• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.3
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• pp.56-64
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• 2019

Various approaches have been attempted to develop recycling technologies related to industrial waste resources containing metals. Among them, glass is not decomposed into microorganisms, so landfill is not suitable, and interest in the recycling of waste glass is increasing. In this paper, by incorporating chelate resin to suppress the elution of heavy metals in waste glass and using waste glass as a fine aggregate and we want to evaluate the strength, drying shrinkage, alkali-silica reaction and heavy metal leaching of shielded filler materials and to provide basic data for utilizing waste glass as an economical and environmentally friendly shielding filler. As a result of the test, it was found that the use of waste glass as a fine aggregate was effective in the development of strength, but the incorporation of chelate resin had an influence on the strength development. In addition, the addition of chelate resin was effective in improving drying shrinkage but it was found to affect the alkali - silica reaction. As a result of the heavy metal leaching test, the KSLP test method satisfies all the criteria for heavy metal leaching. However, in case of lead, the limit of US ANSI 67-2007a was exceeded and further study should be done.

• Journal of the Korean Chemical Society
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• v.44 no.6
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• pp.547-555
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• 2000

The surface water in the upstream and midstream of Nakdong river, which is being used as tap water and industrial water supply in Daegu city and Kyungpook province, was analyzed in its water quality. In addition, the sediments of which was analyzed in terms of heavy metal and organic substance contents. All the sampling was done in the drought season for 2 days of June 22-23 and carried out in 10 sampling sites. The sites cover the whole Kyungpook provincial region, starting from Yangsam Bridge in Chyeong Ryang Provincial Park as the upper end, to the Ko Ryung Bridge as the lower end sampling site of Nakdong river that flows through Kyungpook province. The 22 items including $NH^{+}_{4}$, $NO^{-}_{2}$ and COD were analyzed for surface water and 11 items including organic constituents(trichloroethylene, etc) and heavy metals were analyzed for sediments. The sediments samples were analyzed by elution testing method and acid dissolution method and then the results were compared with each other. All heavy metals in samples were determined by Inductively Coupled Plasma-Atomic Emission Spectroscopy(ICP-AES) and other constituents were analyzed by standard testing methods of the Korean Ministry of Environment.

• 한국해양학회지
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• v.10 no.1
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• pp.33-40
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• 1975

The ion exchange sorption and elution behavior of toxic heavy metal ions, such as Hg(II) and Zn(II), have been studied in aqueous and methanolic media of MCl (M: K, Na and NH$\_$4/). The ion exchange resins studied are Dowex 1-X8, Cl$\^$-/ (50-100 or 200-400 mesh) and Dowex 50W-X8, M$\^$+/ form (M: K, Na, NH$\_$4/ and H). the sorption and elution of metal ion on the resin is largely due to the formation of the anionic chlororocomplex of metal ion. The addition of methanol in the medium contributes markedly to the distribution data. In order to apply this work for the treatment of polluted sea water with toxic heavy metal ions, removal experiment of the metal ions from the synthetic sample solution was investigated.

• Journal of Soil and Groundwater Environment
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• v.24 no.6
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• pp.1-8
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• 2019

This study evaluated the relative extraction ratio (RER) of As and heavy metals (Cd, Cu and Pb) in paddy soils using the two types extractant, 0.05 M EDTA and 0.43 M HNO₃. The RER was calculated by dividing the concentrations of metals obtained by 0.05 M EDTA or 0.43 M HNO₃ extraction by those obtained by aqua regia extraction. The RER of 0.43 M HNO₃ was larger than that of 0.05 M EDTA. Correlation analysis indicated there was statistically significant correlation (p<0.001) between the concentration in aqua regia and 0.05 M EDTA or 0.43 M HNO₃. Especially, Cd showed the higher correlation than other metals. Stepwise multiple linear regression analyses indicated soil pH, CEC, organic matter content, and soil texture all influenced the metal extraction rates and bioavailability of the metals.

• Korean Journal of Environmental Agriculture
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• v.25 no.4
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• pp.316-322
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• 2006

Objective of this research was to assess the release characteristics of metals from the mine tailing to base the prediction of metal load potential from tailing to soils. Water-soluble concentrations of Cd, Cu, Pb and Zn released from mine tailing after 2 hrs were 2.31, 129.38, 17.17, and 287.53 mg/kg, respectively, as compared to 1.6, 128, 108, and 142 mg/kg that were extractable by 0.1 M HCl. Kinetics of metal releases followed the power function model significantly indicating that more of water soluble fractions of those metals released at the initial short time, followed by a slow increase. Concentrations of metals released from tailing by water and 0.1 M HCl were in the orders of Zn > Cu > Pb > Cd. The breakthrough curve from the column experiment showed that concentrations of Cd, Cu, and Zn reached at highest after one pore volume, but that of Pb reached highest after five pore volumes when 0.1 M HCl was used as eluent. The release rate of Cd from mine tailing was the fastest but Pb was the slowest. The cumulative mass of metal released by 0.1 M HCl was in the order of Zn > Cu > Pb > Cd after nine pore volume elution.

