• 공업화학
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• 제19권1호
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• pp.98-104
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• 2008

본 연구는 광미오염토양을 대상으로 입자크기에 따른 토양세척기술의 중금속 추출특성 평가와 토양세척 전과 후의 화학적 분포형태를 파악하고자 실시되었다. 오염토양의 입자크기 별 총 농도는 모든 중금속에서 입자가 작을수록 증가하는 경향을 보였지만, Fe과 Mn은 입자크기와는 무관하였다. 0.05 M EDTA를 이용한 토양세척(Soil washing)에 의한 중금속 추출은 모든 중금속에서 추출 6 h 내에 준평형상태에 도달하였다. 추출효율은 입자크기가 작을수록 Pb, Cu, Zn의 일부에서 추출효율이 감소하였지만, Cd에서는 추출효율의 차이가 크지 않았다. Cd의 추출효율이 86~91%로 가장 높은 반면에 Fe이 5~14%로 가장 적었다. 화학적 분포형태는 토양세척 이전 모든 중금속에서 거의 대부분이 환원성, 산화성, 잔류성으로 존재하였으며 특히, Pb과 Cu는 입자가 작을수록 잔류성 형태도 증가하였다. 그러나, 0.05 M EDTA에 의한 토양세척 이후에는 Cu를 제외하고 Pb, Zn, Cd에서 상당부분이 환원성(Fe/Mn산화물)과 잔류성으로 존재하였고, Cu는 주로 산화성과 잔류성으로 존재하였다. 특히, Pb과 Cu는 입자가 작을수록 잔류성 형태도 증가하였다. 또한, Pb, Zn, Cd에서 환원성형태의 화합물이 0.05 M EDTA에 의해 거의 90% 이상이 제거되었다. 본 연구결과 광미오염토양의 중금속 분포형태 및 추출효율은 많은 인자들 외에 광물학적 요인과 함께 토양입자크기에 좌우되는 주요인자임이 확인되었다.

• 한국분말재료학회지
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• 제26권3호
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• pp.201-207
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• 2019

Tungsten heavy alloys (W-Ni-Fe) play an important role in various industries because of their excellent mechanical properties, such as the excellent hardness of tungsten, low thermal expansion, corrosion resistance of nickel, and ductility of iron. In tungsten heavy alloys, tungsten nanoparticles allow the relatively low-temperature molding of high-melting-point tungsten and can improve densification. In this study, to improve the densification of tungsten heavy alloy, nanoparticles are manufactured by ultrasonic milling of metal oxide. The physical properties of the metal oxide and the solvent viscosity are selected as the main parameters. When the density is low and the Mohs hardness is high, the particle size distribution is relatively high. When the density is high and the Mohs hardness is low, the particle size distribution is relatively low. Additionally, the average particle size tends to decrease with increasing viscosity. Metal oxides prepared by ultrasonic milling in high-viscosity solvent show an average particle size of less than 300 nm based on the dynamic light scattering and scanning electron microscopy analysis. The effects of the physical properties of the metal oxide and the solvent viscosity on the pulverization are analyzed experimentally.

• 환경위생공학
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• 제14권3호
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• pp.71-79
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• 1999

The Hg, Cd, Cu, Mn, and Zn in bottom sediments of han river and their tributaries were analyzed to evaluate the seasonal variations of heavy metals. Leaching tests were also performed for estimation of availability of heavy metal retention in sediments. Sediments of Anyang stream showed the highest concentration of heavy metal in the sediment samples. Heavy metal concentration was heavily depended upon the heavy metal source of tributaries of han river and particle distribution. Clay and silt had higher concentration of heavy metals than very fine san and fine sand due to difference of retention capability of heavy metal. The highest concentration of heavy metal was observed in bottom sediments irrespective of sites investigated. Heavy metals and ignition loss showed positive relations, and higher relationships with p-value <0.01 were observed between copper and lead. copper and zinc, and depended on the pH condition of leaching test, and leachated fraction increased with decrease of the pH.

• 한국식품영양학회지
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• 제9권3호
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• pp.299-306
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• 1996

The study was performed under the various conditions, such as the edible parts and particle sizes of Allium. The concentrations, the temperartures, and the pH of heavy metal solutions to investigated their adsorption capacity of heavy metals by genus Allium. The adsorption amount of Pb by Allium in the aqueous soluton was apparently higher than that of Ni and Cu by them. The larger the particle sloe of welsh onion and shallot was, the higher the adsorption of Cu was. The adsorptlons of Cu, Ni and sorption ratio was not different. As the temperature increased, the amount of heavy metal adsorption increased in general, but the adsorption of Ni by welsh onion and wild garlic and leek, Cu by shallot, wild garlic and leek decreased. Adsorption of Pb to Allium was not affected by the different values of pH, and adsorptions of Ni and Cu were greatly affected by those of pH. Especially, the higher the pH was, the greater the Ni adsorption to Allium was, and the lower the pH was, the higher the Cu adsorption was. The correlation between the amount of components in edible parts of Allium and that of adsorption of heavy metals was significantly high In amino acids containing sulfhydryl group(-SH) and vitamin B2.

