• Journal of Hydrogen and New Energy
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• v.16 no.1
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• pp.31-39
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• 2005

Direct methanol fuel cell (DMFC) is considered as a candidate for portable power sources, that could overcome the disadvantages of lithium battery. But in order to attain commercial viability the long term stability of the DMFC should be achieved. Understanding the long-term behavior of membrane-electrode assembly (MEA) is a prerequisite to this purpose and the optimization of the MEA is also needed. In this study we have investigated the changes in performance and electrochemical properties of the MEA during extended operation and the effects of heat treatment of MEA on the long-term performance. The MEAs have been treated in an autoclave with saturated water vapor at 120$^{\circ}C$, vacuum oven at 140$^{\circ}C$ and boiling in organic solvents. The autoclaved MEA was found to be have the best long term performance. The on-off operation mode also increased the performance probably due to effective removal of products from the electrodes. Physical and electrochemical analyses using a scanning electron microscope, impedance analyser and half-cell technique have been done to characterize the MEAs.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.4
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• pp.771-781
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• 1994

The heat generation of cement causes the internal temperature rise and volume change at early age, particulary in massive concrete structures. As the results of the temperature rise and restraint conditions, the thermal stress may induce cracks in concrete. Therefore, the prediction of the thermal stress is very important in the design and construction in order to control the cracks developed in mass concrete. In case of young concrete, creep effect by the temperature load is larger than that of old concrete. Thus, the effect of creep must be considered for checking the cracks, serviceability, durability and leakage. This paper is concentrated on the development of a finite element program which is capable of simulating the temperature history and the thermal stress considering creep and the modified elastic modulus due to inner temperature change and maturity. The analytical results in the inner parts highest important to control cracks are in good agreement with experimental data. Therefore this study may provide available method to control the cracks.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.123.2-123.2
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• 2010

Fuel Cell cogeneration system is a promising technology for generating electricity and heat with high efficiency of low pollutant emission. We have been developed 5kW class fuel cell cogeneration system for commercial and residential application. The fuel processor is a crucial part of producing hydrogen from the fossil fuels such as LNG and LPG. The 5kW class high efficiency fuel processor consists of steam reformer, CO shift converter, CO preferential oxidation(PrOx) reactor, burner and heat exchanger. The one-stage CO shift converter process using a metal oxide catalyst was adopted. The efficiency of 5 kW class fuel processor shows 75% based on LHV. In addition, for the purpose of continuous operation with load fluctuations in the commercial system for residential use, load change of fuel processor was tested. Efficiency of 30%, 50%, 70% and 100% load shows 75%, 75%, 73% and 72%(LHV), respectively. Also, during the load change conditions, the product gas composition was stable and the outlet CO concentration was below 5 ppm. The Fuel processor operation was carried out in residential fuel cell cogeneration system with fuel cell stack under dynamic conditions. The 5kW class fuel processor have been evaluated for long-term durability and reliability test including with improvement in optimal operation logic.

• Korean Journal of Materials Research
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• v.21 no.5
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• pp.283-287
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• 2011

As the performance of microelectronic devices is improved, the use of copper as a heat dissipation member is increasing due to its good thermal conductivity. The high thermal conductivity of copper, however, leads to difficulties in the joining process. Satisfactory bonding with copper is known to be difficult, especially if high shear and peel strengths are desired. The primary reason is that a copper oxide layer develops rapidly and is weakly attached to the base metal under typical conditions. Thus, when a clean copper substrate is bonded, the initial strength of the joint is high, but upon environmental exposure, an oxide layer may develop, which will reduce the durability of the joint. In this study, an epoxy adhesive formulation was investigated to improve the strength and reliability of a copper to copper joint. Epoxy hardeners such as anhydride, dihydrazide, and dicyandiamide and catalysts such as triphenylphosphine and imidazole were added to an epoxy resin mixture of DGEBA and DGEBF. Differential scanning calorimetry (DSC) analyses revealed that the curing temperatures were dependent on the type of hardener rather than on the catalyst, and higher heat of curing resulted in a higher Tg. The reliability of the copper joint against a high temperature and high humidity environment was found to be the lowest in the case of dihydrazide addition. This is attributed to its high water permeability, which led to the formation of a weak boundary layer of copper oxide. It was also found that dicyandiamide provided the highest initial joint strength and reliability while anhydride yielded intermediate performance between dicyandiamide and dihydrazide.

• Water for future
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• v.5 no.2
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• pp.6-16
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• 1972

It has been well studied and known that the yields from the rice fields irrigated by the cold water such as the water directly flowing in from mountain valleies, underground water and subground water are largely influenced by the water temperature. However, the best method of raising water temperature has not yet been established. This is because there are some essentially difficult problems associated. When we examine the effects of $1^{\circ}C$ rise in the water temperature under natural condition on rice growing, the necessity of this line of study is verified. The results of Mihara's study show that rice bears its fruits at the water temperature above $19^{\circ}C$ and the difference of $1^{\circ}C$ in the range of $19^{\circ}C$ to $22^{\circ}C$ can produce the 20% of difference in yields. Because of these facts, most farmers have made use of water temperature raising ponds, zigzag waterways and shelter belts. But the most important factor in raising water temperature has been found to be the heat loss due to evaporation. Recently, a good deal of experiment on raising water temperature and soil temperature by reducing the evaporation are being carried out all over the world. The reduction of evaporation does not only reduce heat loss, from the surface but also reduce the loss of water. Present study is aimed to determine the efficiency of different chemicals by which monomolecular films are formed over different surfaces such as water surface, soil surface and the surface of plant leaves with a purpose of preventing the transpiration, and aimed to observe the effects of the temperature rise and its influence on growing state as well as the durability of the plants under drought condition.

