• Title/Summary/Keyword: heat durability

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Carbon-Supported Ordered Pt-Ti Alloy Nanoparticles as Durable Oxygen Reduction Reaction Electrocatalyst for Polymer Electrolyte Membrane Fuel Cells

  • Park, Hee-Young;Jeon, Tae-Yeol;Lee, Kug-Seung;Yoo, Sung Jong;Sung, Young-Eun;Jang, Jong Hyun
    • Journal of Electrochemical Science and Technology
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    • v.7 no.4
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    • pp.269-276
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    • 2016
  • Carbon-supported ordered Pt-Ti alloy nanoparticles were prepared as a durable and efficient oxygen reduction reaction (ORR) electrocatalyst for polymer electrolyte membrane fuel cells (PEMFCs) via wet chemical reduction of Pt and Ti precursors with heat treatment at $800^{\circ}C$. X-ray diffraction analysis confirmed that the prepared electrocatalysts with Ti precursor molar compositions of 40% (PtTi40) and 25% (PtTi25) had ordered $Pt_3Ti$ and $Pt_8Ti$ structures, respectively. Comparison of the ORR polarization before and after 1500 electrochemical cycles between 0.6 and 1.1 V showed little change in the ORR polarization curve of the electrocatalysts, demonstrating the high stability of the PtTi40 and PtTi25 alloys. Under the same conditions, commercial carbon-supported Pt nanoparticle electrocatalysts exhibited a negative potential shift (10 mV) in the ORR polarization curve after electrochemical cycling, indicating degradation of the ORR activity.

Anti-fouling Properties of Functional Coating according to the Film Thickness and its Application to the Insulators for Electrical Railway (코팅막의 두께에 따른 기능성 코팅의 내오염 특성 분석 및 전기철도용 애자로의 활용)

  • Shan, Bowen;Kang, Hyunil;Choi, Wonseok;Kim, Jung Hyun
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.66 no.2
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    • pp.94-97
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    • 2017
  • A method of improving the anti-fouling characteristics of porcelain insulators was proposed in this study. Functional coating was performed as a method of reducing the surface contamination of the porcelain insulators. The functional coating was applied on a ceramic substrate, which has the same material as the porcelain insulators. After coating the ceramic substrate 2, 3, 4, and 5 times alternately in the horizontal and vertical directions, the surface characteristics according to the thickness of the coating film were analyzed. The optimal process was selected to coat the surfaces of the post insulators and long rod insulators, which are the representative porcelain insulators. After coating, heat treatment was performed for 1 hour at $200^{\circ}C$ in a furnace to secure the durability of the coating film. Compared to the uncoated insulators, the insulators with the functional coating showed significantly improved anti-fouling characteristics as well as excellent adhesion to the coated insulator surface.

Two Dimensional Numerical Model for Thermal Management of Proton Exchange Membrane Fuel Cell with Large Active Area (대면적 셀 고분자 막전해질 연료전지의 열관리를 위한 2 차원 수치 해석 모델)

  • Yu, Sang-Seok;Lee, Young-Duk;Ahn, Kook-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.5
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    • pp.359-366
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    • 2008
  • A two-dimensional thermal model of proton exchange membrane fuel cell with large active area is developed to investigate the performance of fuel cell with large active area over various thermal management conditions. The core sub-models of the two-dimensional thermal model are one-dimensional agglomerate structure electrochemical reaction model, one-dimensional water transport model, and a two-dimensional heat transfer model. Prior to carrying out the simulation, this study is contributed to set up the operating temperature of the fuel cell with large active area which is a maximum temperature inside the fuel cell considering durability of membrane electrolyte. The simulation results show that the operating temperature of the fuel cell and temperature distribution inside the fuel cell can affect significantly the total net power at extreme conditions. Results also show that the parasitic losses of balance of plant component should be precisely controlled to produce the maximum system power with minimum parasitic loss of thermal management system.

