• Title/Summary/Keyword: heavy metal elements

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Evaluation of Heavy Metal Contents in the Floras Derived from Granite and Coal Bearing Shale Areas in Keumsan (금산의 화강암 및 함탄질 셰일 지역 토양내 식물체의 중금속 함량 특성)

  • Song Suck-hwan;Kang Young-Rib;Kim Il-Chool
    • Korean Journal of Plant Resources
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    • v.18 no.2
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    • pp.251-259
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    • 2005
  • Three different floras(M. sinsinsis, A. vulgaris, Robinia pseudo-acacia) were collected from the granite(GR) and coal bearing shale area(CB) and analysed for their heavy metal elements with the representative soils. Regardless of the flora species, the CB were high in average contents. Among the correlation relationships, the CB were more distinctive than the GR, and the A. vulgaris showed higher correlations than the M. sinsinsis. In the same soils, the A. vutgaris showed high contents than the M. sinsinsis and Robinia pseudo-acacia, and the M. sinsinsis were high relative to the Robinia pseudo-acacia. In the comparisons of the flora, root parts were high in most of the elements except for Zn. In the soils, the CB were high in most of elements while As and Mo showed different contents between the GR and CB. In the comparison between soil and flora, soils of the GR were high in the V and Sc contents and low in Zn and Cu, while those of the CR were high in the Cr, V and Sc contents, and low in the Zn contents, Comparing with the soil contents, the M, sinsinsis in the GR were similar to Co and V contents while, in the CB, the M. sinsinsis were similar to the Ni, Cr, Co, Zn, Mo contents, and the Robinia pseudo-acacia were similar to the Ni, Zn, Cu contents. Overall results suggested that the M. sinsinsis and A. vulgaris should be eligible for the bioremediation of the soils polluted by heavy metal such as the CB.

Interpretation of heavy metal elements from the road dusts using GIS (GIS를 이용한 도로 분진의 중금속원소 함량 해석에 관한 연구)

  • 이효재;이근상;이언호;장영률
    • Spatial Information Research
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    • v.10 no.2
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    • pp.201-213
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    • 2002
  • Chemical analyzes were carried out the samples from roadsides of the Gwangju city. The purpose of this research is to investigate the concentrations and distribution patterns of heavy metals due to urbanization and industrialization in the Gwangju city This study area is not significantly contaminated based on the concentrations of Cd, Cu, Fe, Mn, Pb and Zn. However, the concentrations of the chemical elements analyzed are locally higher than those of serious contamination level indicated by Ministry of environment. The dust pH is in the rage of 5.60-7.09 and was generally neutral, and there are no difference in pollution area and nonpollution area. Chemical analyses utilized are dilution by 0.1N HCl. In result of analysis by the method using 0.1N HCl, concentrations of Cd and Cu are a little high in Gwangchondong of Seo-Gu. Concentrations of Mn and Pb are a little high in Buk-Gu and Nam-gu, and Concentrations of Zn are generally higher than average of soils. Zn, in the study area, keeps polluting greatly as Zn concentration of average is 150.9ppm. All of P.I values are lower than 1, it means heavy metal pollution is not serious.

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Isoform-specific response of two GAPDH paralogs during bacterial challenge and metal exposure in mud loach (Misgurnus mizolepis: Cypriniformes) kidney and spleen

  • Cho, Young-Sun;Kim, Dong-Soo;Nam, Yoon-Kwon
    • Journal of fish pathology
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    • v.24 no.3
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    • pp.269-278
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    • 2011
  • Gene expression of two glyceraldehyde-3-phosphate dehydrogenase (GAPDH) paralogs was examined during Edwardsiella tarda challenge and heavy metal exposures in mud loach (Misgurnus mizolepis; Cypriniformes) kidney and spleen. Transcription of the two mud loach GAPDH paralogs (mlGAPDH-1 and mlGAPDH-2) was significantly modulated by these stimulatory challenges in an isoform-dependent manner. Based on the real-time RT-PCR analysis, the mlGAPDH-2 transcripts were more preferentially induced by E. tarda challenge, whereas the mlGAPDH-1 transcripts were proven to show more inducibility in response to heavy metal exposure using Cd, Cu, Mn and Zn at $5{\mu}M$. Their isoform-specific response patterns were closely in accordance with the TF binding profiles in promoter and intron-1 of the two mlGAPDH isoforms, in which the mlGAPDH-2 has more binding sites for immune-related transcription factors than mlGAPDH-1 while the mlGAPDH-1 possesses exclusively metal responsive elements in its intron. Collectively, the mlGAPDHs are potentially involved in cellular pathways independent of glycolysis and the two GAPDH paralogs might undergo functional diversification or subfunctionalization at least at the transcription level.

