L$], respectively. Male (1.56 mg/kg in hair, 6.00 ${\mu}g/L$ in blood) was significantly higher than that of female (1.03 mg/kg in hair, 4.56 ${\mu}g/L$ in blood), and the concentrations were elevated as age increased up to the 50s. Education, smoking, alcohol drinking, and using of pesticides were also shown to influence mercury concentrations in hair and blood. The ratio of hair/ blood mercury concentration was 261.3. The total mercury concentration in hair was identified to be significantly related with total mercury concentration in blood (r=0.814, p<0.001). Conclusion: The geometric mean concentrations of hair and blood mercury were higher than the levels provided in international recommendations. The total mercury concentration in hair was positively correlated with the concentration in blood. The results of this study suggest that hair mercury be considered as a useful tool for the evaluation of mercury exposure.

Physiological Activity and Effects on Lipid Peroxidation of Hot Water-Extract Obtained from Euonymus alatus in Cultured Rat Hepatocyte (Rat의 hepatocyte에서 $amyloid-{\beta$}$로 유발된 세포사, 지질과산화 및 세포산화에 대한 귀전우 열수 추출물의 보호효과)

  • Soo-Sung, Kim;Jong-Dae, Kim
    • The Journal of Korean Medicine
    • /
    • 제22권2호
    • /
    • pp.53-63
    • /
    • 2001
  • This study was carried out to investigate the physiological activityof the water extract from EA. The present study was done to investigate the effects of EA on cultured hepatocyte cell system and lipid peroxidation in $A{\beta}$ treatment conditions. Pretreatment of EA attenuated in cell cytotoxicity enhanced by increasing concentrations of $A{\beta}$. MDA level induced by $A{\beta}$ treatment was significantly increased and the level was slightly reduced by pretreatment of EA. The ability of EA to reduce cell death and MDA level induced by $A{\beta}$ suggest that EA may be a protective agent against free radical generating compounds such as $A{\beta}$. EA exhibited anti oxidative activity at all concentration tested.The extract was as good as antioxidative activity of the synthetic antioxidants, butylated hydroxy toluene and ascorbic acid. Furthermore, this was superior to that of natural antioxidant, a-tocopherol. In the presence of heavy metal ions ($Fe^{2+},{\;}Zn^{2+}$), EA showed strong antioxidative activity. The extracts showed about 3075% in the nitrite scavenging effect under pH 1.2 and $37^{\circ}C$ for 1 hr. There was significant difference among concentration of extracts.

  • PDF

Preparation of Acrylic Acid Grafted Polypropylene by Electron Beam Irradiation and Heavy Metal Ion Adsorption Property (전자선 조사를 이용한 아크릴산이 그라프트된 폴리프로필렌의 제조 및 중금속 이온 흡착 특성)

  • Cheon, Ja young;Jeun, Joon-pyo
    • Composites Research
    • /
    • 제32권6호
    • /
    • pp.335-341
    • /
    • 2019
  • In this study, an acrylic acid (AAc) was grafted on a polypropylene (PP) nonwoven fabric using electron beam irradiation. Electron beam grafting was carried out under various conditions to produce AAc grafted PP (PP-g-AAc) nonwoven fabric having a grafting yield of about 50% at radiation dose of 100 kGy and a monomer concentration of 60%. The physical and chemical properties of PP-g-AAc nonwoven fabric were evaluated by SEM, ATR-FTIR, thermal analysis and tensile strength. The morphology of PP and PP-g-AAc nonwoven fabric confirmed by SEM showed no significant change, and it was judged that AAc was introduced into PP nonwoven fabric from ATR-FTIR. PP-g-AAc nonwoven fabric showed an increase in tensile strength and a decrease in tensile strain compared to PP nonwoven fabric. However, since change of value is not significant, it is considered that there is no significant influence on the physical characterization. Adsorption experiments of PP-g-AAc nonwoven fabric on various ions showed selective adsorption behavior for lead ion. In conclusion, the electron beam radiation-induced PP-g-AAc nonwoven fabric is expected to be applied as an effective adsorbent for the adsorption of lead ions.