Study on Properties and Accelerated Life-time Test of Rubber O-ring by Temperature Stress

  • Shin, Young-Ju;Kang, Bong-Sung;Chung, Yu-Kyung;Choi, Kil-Yeong;Shin, Sei-Moon
    • Proceedings of the Korean Reliability Society Conference
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    • 2006.05a
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    • pp.48-54
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    • 2006
  • In this thesis, accelerated life test (ALT) method and procedure for rubber O-ring are applied to assure specified reliability of the products at guaranteeing the life of the products. Rubber O-ring is parts that keep intensity or make machine operation smoothly on attrition portion of machine and is used to prevent that oil is leaked. Usually. Rubber O-ring used NBR that is copolymer of acrylonitrile and butadiene. this are superior oil resistance, heat resistance, durability of abrasion, cold resistance, chemical resistance etc. The accelerated life test model for rubber O-ring are developed using the relationship between stresses and life characteristics of products. Using the accelerated life test method and the acceleration life test equipment which is developed, we performed life test, collected life data and analyzed the results of tests. The proposed accelerated life test method and procedure may be extended and applied to testing similar kinds of products to reduce test times and costs of the tests remarkably.

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Combustion Instability in Gas Turbine Engines (가스터빈에서의 연소불안정 현상)

  • Oh, Jeong-Seog;Yoon, Young-Bin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.12 no.4
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    • pp.63-77
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    • 2008
  • This paper described the general concept of combustion instability and its mechanism in gas turbine engines. The approaching method to study this phenomenon was introduced including the up-to-date research activity in tile world. Combustion instability is one of critical problems, still now, affecting engine performance, durability and operation. In addition it is known that this problem is caused by coupling between fuel or air flow fluctuation and heat release rate in gas turbine engines, which is related with NOx reduction strategies. Therefore, in order to understand the current status of combustion instability we reviewed the combustion instability phenomenon in gas turbine engines.

A Study on the Life Cycle Cost Analysis of the See-through a-si Building Integrated Photovoltaic System (투광형 비정질 BIPV 시스템의 LCC 평가에 관한 연구)

  • Lee, Han-Myoung;Oh, Min-Seok;Kim, Hway-Suh
    • Journal of the Korean Solar Energy Society
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    • v.29 no.1
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    • pp.1-10
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    • 2009
  • This study was carried out to evaluate the Life Cycle Cost(LCC) of three types of RTPV(Building Integrated Photovoltaic) systems-Glass plus Granite. Crystalline BIPV and See through Amorphous BIPV-which were vertically installed to generate the same power output(76 kW level). Initial investment costs. cost. savings and maintenance costs had been predicted during the period of analysing the LCC of three types of BIPV(Building Integrated Photovoltaic) systems installed for the purpose of evaluating the LCC. In case of cost savings, it had been analyzed by measuring the amount of electric power generated, reduction in lighting load and heat & cooling loads through simulation. From this analysis, it was predicted that the See-through amorphous BIPV offering cost saving advantages demonstrated the economical efficiency similar to the Class plus Granite when it is backed by more than 20 years of durability.

A Study Properties of concrete Recycling Cockle Shells as Fine Aggregate (고막 패각의 콘크리트 잔골재로 재활용 방안에 관한 연구)

  • Kim, Jeong-Sup;Kim, Kwang-Sup;Kim, Pan-Sun
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.1
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    • pp.141-146
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    • 2004
  • 1) As a result of compressive strength experiment, rupture compressive strength showed more increases in specimens of 15% and 20% of Cockle shells in those of non-mixture. Comparing compressive strength between no-mixed Specimens and Specimens of containing Cockle shells, Specimens containing Cockle shells showed higher strength in 60 days and 90 days of age, and as ark Cockle is contained and age is elapsed, compressive strength is also increased In addition, estimation of compressive strength by reactive hardness in concrete using Cockle shells as aggregate shows low reliability. 2) As a result of experimenting compressive strength after heating, Specimens containing Cockle shells and non-mixed Specimens showed similar strength at $200^{\circ}C$, but compressive strength was lowered as content of Cockle shells increased at over $400^{\circ}C$ and heating temperature was higher. It is because Cockle shells was fired by heat and then its adhesion and bonding capacity were lost. 3) To sum up the above experimental results, it is found that using splitted Cockle shells as aggregate for concrete by 10%~20% showed the same or higher compressive strength and shear strength as concretes using general aggregate and it can be used as substitute aggregate of concrete. It is considered that for future use of splitted Cockle shells as substitute concrete aggregate, continuous researches of its durability, applicability and economy are needed.