Transfer of Arsenic and Heavy Metals from Soils to Rice Plant under Different Drainage Conditions (논토양 배수조건에 따른 비소 및 중금속의 용출 및 벼 전이특성)

  • Koh, Il-Ha;Kim, Jungeun;Kim, Gi Suk;Ji, Won Hyun
    • Journal of Soil and Groundwater Environment
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    • v.22 no.6
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    • pp.12-21
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    • 2017
  • A pot experiment was conducted to investigate the transfer of As and cationic heavy metals (Fe, Mn, Zn, Cd and Pb) from soil to rice plant in soil condition with submerged and drained. During the ninety-day monitoring period for soil solution, solubility of reducible elements such as As, Fe and Mn in submerged condition were higher than that of Zn. On the contrary, concentration of Zn in drained condition was higher than that of reducible elements. The concentration of As, Cd, Pb and Zn in rice plant (root, stem, leaf and grain) showed similar pattern with soil solution. The As concentration in each part of rice plant, which cultivated in drained condition, measured 56%~94% lower than those in submerged condition. However, the contents of cationic heavy metals (Cd, Pb and Zn) were represented the opposite result with As. These results are due to mobility of As and cationic heavy metals under different soil drainage conditions which represent oxidation and reduction. Thus soil drainage control can be used as acceptable passive treatment methods to reduce transfer of inorganic contaminants from soil to rice plant. However more detailed examination on soil condition conversion is needed, because yield of rice was decreased when it cultivated in drained condition only. It also needed when soil is contaminated by As and cationic heavy metal because single drainage condition cannot reduce transfer of both kinds of contaminants all.

Influence of Toxicologically Relevant Metals on Human Epigenetic Regulation

  • Ryu, Hyun-Wook;Lee, Dong Hoon;Won, Hye-Rim;Kim, Kyeong Hwan;Seong, Yun Jeong;Kwon, So Hee
    • Toxicological Research
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    • v.31 no.1
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    • pp.1-9
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    • 2015
  • Environmental toxicants such as toxic metals can alter epigenetic regulatory features such as DNA methylation, histone modification, and non-coding RNA expression. Heavy metals influence gene expression by epigenetic mechanisms and by directly binding to various metal response elements in the target gene promoters. Given the role of epigenetic alterations in regulating genes, there is potential for the integration of toxic metal-induced epigenetic alterations as informative factors in the risk assessment process. Here, we focus on recent advances in understanding epigenetic changes, gene expression, and biological effects induced by toxic metals.

Geochemical investigation of stream sediment and water of the Anyang river: Environmental implication (안양천 하천수 및 퇴적물의 지구화학 예비조사와 환경적 의미)

  • 이상훈;문지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.151-155
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    • 1998
  • The Anyang river drains a highly polluted industrial area and enters the lower part of Han river. In this preliminary study for the comprehensive understanding of geochemical behaviour of elements in the stream sediments and its implications on the river chemistry and ecology, major and trace elements in stream sediments, suspended solids and stream water were analysed to look into elemental enrichments and elemental behaviour with distance from upper part of the stream. Chemical analyses of the stream sediments show enrichements of heavy metals including Cr, Zn, Ni, Co between 10 to 100 times. Other trace elements, Cd, Pb and As are also enriched between several to 10 times, based on relative ratio with Al in fresh rock. Chemical analyses of the sediments, suspended solids and water show indications of anthroporgenic impact for the heavy metal accumulation. It was nortworth Hg is detected between 2 and 4 ppb in the water.

