• Title/Summary/Keyword: heat of hydration,

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The Effect of ZnO on the Hydration Reaction and Physical Properties of Cement (Cement의 수화반응 물리특성에 미치는 ZnO의 영향)

  • 김홍기;추용식;이경희;송명신
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.399-405
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    • 1997
  • With the increase of ZnO content, heat of hydration decreased. For specimens containing ZnO more than 0.6 wt.%, the compressive stength of cement cured for 28 days could not be measured because setting was not occurred. With the increase of ZnO content, Blaine specific surface area of cement was decreased and the residue of 45 ${\mu}{\textrm}{m}$ and 90 ${\mu}{\textrm}{m}$ was increased when cement was ground. That is, grindability became worse as ZnO increased in clinker. The difference of color as a function of ZnO content could not be observed, but in the excess of amount of ZnO added, color became more white and reddish yellow.

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Effect of Micro Organic-inorganic Complex on the Hydration of Portland Cement(II) (Mcchanical and rheological properties of PVA-montmorillonite complex cemenrt system) (마이크로 유기-무기 복합체가 포오틀랜드 시멘트 수화에 미치는 영향(II) (PVA-점토 복합체-시멘트 계의 기계적 유동학적 특징))

  • 김창은;김배연;최진호;이형복
    • Journal of the Korean Ceramic Society
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    • v.22 no.6
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    • pp.15-20
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    • 1985
  • In the course of cement hydration it was found that the addition of polyvinyl alcohol(contracted as PVA. here after) only in the cement paste could more influence on the set-retardation the depression of heat evol-ution rate than that of montmorillonit only or PVA-montmorillonie intercalation complex (PMIC) due to the effective adsorption of PVA on cement particles. The improved mechanical strength by addition of montmorillonite and PMIC was observed remarkably up to 0.05wt% due to the decrease of macro-pores caused by lowed viscosity or the acceleration of hydration reaction.

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Influences of the N.B.R. Latex on the Hydration of Gypsum Plaster (N. B. R. Latex가 석고 플라스터의 수화에 미치는 영향)

  • 형경우;이홍림;김창은
    • Journal of the Korean Ceramic Society
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    • v.19 no.3
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    • pp.187-192
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    • 1982
  • N.B.R. latex was used as the admixture in order to improve the various properties of gypsum plaster which is widely used as the construction material. The influences of N.B.R. latex on the hydration of gypsum plaster were studied. The results obtained are summerized as follows; 1. The water/gypsum plaster ratio is decreased wth increasing amounts of surfactant (P.O.E. Nonyl Phenol Ether) as the additive. 2. It is the pore of large size (${\gg}$7500A) that is mainly decreased with increasing amounts of surfactant. 3. With the small amount of surfactant as the additive, the hydration was slightly retarded, but was gradually recovered with increasing amounts of surfactant, and their heat of liberation after 20 hours were nearly same.

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Effects of nanomaterials on hydration reaction, microstructure and mechanical characteristics of cementitious nanocomposites: A review

  • Kim, Gwang Mok
    • Journal of Urban Science
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    • v.9 no.1
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    • pp.7-16
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    • 2020
  • Application of nanomaterials to cementitious composites has been attempted with the rapid development of nanotechnology since the 1990s. Various nanomaterials such as carbon nanotube, graphene, nano-SiO2, nano-TiO2, nano-Al2O3, nano-Clay, and nano-Magnetite have been applied to cementitious composites to improve the mechanical properties and the durability, and to impart a variety of functionality. In-depth information on the effect of nanomaterials on the hydration reaction, the microstructure, and the mechanical properties of cementitious nanocomposites is provided in the present study. Specifically, this paper mostly deals with the previous studies on the heat evolution characteristics of cementitious nanomaterials at an early age of curing, and the pore and the compressive strength characteristics of cementitious nanocomposites. Furthermore, the effect of nanomaterials on the cementitious nanocomposites was systematically discussed with the reviews.

An Integrated System to Predict Early-Age Properties and Durability Performance of Concrete Structures

  • Wang, Xiao-Yong;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.465-466
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    • 2010
  • In this paper, an integrated system is proposed which can evaluate both the early-age properties and durability performance of concrete structures. This integrated system starts with a hydration model which considers both Portland cement hydration and chemical reactions of supplementary cementing materials (SCM). Based on the degree of hydration of cement and mineral admixtures, the amount of reaction products, the early age heat evolution, chemically bound water, porosity, the early age short-term mechanical behaviors, shrinkage and early-age creep are evaluated as a function of curing age and curing conditions. Furthermore, the durability aspect, such as carbonation of blended concrete and chloride attack, are evaluated considering both the material properties and surrounding environments. The prediction results are verified through experimental results.

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The Effects of Na$_2$SO$_4$ on the Hydration of Fly ash Blended Cement (플라이애쉬 혼합시멘트에 미치는 Na$_2$SO$_4$의 영향)

  • 정석재;방완근;김창은
    • Journal of the Korean Ceramic Society
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    • v.35 no.11
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    • pp.1227-1232
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    • 1998
  • In order to prohibit the delay of early stage hydration activator Na2SO4 was added to Fly Ash blended ce-ment and its effects were investigated. Various measurements such as Compressive strength Heat of hy-dration Pore size distribution Hydration products Microstructure were evaluated and the results show that specimens of Fly Ash(50wt%) with 5% Na2SO4 dramatically improved the compressive strength because pozzolanic reaction of Fly Ash and the formation of ettringite make th microstructure denser than OPC and flyash cement paste.

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Accelerated Chloride Diffusion Properties of Portland Cement Concrete (포틀랜드계 시멘트 콘크리트의 촉진 염화물 확산 특성)

  • 김진철;이찬영;이용은
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.775-778
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    • 1999
  • Accelerated chloride diffusion tests were carried out to estimate the chloride diffusion coefficient of concrete using ordinary portland cement, low heat belite-rich portland cement, and sulphate resistant portland cement. Concrete using low heat belite-rich portland cement showed a high diffusion coefficient due to delayed hydration of low heat belite rich portland cement, while the diffusion coefficients of concrete using sulphate resistant portland cement and ordinary portland cement were low.

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Hydration Characteristics of Liquid Red Mud Mixed Cement Paste Neutralized with Sulfuric Acid (황산으로 중화시킨 액상 레드머드를 혼입한 시멘트 페이스트의 수화특성)

  • Kang, Suk-Pyo;Hong, Seong-Uk;Kim, Sang-Jin;In, Byung-Eun
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.5
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    • pp.431-439
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    • 2022
  • In this study, Neutralized red mud(LRM+S) at a pH of 6-8 was prepared by adding sulfuric acid to liquefied red mud(LRM) at a pH of 10~12. After adding LRM and LRM+S to the cement paste, the hydration heat, compressive strength, and hydration products were examined. The observed accumulated hydration heat revealed that the calorific value of the cement paste with LRM was low and its and peak was delayed when compared with that of plain cement paste(referred to as Plain), whereas the calorific value of the cement paste with LRM+S was similar to that of Plain. At the age of 28 days, the compressive strength of the cement paste with 20% LRM was 55% of the strength of Plain. Using X-ray diffraction, it was determined that the cement paste with 20% LRM exhibited a Ca(OH)2 peak after 3 days, whereas the cement paste with 20% LRM+S and Plain exhibited a Ca(OH)2 peak after an hour. Thus, the strength degradation of cementitious materials was improved by adding neutralized red mud prepared by adjusting the pH of highly alkaline LRM with sulfuric acid.