• Journal of Energy Engineering
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• v.24 no.4
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• pp.63-70
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• 2015

Crevices between window and window frame cause not only heat losses but also serve path to sound transmission and infiltration of fine dusts that are harmful to humans. There were many efforts in the past to eliminate these crevices but because of the windows' indispensable function of opening and closing, it was an unsolvable problem. In this study, a new type sliding window is developed by applying horizontally rolling wheels to implement a surface sealing which is excellent for enhancing air tightness. To evaluate the feasibility of the newly developed window, forces for opening and closing, durability and air tightness were testet according to Korean Testing Standards. Force for opening a 2000 N window is 30 N. It endured 100,000 cycles of opening and closing. Infiltration was $0.00m^3/(m^2h)$ for a pressure difference of 10 Pa. Since this window has few moving parts, it has favorable features of low cost and few breakdown.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.3
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• pp.120-128
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• 2005

In the construction industry, due to the cost rise of raw material for concrete, we have looked into recycling by-products which came from foundry. When using the Ground Granulated Blast-Furnace Slag(SG), it is good for enhancing the qualities of concrete such as reducing hydration heat, increasing fluidity, long-term strength and durability, but it has some problems : construction time is increased or the rotation rate of form is decreased due to low development of early strength. In this study, therefore, to enhance the early strength of SG mortar, we used some alkali activators(KOH, NaOH, $Na_2CO_3$, $Na_2SO_4$, water glass, $Ca(OH)_2$, alum. This paper deals with reacted products, setting time, heat evolution rate, flow and the strength development of SG cement mortar activated by alkali activators. From the results, if alkali activators were selected and added properly, SG is good for using as the materials of mortar and concrete.

• Journal of the Korean GEO-environmental Society
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• v.18 no.11
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• pp.35-40
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• 2017

The rearside of concrete lining of tunnels constructed in cold region might experience on freezing due to the low temperature. This causes damage of concrete lining resulting in adverse affect on the durability as well as integrity of tunnel structure by causing damage to the concrete lining. In order to prevent the rearside of tunnel lining from freeing, the temperature change inside the concrete lining was measured by attaching a heating element to the tunnel lining surface and generating heat for a certain period of time. A special freezing chamber was developed to conduct the experiments considering in-situ environment. The carbone nanotube (CNT) was used as a heating element in this study. The temperature distribution of the concrete lining was measured by applying the heat to the heating element. The effect of the outside temperature and heating duration were analyzed.

• Korean Chemical Engineering Research
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• v.53 no.3
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• pp.276-281
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• 2015

Nanostructured $TiO_2-SiO_2$ materials have widely been used as anti-reflecting coating, optical-chemical sensors and catalysts because of their superior optical and thermal properties as well as chemical durability. Web type $SiO_2$ microfibers with nano-crystalline $TiO_2$ were prepared by electrospinning of Ti-PCS mixed solution and oxidation controlled heat-treatment, rather simple than sol-gel process. Nano-crystalline anatase phase were formed for the heat-treatment up to $1200^{\circ}C$ and they were finely dispersed in the amorphous $SiO_2$ matrix.

• The KSFM Journal of Fluid Machinery
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• v.14 no.3
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• pp.23-27
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• 2011

Due to a roots type medium vacuum pump is operated in condition of $1{\sim}10^{-3}$ torr vacuum, it could be applied for production and process of industrial parts, such as precise processing, vaporization, enrichment, separation, casting, metaling, welding, transportation. Therefore, the demand of this pump is increasing nowadays in our industrial markets of semiconductor, electric, electronic, automobile, material, environmental and transporting industries. However, the pumps are almost imported, because the domestic pumps are inferior in fields of vacuum range as under $10^{-1}$torr, relevant techniques(design, fabrication, casting, test, etc.) to the imported ones. In this study, essential parts of the development pump are designed with using of CFD and 3D decodes, FEM for analysing strength and deformation, generated heat, vibration and noise control, and are casted with using of mechanochemistry techniques for decreasing of weights, increasing of heat resistances and abrasion durability of materials for pump caing and impellers especially. Besides, in order to achieve ultimate vacuum around $10^{-3}$torr, this pump is composed of 6 stages, among which 1st stage is operated separately from remained stages. Additionally, a test rig for prototype pumps(300$m^3/h$ and 2,500$m^3/h$) is designed and procured as to apply for multi-staged rootz type vacuum pump, with modification of the test method recommended by KS B 6314 "Positive-displacement oil-sealed rotary vacuum pumps".