Effect of Turbid Water on Fishes in the Streams of Imha Reservoir (임하호 유입지천에 서식하는 어류에 미치는 탁수의 영향)

  • Yu, Sam-Hwan;Kim, Jeong-Sook;Shin, Myung-Ja;Lee, Jong-Eun;Seo, Eul-Won
    • Journal of Life Science
    • /
    • 제19권10호
    • /
    • pp.1410-1416
    • /
    • 2009
  • The present study aims to examine the effect of turbid water on fishes in streams which branch into a turbid water area (Yeongyang-gun) and a non-turbid water area (Cheongsong-gun), and finally flow into the Imha reservoir. In a comparison of water quality, the chemical status of the water showed higher pH, DO and SS in the turbid water area than in the non-turbid water area. Also, high density of clay minerals such as vermiculite (V) and illite (I), which is from clay mineral leakage during rainfall, was detected in turbid water, resulting in an increase of turbidity. Fishes inhabiting the turbid water showed irregular spaces in gill lamella, cell separation, edema, and clubbing in epithelial tissues. Also, the gill surface showed roughness and plenty of muddy debris substances inside the gills. The Bowman's space was expanded because of contraction of the glomerulus in the Bowman's space of the kidney tissues. Antioxidant enzymes such as SOD, CAT, GPX, and GST showed higher activities in the specific tissues, muscles and kidney, of fishes living in turbid water than in the non-turbid area. We suggested that; first, the antioxidant activities were increased due to removal of harmful radicals generated in fish bodies in the turbid water area, second, long-time exposure of these histological changes in the tissues might have induced secondary lesion accompanying the inaccurate physiological constancy of fishes.

Cellular Immune Responses of the Manila Clam, Ruditapes philippinarum, Exposed to Cadmium Chloride (카드뮴에 노출된 바지락 (Ruditapes philippinarum) 의 세포성 면역 반응)

  • Park, Kyung-Il;Choi, Min-Soon;Park, Sung-Woo;Park, Kwan-Ha;Choi, Sang-Hoon;Yoon, Jong-Man
    • The Korean Journal of Malacology
    • /
    • 제25권2호
    • /
    • pp.135-143
    • /
    • 2009
  • The Manila clam, Ruditapes philippinarum, has been considered as a sentinel species due to dominant distribution along the coast of Korea and well developed regulatory system. In order to develop and understand immune responses of the Manila clams, clams were exposed to $50\;{\mu}g/L$ of cadmium chloride (Cd) for 8 days and monitored the cellular immune parameters of the hemocytes including blast cell composition, DNA damage, necrosis, apoptosis and hemocyte mortality using a flow cytometer. The results showed that all immune parameters analyzed in the present study increased remarkably compared to the controls and the increases were statistically significant. Apoptosis rate was higher than necrosis rate in the clams exposed to Cd suggesting that apoptosis was preferably induced by the concentration of Cd used in the present study. Our study indicates that the measurement of cellular immune responses of the Manila clam using flow cytometer will be a useful technique for assessment of heavy metal contamination in marine environment.

  • PDF

Fish Farm Performance of Copper-alloy Net Cage: Biological Safety of Red Sea Bream Pagrus major Rearing the Copper-alloy Net Cage (동합금가두리망에서 사육한 참돔, Pagrus major의 생물학적 안전성)

