• Title/Summary/Keyword: heat of hydration,

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Thermal Crack Control of SRC Pier Using Low-Heat Portland Cement (저열 포틀랜드 시멘트 적용을 통한 SRC 교각 온도균열 제어)

  • 김태홍;하재담;유재상;이종열
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.297-302
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    • 2001
  • SRC pier at KTE 6-1 construction area is a very important structure. Precise control of quality is needed. This pier has 3.50m$\times$3.73m section and 38.20m length. So this structure must be treated as mass concrete and thermal crack caused by hydration heat should be controled. In this project belite cement concrete is used to control the thermal crack. As a result of adapting belite cement concrete perfect control is achieved. Finally, hydration heat FEM analysis of horizontal element is executed for Ordinary Portland Cement concrete and belite cement concrete. In comparison of two results, it is confirmed that using low heat portland cement concrete is necessary.

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The Early Hydration Characteristics of the System $C_3S-C_3A-C_4AF$(I) : Effect of Clinker Composition Variations ($C_3S-C_3A-C_4AF$계의 초기수화특성(I) : 클링커 조성변동의 영향)

  • 신규연;한기성
    • Journal of the Korean Ceramic Society
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    • v.27 no.8
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    • pp.1055-1063
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    • 1990
  • The early hydration characteristics of the system $C_3S-C_3A-C_4AF$ according to the clinker composition variations, in order to establish the mutual interactionof clinker minerals during the portland cement hydration, have been studied. The early hydration rate of $C_3S$ was greatly effected by the change of $C_3S/C_3A$ ratio. The lower the $C_3S/C_3A$ ratio was, the faster the apex reaching time and the rate of heat liberation of the 2nd exothermic peak originating from the formation of $Ca(OH)_2$ were. The effect of $C_3S/C_3A$ ration on the amounts of $Ca(OH)_2$ formation was decreased, in process of hydration time, but the effect of $C_3S$ content was increased.

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A Fundamental Experiment on Preventing Frost Damage at Early Age of Mortar in Low Temperature using Reduction Slag (환원슬래그를 사용한 모르타르의 저온에서의 초기동해 방지에 관한 기초적 실험)

  • Min, Tae-Beom;Mun, Young-Bum;Kim, Hyeong-Cheol;Choi, Hyun-Kuk;Kim, Jae-Young;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.1
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    • pp.1-7
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    • 2016
  • In this research, it used cement powder and reduction slag, which generates high hydration heat in hydration reaction without heat cure below $-5^{\circ}C$ degree. Purpose of final research is preventing freezing and thawing by making the compressive strength 5MPa in 3days below zero temperature due to own heat of concrete. and it is the result of physical characteristic and thermal property evaluation of reduction slag. Because reduction slag generates high hydration heat, compressive strength development is excellent. By generating highly hydration heat by $C_{12}A_7$ and $C_3A$ in reduction slag, compressive strength is developed in low temperature. In case of displacing only reduction slag without $SO_3$, it is indicated that quick-setting occurs by shortage of $SO_3$. For preventing quick-setting, gypsum is used essentially. According to this research result, in case of using reduction slag and gypsum as a ternary system, compressive strength developed 5MPa in 3 days below zero temperature. It is identified to prevent early frost damage of concrete below zero temperature.

Effect of Phase Change Material on Hydration Heat of Mortar with Fly Ash and Blast Furnace Slag (상전이물질이 플라이애시 및 고로슬래그를 혼입한 모르타르의 수화발열에 미치는 영향)

  • Nam, Yi-Hyun;Jang, Seok-Joon;Kim, Sun-Woong;Park, Wan-Shin;Yun, Hyun-Do
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.1-8
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    • 2019
  • Phase change material(PCM) has the capacity to absorb or release energy in heat when the phase changes. This study conducted to investigate the effect of strontium-based PCM on the hydration heat and mechanical properties of mortar with fly ash and blast furnace slag. The amounts of PCM were 1%, 2%, 3%, 4%, and 5% by the cementitious materials weight. The tests about mortar flow, semi-adiabatic temperature rise, compressive and flexural strength tests were carried out for twelve types of mortar mixtures. The test results indicated that the use of PCM was effective to reduce hydration heat and retard hydration of mortar with industrial by-products. In particular, the heat generation rate of mortars with fly ash was lower than that of mortars with blast furnace slag. The compressive strength of mortar with fly ash and blast furnace slag were decreased with increasing PCM ratio.

Hydration Reaction Properties of Concrete With Binders and Admixtures (결합재와 혼화재 종류에 따른 콘크리트의 수화반응 특성)

  • Cho, Il-Ho;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.50 no.2
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    • pp.27-34
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    • 2008
  • Recently, owing to the development of industry and improvement of building techniques, concrete structures are becoming larger and higher. This study was performed to analyze hydration reation properties of concrete with binders and admixtures, such as OPC, low heat cement, belite rich cement, slag powder, lime powder and fly ash. To investigate effects of PC type superplasticizer on the hydration, experiments involving FT-IR, XRD, DSC, SEM were analyzed at the curing age 1day, 3days and 28days. The hydration reaction rate of OPC concrete slightly delayed at the curing age 1day, blast furnace slag powder and fly ash were more effective. BRC and LHC concretes can be used for concrete structures in winter season.