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Leaching and stabilization of the heavy metals with pH in EAF dust-clay system (EAF 더스트-점토계의 중금속 용출 및 안정화에 미치는 pH의 영향)

  • Lee, Jee-Young;Lee, Ki-Gang;Kim, Yoo-Taek;Kang, Seung-Gu;Kim, Jung-Hwan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.2
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    • pp.88-93
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    • 2006
  • To recycle the electric arc furnace (EAF) dust as a ceramic raw materials, the leaching concentrations of heavy metals (Zn, Pb, Cr, Cd) were analysed with various pH and mixing ratios for EAF dust and EAF dust-clay mixtures. The evaporation amounts of the some heavy metals were evaluated by measuring their total concentrations in the sintered bodies of EAF dust-clay mixtures with various mixing ratio and sintering temperature. Toxicity characteristic leaching procedure (TCLP) test was conducted for evaluating the chemical stabilities of the heavy metal elements. Leaching concentrations of heavy metal ions shows minimum leaching concentration at the pH 10. Evaporation amount of heavy metals in the sintered bodies were evaluated for the mixtures of pH 10 depenidng on mixing ratio and sintering temperature. Evaporation of heavy metal components were increased with increasing the sintering temperature and contents of the EAF dust. The evaporation of the heavy metal components in EAF dust was effectively suppressed by increasing the clay content. The leaching concentrations of heavy metal components were decreased with increasing clay content and temperature.

A Basic Study for Removal of Heavy Metal Elements from Wastewater using Spent Lithium-Aluminum-Silicate(LAS) Glass Ceramics (사용 후 유리세라믹(Lithium-Aluminum-Silicate)을 활용한 중금속 제거 기초 연구)

  • Go, Min-Seok;Wang, Jei-Pil
    • Resources Recycling
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    • v.31 no.4
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    • pp.49-55
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    • 2022
  • In this study, the heavy metal ions (of Pb, Cd, Cr, and Hg) in wastewater were removed using a spent Li2O-Al2O3-SiO2-based crystallized glass previously used as an induction top plate material. Changes in the removal efficiency of heavy metals according to different reaction parameters, such as the amount of zeolite used as a heavy-metal adsorbent, adsorption time, initial concentration of the heavy metals, and pH of the initial solution, were investigated. As the amount of zeolite added increased, the heavy-metal removal efficiency also increased. Adsorption time had a considerable influence on adsorption characteristics, and the removal efficiency of all heavy metals increased with increasing adsorption time. In the case of Cd, the removal efficiency was greatly improved depending on the adsorption time. The initial concentration of the heavy-metal solution did not affect the removal efficiency; however, the initial pH of the heavy-metal solution affected the removal efficiency. More specifically, the removal efficiency of Cd increased while that of Pb and Cr decreased with increasing pH. The adsorption characteristics of Hg were not significantly affected by pH.

The Ingredients of Mascara Causing Effects on the Eyes (눈에 영향을 미칠 수 있는 마스카라의 성분)

  • Jang, Sun;Kho, Young Lim;Kim, Hyojin;Kang, Bonghoon;Lee, Eun-Hee
    • Journal of Korean Ophthalmic Optics Society
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    • v.14 no.4
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    • pp.83-87
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    • 2009
  • Purpose: This study was performed to detect various chemicals such as metal elements and volatile organic compounds which contained in mascara and we analyzed 5 sorts of mascaras frequently used by people. Methods: We purchased five sorts of mascaras commercially available and analyzed for detecting metal elements and volatile organic ingredients. Results: We found somewhat high concentration of aluminum and manganese and several organic compounds in some samples. Conclusions: The results suggest that mascara has metal elements and organic compounds which can influence to eye.

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Assessment of heavy metals in sediments of Shitalakhya River, Bangladesh

  • Al-Razee, A.N.M.;Abser, Md. Nurul;Mottalib, Md. Abdul;Rahman, Md. Sayadur;Cho, Namjun
    • Analytical Science and Technology
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    • v.32 no.5
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    • pp.210-216
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    • 2019
  • Concentrations of Cu, Zn, Fe, Mn, Ni and Cr have been estimated in sediments of the Shitalakhya River at Polash-Ghorashal area, Narsingdi, Bangladesh. 36 samples of sediments from nine sampling point at different locations of Shitalakhya River were collected to determine the concentration of Cu, Zn, Fe, Mn, Ni, Cr and the samples were analyzed by atomic absorption spectrophotometer (AAS). The obtained results were compared with national and international guidelines. The levels of heavy metal concentrations in sediments were found to decrease in the order of Fe > Mn > Zn > Ni > Cu > Cr, respectively. The heavy metal concentration in sediment of Shitalakhya was below the recommended safe limits of heavy metals by WHO, FAO and other international standards. Contamination factor (CF) of Zn and Cu at sampling point Fsd2 show higher (> 1) values due to the influence of external discrete sources like wastage catalysts of ZnO and CuO. Geo-accumulation index values of the study indicate as non-contaminated to moderately contaminate.