• 제목/요약/키워드: heat of formation

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Effect of Hot Water and Heat Treatment on the Apatite-forming Ability of Titania Films Formed on Titanium Metal via Anodic Oxidation in Acetic Acid Solutions

  • Cui, Xinyu;Cui, Xinyu
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.36.2-36.2
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    • 2011
  • Titanium and its alloys have been widely used for orthopedic implants because of their good biocompatibility. We have previously shown that the crystalline titania layers formed on the surface of titanium metal via anodic oxidation can induce apatite formation in simulated body fluid, whereas amorphous titania layers do not possess apatite-forming ability. In this study, hot water and heat treatments were applied to transform the titania layers from an amorphous structure into a crystalline structure after titanium metal had been anodized in acetic acid solution. The apatite-forming ability of titania layers subjected to the above treatments in simulated body fluid was investigated. The XRD and SEM results indicated hot water and/or heat treatment could greatly transform the crystal structure of titania layers from an amorphous structure into anatase, or a mixture of anatase and rutile.The abundance of Ti-OH groups formed by hot water treatment could contribute to apatite formation on the surface of titanium metals, and subsequent heat treatment would enhance the bond strength between the apatite layers and the titanium substrates. Thus, bioactive titanium metals could be prepared via anodic oxidation and subsequent hot water and heat treatment that would be suitable for applications under load-bearing conditions.

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재연소 과정을 적용한 연소로에서 공기 다단 연소기의 NOx 발생 및 열전달에 대한 효과 (Effect of a Multi Air-staged Burner on NOx Formation and Heat Transfer in Furnace Adopted the Reburning Process)

  • 김혁수;백승욱;이창엽
    • 대한기계학회논문집B
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    • 제30권9호
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    • pp.842-849
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    • 2006
  • An experimental study has been conducted to investigate the effects of a multi air-staged burner on NOx formation and heat transfer in a 15kW large-scale laboratory furnace adopted the reburning process. The reburn fuel as well as burnout air was injected from each nozzle attached at the wall of the cylindrical furnace. Fuel in both main burner and reburn nozzle was LPG (Liquefied Petroleum Gas). The paper reports the influences on NOx reduction of reburn fuel fraction in reburning zone. Temperature distribution inside the overall region as well as total heat flux at the wall of the furnace has been measured to examine the heat transfer characteristics due to the reburning process. For comparison, the reburning effects were examined for a combustor with two types of burner; a regular single staged burner and a multi-air staged burner. A gas analysis was also performed to evaluate an appropriate condition for NOx emission in a primary zone for the excess air ratio of 1.1. As a result, combustion efficiency expected to become more efficient due to the reduction of heat loss in burnout zone decrease when multi air-staged burner in furnace adopted reburning technology was used.

해조류 톳 (Hizikia fusiforme)의 효소 가수분해 (Enzymatic Hydrolysis of Marine Algae Hizikia fusiforme)

  • 송부복;김성구;정귀택
    • KSBB Journal
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    • 제26권4호
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    • pp.347-351
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    • 2011
  • In this study, we investigated the effect of reaction factors on enzymatic hydrolysis of Hizikia fusiforme, which is brown algae in marine biomass resource, using commercial enzymes. The composition of H. fusiforme is 38.9% of reducing sugar, 4.8% of moisture, 17.8% of ash, and 38.5% of others. In the condition of 1-5% substrate, the increase of substrate concentration enhanced the increase of reducing sugar formation; however, the hydrolysis yield did not increase after 24 h. After reaction of 75 h, conversion yield of reducing sugar were obtained to 16.45%, 17.99%, and 14.55% at 1, 2.5, and 5% substrate, respectively. As a result of effect of enzyme amount, the formation of reducing sugar did not show considerable change at 1% substrate. However, in the condition of 2.5% substrate, the great change of reducing sugar formation was observed by the increase of enzyme amount. The conversion yields of reducing sugar were obtained to 18.77% and 22.83% at 1% and 2.5% substrate with 30% enzyme, respectively. As a result of heat treatment of biomass, the high yield was obtained in 2.5% substrate and the yields were increased to 0.06-7.2% by the heat treatment. This result will provide the basic information for production process of biofuels and chemicals from marine biomass H. fusiforme.