  • Shin, Yun Kyung;Kim, Won-Jin;Jun, Je-Cheon;Cha, Bong-Jin;Kim, Myoung-Sug;Park, Jung Jun
    • Korean Journal of Ichthyology
    • /
    • 제29권1호
    • /
    • pp.41-51
    • /
    • 2017
  • To understand the application in farm for the fish aquaculture, we investigated biological and pathological traits on red sea bream Pagrus major which were reared in each copper-alloy net cage and the synthetic fiber net cage for 9 months. Two groups of cage were made and set in Yokji-eup, Tongyoung, Gyeongsangnam-do in size of 25 m in diameter and 10 m of depth. Survival rate of the red sea bream in the rearing copper-alloy net cage and synthetic fiber cage showed 99.75% and 99.70% respectively, there was no significant difference. Daily weight growth rate in each net was shown to 2.13 g/day and 1.65 g/day. Health analysis by blood composition analysis showed a favorable result in the copper-alloy net cage rather than in the synthetic fiber net. Bioaccumulation of heavy metal such as Cu and Zn especially in gonad was higher than other organ. Bioaccumulation of Cu and Zn in the muscle was lower compared to the permitted standard for food safety. Pathogenic infection test discovered Microcotyle tai for parasite, V. alginolyticus and other five species for bacteria. But there was a little bit difference of bacteria infection in copper-alloy net cage and copper-alloy net cage is expected to be has antibacterial effect. Thus, copper-alloy net cage can be applied to farm considering its system stability, recycling, antibiosis and food safety.

Characteristics on Chemical Activation and VOCs Adsorption of Activated Carbon according to Mixing Ratio of Anthracite and Lignite (활성탄 제조시 유·무연탄 혼합에 따른 화학적 활성화 및 휘발성유기화합물 흡착 특성)

  • Cho, Joon-Hyung;Kang, Sung-Kyu;Kang, Min-Kyoung;Cho, Kuk;Oh, Kwang-Joong
    • Clean Technology
    • /
    • 제23권4호
    • /
    • pp.364-377
    • /
    • 2017
  • In this study, to improve the low surface area of domestic anthracite as raw materials of activated carbon, characteristics on chemical activation and VOCs adsorption of activated carbon according to mixing ratio of anthracite and lignite. For these, properties of raw materials, parameter characteristics of preparation processes for activated carbon, and VOCs adsorption characteristic of the prepared activated carbon are analyzed. The experimental results showed that, the domestic anthracite had disadvantages of high contents for ash and lead, arsenic, which were exceeded for the heavy metal limits, in the properties of raw materials. To improve these diadvantages, using the mixing ratio of anthracite and lignite, and the optimum conditions for pretreatment, activation, washing, and pellitization process, the activated carbon had a range of BET (Brunauer-Emmett-Teller) surface area of $1,154{\sim}1,420m^2g^{-1}$ with mesopore development and hydrophobic surface property. The carbons were satisfied with the quality standard for granular activated carbon, and had similar physicochemical properties with the commercial activated carbon. The minimum mixing condition for commercial VOCs activated carbon performance must have the caloric value of above $5,640kcal\;kg^{-1}$, and the carbon had higher adsorption capacity with order of xylene > toluene > benzene according to more higher molcular weight and hydrophobic property.

Optimum Extraction Conditions of Gelatin from Fish Skins and Its Physical Properties (어피젤라틴의 최적 추출조건 및 그 물성)

  • Kim, Se-Kwon;Byun, Hee-Guk;Lee, Eung-Ho
    • Applied Chemistry for Engineering
    • /
    • 제5권3호
    • /
    • pp.547-559
    • /
    • 1994
  • To effectively utilize fish skin wastes from marine manufactory, the optimal extraction conditions to prepare gelatin from fish skins of Alaska pollack, cod and yellowfin sole were investigated. In addition, the physical properties of the fish skin gelatins prepared under the optimal extraction conditions were compared with the commercial animal skin gelatin. The conditions for extraction of gelatins from fish skins were as follows ; The skins were limed with 1.0~1.5%(w/v) calcium hydroxide solution. The fish skin gelatins were extracted with 6~7 volumes of water(pH 6.0~7.0) for 5hrs at $40{\sim}50^{\circ}C$, and the yield of Alaska pollack skin gelatin extracted under the above conditions was higher than those of cod and yellowfin sole skins. The heavy metal contents, jelly strength and electric conductivities of fish skin gelatins were lower than those of a commercial gelatin(bovine skin), but the viscosity and isoelectric point were higher. The amount of amino acid in fish skin, such as gelatin, glutamic acid, serine, threonine, methionine and cysteine, were higher than those in pig and ox skin. However, the contents of hydroxyproline and proline were lower.

  • PDF