• 제목/요약/키워드: heat of hydration,

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Hydration property of Recycled Cement Using Waste Cementitious Powder (폐콘크리트 미분말을 이용하여 제조한 시멘트의 수화특성)

  • Shin, Hyeon-Uk;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.47-48
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    • 2014
  • This study is to hydration property of low carbon type recycled cement from waste cementitious powder and cement raw materials. Waste cementitious powder possible to low carbon type recycled cement in small part of additive materials. Also, low carbon type recycled cement using waste cementitious powder is suitable for low heat type cement.

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The Effects of the Heavy Metal Ions on the Hydration and Microstructure of the Cement Paste (중금속이온이 시멘트의 수화 및 미세구조에 미치는 영향)

  • 김창은;이승규
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.967-973
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    • 1993
  • The effect on the hydration of cement was that Cu and Pb reacted with alkali to form soluble hydrates at theinitial stage and then there followed a slow reaction forming insoluble metal hydroxides. These hydroxides were deposited on the surface of cement particles providing a barrier against further hydration. But as a slow reaction continued, the insoluble layers were eventually destroyed and the hydration reaction resumed. Thereafter, another retardation occured by restricting the polymerization of silicates, shown by FT-IR spectroscopy analysis. In the case of Cr, as its reaction with cement caused H2O, the coordinator of Cr complex, to replace or polymerize with OH-, the formation of Cr complex promoted the leakage of OH- and increased the heat of dissolution. So the total heat evolution during hydration was larger than that in the case of Pb or Cu. The retarding effect of heavy metal ions was in the order Pb>Cu>Cr.

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A novel Fabry-Perot fiber optic temperature sensor for early age hydration heat study in Portland cement concrete

  • Zou, Xiaotian;Chao, Alice;Wu, Nan;Tian, Ye;Yu, Tzu-Yang;Wang, Xingwei
    • Smart Structures and Systems
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    • v.12 no.1
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    • pp.41-54
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    • 2013
  • Concrete is known as a heterogeneous product which is composed of complex chemical composition and reaction. The development of concrete thermal effect during early age is critical on its future structural health and long term durability. When cement is mixed with water, the exothermic chemical reaction generates hydration heat, which raises the temperature within the concrete. Consequently, cracking may occur if the concrete temperature rises too high or if there is a large temperature difference between the interior and the exterior of concrete structures during early age hydration. This paper describes the contribution of novel Fabry-Perot (FP) fiber optic temperature sensors to investigate the thermal effects of concrete hydration process. Concrete specimens were manufactured under various water-to-cement (w/c) ratios from 0.40 to 0.60. During the first 24 hours of concreting, two FP fiber optic temperature sensors were inserted into concrete specimens with the protection of copper tubing to monitor the surface and core temperature change. The experimental results revealed effects of w/c ratios on surface and core temperature developments during early age hydration, as well as demonstrating that FP fiber optic sensors are capable of capturing temperature variation in the concrete with reliable performance. Temperature profiles are used for calculating the apparent activation energy ($E_a$) and the heat of hydration (H(t)) of concrete, which can help us to better understand cement hydration.

Study on Hydration Heat Analysis of Pier Foundation-Column Using Low Heat Concrete (저발열 콘크리트를 사용한 교각 기초-기둥의 수화열 해석에 관한 연구)

  • Jeon, Joong-Kyu;Kim, Sun-Gil;Jeon, Chan-Ki;Kim, Ki-Hyung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.3
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    • pp.217-224
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    • 2014
  • This study carried out to evaluate the hydration heat analysis and fundamental characteristics such as air content, slump and compressive strength for field application of low heat concrete with premixed cement. The results of experiment show that low heat concrete with premixed cement have sufficient performances on the workability and compressive strength. In addition, hydration heat analysis shows that low heat concrete with premixed cement make sure of target thermal cracking index. Therefore, it is desirable to apply the low heat concrete with premixed cement on pier foundation-column.

An Experimental Study on the Hydration Heat of Self-Compacting Concrete (다성분계 초유동 콘크리트의 수화열에 관한 실험적 연구)

  • Joung, Won-Seoup;Kwon, Ki-Joo;Nah, Hwan-Seon;Oh, Byoung-Cheol;Noh, Jea-Myoung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.152-155
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    • 2004
  • Recently constructions of large scale infrastructures have been tending upwards, due to continuous growth of economy and increase of demands. In addition, hydration heat occurs rapidly in early age just after casting of concrete owing to higher strength and massive structure of concrete. Consequently, cracks and residual stress are developed in accordance to field condition. Moreover, These have harmful influences on safety, durability, watertight, waterproof, and shape of concrete structure. In this study, hydration heat tests were conducted on three of self-compacting concrete and one of high strength concrete. Heat generation and temperature are compared and evaluated based on the test results.

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Field Application of Low Heat Concrete with Phosphate-PCM in Vietnam (Phosphate-PCM계 보급형 저발열 콘크리트 베트남 지역 현장 적용 평가)

  • Ki, Jun-Do;Lee, Sang-Hyun;Cho, Hong-Bum;Kim, Young-Sun;Jeon, Hyun-Soo;Yang, Wan-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.171-172
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    • 2022
  • This study aims to develop the hydration heat reducing material (powder type) to lower the heat of hydration of mass members in the extremely hot weather condition. In this study, we applied the developed material to the concrete that used two kinds of binders with cement and evaluate the concrete properties with it.

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A Study on the Structural Behavior in Mass Concrete Box Rahmen due to Hydration Heat (수화열에 의한 매스콘크리트 박스 라멘 구조물의 구조거동 연구)

  • 조병완;김영진;허민희
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.349-352
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    • 1999
  • Concrete cracks due to hydration heat are a serious problem, particularly in mass concrete structures such as box rahmen, dam or footing of pier, etc.. As a result of the temperature rise and restriction condition of foundation, the thermal stress which may induce the cracks can occur. In this, study, ABAQUS program package was used to calculate the temperature distributions generated by hydration heat and the thermal stress in box rahmen structure which have thickness of 1.7~2.2m, and applied for various equations of adiabatic temperature rise such as korean code, japanese code, convection coefficient and low heat cement code.

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Effect of Hydration Heat and Drying Shrinkage of Mass Concrete Using Hwangtoh Binder (황토결합재를 이용한 매스콘크리트의 수화열과 건조수축 효과)

  • Kang, Sung-Soo;Lee, Seong-Lo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.649-652
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    • 2008
  • In this paper, the applicability of hwangtoh, as an alternative of cement paste, is investigated for the solution of internal heat and shrinkage caused by the hydration of cement paste. Several small-sized specimens of hwangtoh and ordinary portland concrete(OPC) were compared as to compressive strength, heat of hydration, and shrinkage strain. Moreover, the applicability of mass structure was reviewed through the test of large-size specimens. The 28-day compressive strength of hwangtoh concrete(HBC), ranged 18 to 33 Mpa, can reach that of ordinary portland concrete. Not only the maximin internal temperature of HBC was read about 1/4 of OPC as it is cured, but also its drying shrinkage decreased as lower as 50% of OPC starting from 60 days. Therefore, hwangtoh binder is more favorable than cement one in the view of hydration heat and shrinkage under the construction of mass structures.

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