Determination of Lactulose and Furosine Formation in Heated Milk as a Milk Quality Indicator

  • Cho, Young-Hee;Hong, Sung-Moon;Kim, Cheol-Hyun
    • 한국축산식품학회지
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    • 제32권5호
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    • pp.540-544
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    • 2012
  • During heat treatment and storage of milk, deteriorative reaction takes place, which consequently influence on the milk quality. In this study, formation of lactulose and furosine under different thermal conditions and storage conditions, and the ratio of lactulose and furosine (LU/FU) in presence of reconstituted milk powder were determined to establish chemical indicators for heat damages of milk and the adulteration of fresh milk in dairy field. The lactulose and furosine contents linearly increased with increased heating temperature and heating time. It showed high correlation between the formation of lactulose and furosine, and the treatment temperature and time (p<0.05). The lactulose and furosine concentration of HTST milk and UHT milk noticeably increased during storage at $30^{\circ}C$, but there was no noticeable increase of lactulose and furosine concentration at lower storage temperature. In the raw milk, the lactulose and furosine contents greatly increased with the addition of reconstituted milk. The increase level of furosine was much higher than that of lactulose, which consequently resulted in the lower LU/FU ratio in milk as increase of added reconstituted milk amounts. As comparing with raw milk, there was more than twice reduction in LU/FU ratios after the addition of reconstituted milk (p<0.05). It can be concluded that lactulose and furosine are suitable milk quality indicators of heat damage and for demonstrating improper addition of reconstituted milk powder.

Bi-Pb-Sr-Ca-Cu-O계 산화물 고온초전도체의 특성에 관한 연구 (A Study on the Characteristic of High Tc Oxide Superconductor, Bi-Pb-Sr-Ca-Cu-O System)

  • 김양수;이민상;이민호;진영철
    • 열처리공학회지
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    • 제4권1호
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    • pp.13-18
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    • 1991
  • The formation of high $T_c$ phase is very sluggish and c parameter of unit cell of high $T_c$ phase is about $37{\AA}$. High $T_c$ oxide superconductor with a $T_c$ above 100 K has been successfully prepared by solid state reaction method in BiSrCaCuO system by Pb adding. The microstructure related to the formation of the high $T_c$ phase has been investigated. As compared with YBCO compound, the formation reaction of the high $T_c$ requires long time heat treatment. It is due to the transformation from the low $T_c$ phase to high $T_c$ phase. The sintering just below the melting point of the calcined powder mixture is effective on the formation of the high $T_c$ phase in Pb-added BiSrCaCuO system. The growth of the high $T_c$ superconducting phase has a thin plate shape, which is characterized by the c parameter of $37{\AA}$. The formation of the high $T_c$ phases is delayed by the excessive addition of Pb. The lattice parameter(c) of the unit cell (both the low and high $T_c$ phases) is increased with increase of Pb.

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Visualization of Diesel and GTL Spray Combustion and Soot Formation in a Rapid Charging Combustion Vessel with Shadowgraph Method

  • Kim, Ki-Seong;Azimov, Ulugbek;Lee, Yong-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • 제32권7호
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    • pp.1019-1029
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    • 2008
  • In this study, visual investigation of sprays and flames has been performed and soot formation in Diesel and GTL fuels has been compared in a specially designed Rapid Charging Combustion Vessel (RCCV) under various ambient gas $O_2$ concentrations and two injection pressures. It has been concluded that soot in the mixing-controlled combustion of Diesel and GTL fuels has similar tendency to be formed in the leading portion of the jet boundaries. Auto-ignition delay for GTL fuel is shorter than that for diesel fuel. The temporal and special variation of soot concentration in the diesel flame jets at various $O_2$ concentrations was correlated with the heat release rate. Soot concentration appears in the regions when diffusion combustion starts, and its concentration reaches maximum at the peak of heat release curve and then decreases due to oxidation. Visualization by shadowgraph method showed that soot decreases with lower $O_2$ concentration, and higher injection pressure.