• Journal of Environmental Science International
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• v.1 no.2
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• pp.157-166
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• 1992

The biosorptlon perFormances of copper were Investigated by the immobilized biomass of nonliving marine brown algae Undaria pinnatifida by each of the Ca-alginate method(Ca-ALG), Ba-alginate method(Ba-ALG), polyethylene glycol method(PEG), and carrageenan method (CARR). The copper removal performance increased but the copper uptake decreased as the biomass amount was increased. However, the copper uptake by the immobilized biomass increased with increasing initial copper concentration. Among the immobilization methods, the copper uptake decreased in the following sequence: Ca-ALG > Ba-ALG > PEG > CARR. The pattern of copper uptake by the immobilized biomass fitted the Langmuir isotherm better than the Freundlich isotherm. Desorption of deposited copper with 0.05 ~0.5M HCI, resulted in no changes of the copper uptake capacity of the immobilized biomass by the immobilization methods except for PEG, through five subsequent biosorptioydesorption cycles. There was no damage to the immobilized biomass which retained its macroscopic appearance in repeated copper uptake/elution cycles.

• Analytical Science and Technology
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• v.21 no.4
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• pp.279-283
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• 2008

Blood soil and the mixture of blood soil, elvan soil and, silica soil materials were molded, then they were sintered in $1100^{\circ}C$ and were used for the emission of the far infrared ray boll. The emission from the manufactured bolls was relatively high in the range of $8{\sim}12{\mu}m$ wavelength each. The elution of minerals from mixture bolls was very low, but the elimination of heavy metal cadmium ion in activated water and energy water treated with mixture bolls was very high. Activated water and energy water had a high to the UV protected ability in comparison to drinking water.

• Journal of the Korean Society of Marine Environment & Safety
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• v.26 no.7
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• pp.858-863
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• 2020

We experimented with the particle-settling velocity and CHCl3 absorption efficiency of seven activated-carbon and analyzed seven heavy metal contents by elution for application to the field treatment of sunken HNS on the marine seabed. The mean particle-settling velocity was in the range 0.5-8 cm/s, except when the 8-20 mesh was used. The larger the HNS particle, the faster the particle-settling velocity was, and the CHCl3 absorption efficiency increased considerably owing to the larger surface area. In addition, the elution test results showed that the total Zn and As contents in >100-meshed activated carbon was higher than the contents criteria for the standard for water-treatment agents, and Cr, Zn, and As were released at higher concentrations than those released by other activated-carbon groups. Taken together, the CHCl3 absorption efficiency, settling velocity, and elution test results suggested that the 20-60, 20-40, and 2mm&down mesh activated-carbon adsorbents could be applied to the field treatment of HNSs and that the minimum required amount for field treatment were 0.82, 0.90, and 1.28 ton/㎘, respectively, as calculated based on the HNS-adsorption-capacity priority.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.4
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• pp.377-389
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• 2020

In this study, pollution characteristics were investigated for the Andong Dam sediments in the Nakdong River. Sediment samples were collected from the middle, left, and right points of the lake up to 40km upstream of the Andong Dam at intervals of about 5km by stratification and turnover period. In the case of nutrients and total organics such as loss of ignition, total nitrogen, and phosphorus, the degree of contamination is low, but heavy metals of arsenic and cadmium is very high. The contamination level of sediments in the dam area is higher than that of the branch of river and the control group, and concentration of chromium, copper, and lead are higher in the stratification period, and that of zinc is higher in turnover period. Arsenic, cadmium, manganese, and zinc showed contamination variation between upstream and downstream but chromium, copper, mercury, iron and lead didn't show the variation.

• Korean Journal of Environmental Agriculture
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• v.29 no.2
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• pp.152-158
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• 2010

Biosorption is considered to be an alternative method to replace the present adsorbent systems for the treatment of metal contaminated wastewater. In this study, by-product which was abandoned from brewing factory was used to remove metal component in aqueous solution. The experimental results showed that the range of the removal efficiency is 60~91% and adsorption equilibrium was reached in about 3 hr. FT-IR and stereo microscope has been used to observe the surface conditions and changes in functional groups by calcination. At the end of elution, the amount of nitrogen and phosphorus in water was increased 11 and 7 times compare raw sample to calcinated samples. The Langmuir isotherm adequately described the adsorption of waste materials and the maximum adsorption capacity was 28.17 mg/g for Cd. The overall results suggested that waste material might can be used for biosorption of Cd.