A Study on the Manufacture of Optical Filters for PDP Panel in Conductive Types (PDP 패널용 전도막 광학 필터 제조에 관한 연구)

  • Kim, Tae-Hoon;Kang, Bong-Gu;Lee, Tae-Hoon;Son, Se-Mo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.26 no.2
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    • pp.31-43
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    • 2008
  • The functional dyes, which has various optical characteristics that can be applicable to field of electronic, photo electronic, such as sensor or electrode, were synthesized. Physical property and optical stability was studied with preparation of conductive type film as a kind of optical filter of plasma display panel, by adapting neon cut off dye, which can selectively absorbing between 580 and 610nm wavelength. The filter was prepared with PSA resin, which has functional group of - COOH and - OH, as binder. And the characters such as spectroscopy, heat-proof / wet-proof, thermal stability and commerciality, which must be held by functional dyes, were examined. Conductive type film is the kind of film includes only neon cut off dyes. For the neon cut off dyes, cyanine dyes can be applied. And it is observed that spectrum of before and after the durability test are not changed due to stability of dyes, as the result of coating on the mesh film with PSA binder.

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PCM/Nylon6 복합사 염착특성

  • Lee, Jun-Hee;Kim, Hyung-Joo;Yim, Sang-Hyun;Im, Jung-Nam;Son, Young-A
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.35-35
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    • 2011
  • Phase change material(PCM) has thermal energy storage and been attracted attention. Latent heat of the organic PCM can keep maintaining temperature when the change of outside energy conditions influence to PCM. Thus, many researchers have interested to thermal energy storage ability and investigated to applications such as thermal storage of solar energy, bioclimatic building, icebank, medical application, clothing industry and so on. Among the many applications, investigation of the PCM in clothing industry is also important because the people has interest functional factor called health-care in the clothing. In addition, PCM can give them mild environment condition such suitable temperature control or humidity. To fabrics, the PCM has various methods such as microcapsule, padding and modified cross-section formation(Sheath/core). Sheath core PCM fabric has a better benefit of durability than other method. However, PCM sheath/core spinning is difficult. In addition, dyeing property is important to use clothing industry due to visual images. In this study, we investigated dyeing properties of Nylon/PCM sheath/core fabrics. Especially, we observed the relation between dyeing property and PCM including ratio. Various temperature and pH conditions were also studied to optimize dyeing properties as acid dye.

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Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine (Hexachlorocyclophosphazene과 Triethanolamine을 이용한 면섬유의 포름알데히드-프리 내구성 방염가공)

  • Kim, Jeong-Hwan;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.32 no.3
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    • pp.150-157
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    • 2020
  • Hexachloro-cyclophosphazene(HCCP), a formaldehyde-free flame retardant (FR), was steam-cured with triethanol amine(TEA) to impart durable flame-retardancy to cotton fabrics. While the HCCP treatment alone showed very limited resistance to repeated laundering cycles, the addition of TEA substantially improved the laundering durability of the FR cotton up to twenty laundering cycles. The extended washing resistance was accomplished by the increased nucleophilic substitution of unreacted P-Cl groups in HCCP by the TEA resulting in the more densely crosslinked FR networks. With increasing molar ratio of TEA to the HCCP up to 2, the flame retarding effectivity and the synergistic effectiveness improved to 2.8 and 1.8 respectively. TGA and microscale combustion calorimetry verified the pyrolysis and combustion behaviors of the FR-cotton, which showed lower maximum pyrolysis and combustion temperatures together with substantially decreased peak pyrolysis and heat release rate, synergistically yielding larger amounts of carbonaceous chars. The formaldehyde-free HCCP and TEA can be a durable FR finishing agents for cotton fabrics acting through a solid-phase flame-retarding mechanism.