메틸나이트로이미다졸 유도체의 화약성능 예측분석 (Predictive analysis on explosive performance of methylnitroimidzole derivatives)

  • 임완권
    • 분석과학
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    • 제28권5호
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    • pp.347-352
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    • 2015
  • 밀도함수 이론을 이용하여 메틸나이트로이미다졸 유도체의 생성열, 밀도 등의 화학적 특성치들을 예측하고 분석하였다. 이미다졸 링에 나이트로기를 계속적으로 치환하면 생성열과 밀도값은 증가한다. 예측된 화학적 특성치들을 이용하여 치타 프로그램으로 화약적 성능을 분석하고, 현재 널리 사용되는 TNT, RDX, HMX 등과 비교하였다. C-J 압력과 폭발 속도 등을 사용하여 화약 성능을 분석하면 메틸다이나이트로 유도체들은 TNT 보다는 성능이 약간 우수하며, 메틸트라이나이트로이미다졸은 RDX에 거의 버금가는 수준이다. 메틸나이트로이미다졸계 화약들은 용융점이 낮아 용융 충전이 가능하다는 장점이 있으므로 군수나 민수 등 다양한 방면이 사용이 가능할 것으로 예측된다.

고온변형 중의 AZ80 마그네슘합금의 집합조직 형성거동에 영향을 미치는 변형속도의 영향 (The Effect of Strain Rate on Texure Formation Behaviors in AZ80 Magnesium Alloy)

  • 배상대
    • 열처리공학회지
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    • 제33권6호
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    • pp.296-302
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    • 2020
  • Magnesium alloys have been rapidly attracting as lightweight structural material in various industry fields because of having high specific strength and low density. It is well known that the crystallographic texture plays an important role in improvement of poor room temperature ductility of magnesium alloys. In this study, high-temperature plane strain compression deformation was conducted on extruded AZ80 magnesium alloy at 723K by varying the strain rates ranging from 5.0×10-3s-1 to 5.0×10-2s-1 in order to investigate the behaviors of texture formation. It was found that texture formation behaviors in three kinds of specimens were affected by continuous and discontiuous deformation mechanism.

표면온도 제어에 의한 착상층 구조변화의 가시화 및 열전달 특성 연구 (A Characteristics Study on the Visualization and Heat Transfer of the Frost Formation Structure Variation by Control Plate Surface Temperature)

  • 김경천;고춘식;정재홍;고영환;신종민
    • 한국가시화정보학회:학술대회논문집
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    • 한국가시화정보학회 2002년도 추계학술대회 논문집
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    • pp.55-58
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    • 2002
  • To control the frost formation, a temperature variation of the cooling plate and characteristics on hydrophilic and hydrophobic surfaces was attempted. As a temperature variation of the cooling plate, being closely related to the frost layer density of frost layer is found to be affected by the melting process inside the frost layer during the heating period. At characteristics on surface, completely different structures of frost are appeared in the initial stage of frost formation due to the difference in surface conditions, while those effects are vanished with time. It is found that the frost thickness, density and heat flux characteristics are closely associated with the frost structure.

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저온 평판에서의 서리층 성장 예측 (Prediction of Frost Layer Growth on a Cold Plate)

  • 지성;이관수;여문수
    • 대한기계학회논문집B
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    • 제26권9호
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    • pp.1325-1331
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    • 2002
  • This study presents a numerical model to predict the behavior of frost layer growth. The characteristics of the heat and mass transfer inside the frost layer are analyzed by coupling the air flow with the frost layer. The present model is validated by comparing with the several other analytical models. It has been known that most of the previous models cause considerable errors depending on the working conditions or correlations used in predicting the frost thickness growth, whereas the model in this work estimates the thickness of the frost layer more accurately within an error of 10% in comparison with the experimental data. Simulation results are presented for variations of heat and mass transfer during the frost formation and for the behavior of frost layer growth along the direction of air flow.