• 대한기계학회논문집
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• 제15권1호
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• pp.241-251
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• 1991

본 연구에서는 이런 점들을 고려, 난류유동장 내의 실제 입자운동을 좀더 사 실에 가깝도록 해석할 수 있는 모델을 제시하여 아직 실험에 의존하고 있는 관계분야 에 그 이론적 응용범위를 넓히는데 그 목적을 두었따. 본 연구의 목적상 입자가 존 재하는 난류장의 통계적 특성은 이미 알고 있는 것으로 가장하였으며 유체 내의 입자 농도가 충분히 낮고 입자의 크기가 충분히 작아서 입자가 유동장에 미치는 영향은 무 시할 수 있다고 간주하였다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2554-2557
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• 2008

Effect of a particle's spin is investigated numerically by considering the effect of lift occurring due to difference of rotations of a particle and of fluid such as the Saffman lift and Magnus force. These lift forces have been neglected in many previous works on particle-laden turbulence. The trajectory of particles can be changed by the lift forces, resulting in significant modification of the stochastic characteristics of heavy particles. Probability density functions and autocorrelations are examined of velocity, acceleration of solid particle and acceleration of fluid at the position of solid particle. Changes in velocity statistics are negligible but statistics related with acceleration are a little bit changed by particle's rotation. When a laden particle encounters with coherent structures during the motion, the particle's rotation might significantly affects the motion due to intermittently large fluid acceleration near coherent structures.

• 환경분석과 독성보건
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• 제21권4호
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• pp.292-303
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• 2018

The particle sizes and heavy metal concentrations (Pb, Zn, Cu, Cd, Hg, As, Cr, Ni, Li, Al) of surface sediments of the Yeongsan River were analyzed to assess the distribution and pollution level of heavy metals. The distribution of particle sizes was dominated by sand in the upstream sites (MS1-MS7) and by silt loam in the downstream sites (MS8-ML3), but MS3 and MS6, located slightly upstream of the two weirs, were found to be loamy sand and silt loam, respectively. The concentrations of Pb, Zn, Cu, Cd and Hg were higher at the upstream sites, while As, Cr, Ni and Li were higher at the downstream sites. The heavy metals of crustal origin (As, Cr, Ni and Li) were strongly correlated with particle size, while the other heavy metals (Pb, Zn, Cu, Cd and Hg) were weakly correlated with particle size. Considering their concentrations, most of heavy metals were evaluated as having almost no toxic effects on benthic organisms, at all sites. In addition, anthropogenic contamination by the $I_{geo}$, EF and CF were found to have no impact at most sites, with only low levels of pollution at the others. Using the PLI method, the MS2 and MS3 sites, located upstream, were assessed to be affected by anthropogenic contamination. Most importantly, Zn, Cu and Hg were found to be the elements responsible for most pollution, and they were highest at the upstream sites, implying pollution by domestic sewage and urban discharge.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 하계학술대회 논문집 C
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• pp.1649-1651
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• 2001

The effect of ribbed spacers having metallic particle attached to the post-type spacer on dielectric breakdown phenomena has been investigated using electric field analysis for imaginary streamer process and a breakdown experiment. It was described that the electric field analysis and the dielectric breakdown test were performed on the case that the particle was attached to the various position of the ribbed spacer having various shapes. As a result, the breakdown voltage of the spacer with two ribs was highest, and it was varied by the length and the thickness of the rib. Especially, in case of the rib with round edge, the breakdown voltage was higher than that with rectangular edge, which complied with the result through the field analysis.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.664-667
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• 2001

Segregation of binary particle systems in a horizontally gyrated bed has been experimentally studied to recover the heavy metals from municipal waste incineration (MWI) ash. Differences in density and size had less effect on segregation. Effective segregation took place under the centrifugal effect of 1 or less for any particle size ratio. Zn, Cu and Pb were concentrated in the upper side of bed by the horizontal vibration. However, there was less change in concentration for other metals such as Mg, Al and Fe etc. The separation system with the horizontal gyrating separator proved to be an effective method for the pretreatment of recovering Zn, Cu and Pb from incineration residues.

• Journal of Magnetics
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• 제11권3호
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• pp.103-107
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• 2006

In grain oriented electrical steel process, hot band annealing has thought to be essential for obtaining good magnetic properties. New hot rolling method of heavy reduction in early hot rolling stage was applied to obtain good magnetic properties in GO process without hot band annealing. Hot rolling was carried out by varyinghot rolling reduction distribution along hot rolling pass. The heavy hot rolling reduction in rear stand improves the magnetic flux density in the case of no hot band annealing. The hot band specimens of the heavy reduction in front stand shows the elongated hot deformed microstructures in the center layer and strong {001}<110> texture.On the contrary, the heavily reduced specimens in rear stand shows the recrystallization in the center layer of hot band and strong {111}<112> and {110}<001> textures.