Early Hydration of Tricalcium Silicate(III) (Tricalcium Silicate의 초기수화반응(III))

  • 오희갑;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.4
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    • pp.385-391
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    • 1987
  • Zeta potential according to the hydration time was studied during the early hydration of C3S with and without CO2 atmosphere. Zeta potential was low as a level of 20mV at the first and second exothermic peaks of heat evolution, but it was rapidly increased up to a level of 300mV. In the CO2 atmosphere, zeta potential was level of 60mV at 10 minutes hydration and it's value became a low gradually according to the hydration time. Zeta potential was also proportioned to the Ca2+ concentration in the liquid phase, i.e., there was positive correlation between zeta potential and Ca2+ concentration. The existence of silicate layer was not found out on the hydrated C3S in the CO2 atmosphere by SEM-EDAX.

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Thermal cracking assessment for nuclear containment buildings using high-strength concrete

  • Yang, Keun-Hyeok;Mun, Jae-Sung;Kim, Do-Gyeum;Chang, Chun-Ho;Mun, Ju-Hyun
    • Computers and Concrete
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    • v.26 no.5
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    • pp.429-438
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    • 2020
  • To shorten the construction times of nuclear facility structures, three high-strength concrete mixtures were developed with specific consideration given to their curing temperatures, their economic efficiency, and the practicality of their quality control. This study was conducted to examine the temperature rise profiles of these three concrete mixtures and the potential for early-age thermal cracking in the primary containment vessel of a nuclear reactor with a wall thickness of 1200 mm. The one-layer placement height of the concrete for the primary containment vessel was increased from the conventional 3 m to 3.5 m. A nonlinear finite element analysis (FEA) was conducted using the thermal properties of concrete determined from the isothermal hydration and adiabatic hydration tests, and tuned through comparisons made with temperature rise profiles obtained for 1200-mm-thick mock-up wall specimens cured at temperatures of 5, 20, and 35℃. The hydration heat performance of the three concrete mixtures and their potential to produce thermal cracking in nuclear facilities indicate that the mixtures have considerable potential for practical application to the primary containment vessel of a nuclear reactor at various curing temperatures, fulfilling the minimum requirements of the ACI 301 and minimizing the likelihood of the occurrence of thermal cracks.

Effect of Superplasticizer on the Early Hydration Ordinary Potland Cement (고성능감수제가 시멘트 초기 수화에 미치는 영향)

  • Na, Seung-Hun;Kang, Hyun-Ju;Song, Young-Jin;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.387-393
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    • 2010
  • To improve concrete quality one of the most widely used chemical admixtures is polycarboxylate type superplasticizer. Unlike lignosulfonate and naphthalene-sulfonate, it has high dispersion property and excellent sustainable dispersion property for cement and concrete. Thus, polycarboxylate type superplasticizer has been widely used as a high-performance water reducing admixture together with silica fume in high-performance concrete and other applications for the dispersion of high-strength concrete over 100 MPa. However, even though there have been many studied on the dispersion of concrete by the structure of polycarboxylate type superplasticizer, there have a few studied that clarified the relationships between its rheological properties and microstructure properties in the early hydration behavior of ordinary portland cement. To investigate the correlations between the rheological properties and microstructure of cementitious materials with polycarboxylate type superplasticizer, this study experimented on the rheology, pore structure, heat evolution, and consistency in early hydration as well as on the compressive strength by early dispersion characteristics.

Construction Method and Control System of the Heat of Hydration for Inchon International Airport Elevated Road Way (인천국제공항 여객터미널 전면 고가 교량 공사 시공방법 및 수화열 대책)

  • 임채만;박명웅;조용기;조선규;김은겸
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.869-881
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    • 1999
  • Inchon International Airport Elevated Road Way is located between the Passenger Terminal Building and Transportaion Center which are Inchon International Airport core construction projects. The deck of the bridge is consists of 5-span or 6-span continuous pre-stressed concrete slab. Steel form has been used to enhance the quality of texture on concrete slab. Steel form has been used to enhance the quality of texture on concrete surface, lower surface of deck slab with the two way arch has been manufactured by highly professional manner in order to get an beautiful exterior architectural looks. The prestressed concrete deck slab is mass concrete structures with a high-specified concrete strength and a varying section in the range of 0.95-2.8m thickness. Therefore high risks of thermal cracking occurrence by heat of hydration highly are expected. To resolve such problem, we adopted type 1 cement and pipe cooking method at construction site through mass concrete specimen test and 3-dimensional analysis. For Pipe cooling we used 25mm diameter stainless pipes with wrinkles. Cooling pipe with spacing 50-60cm has been installed. And continuous pipe cooling with cooling water of 15$^{\circ}C$ was conducted for 2days. In present 8 span of all 29 spans construction has been completed. No thermal cracking heat hydration has been observed yet.

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A Study on the Effects of Variables in Temperature Distribution of Mass Concrete (매스 콘크리트의 온도분포에 영향을 주는 주요 변수에 관한 연구)

  • 정철헌;강석화;정한중;박칠림;오병환
    • Magazine of the Korea Concrete Institute
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    • v.6 no.5
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    • pp.203-212
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    • 1994
  • The setting and hardening of concrete is accompanied by nonlinear temperature distribution caused by developing heat of cement hydration. This leads to tensile stresses that may exceed the strength of the young concrete, and cracks occur. In this present study, the heat of hydration characteristics are obtained from a study in which insulated concrete cubes were tested. Based on test results, concrete heat of hydration characteristics according to unit weight cement and flyash replacement quantity are determined, then employed in a numerical temperature analysis that consider both environmental interaction and concreting phases. The numerical results are performed by ADINA - T. The analytical results are in good agreement with experimental data.