• 전자공학회논문지B
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• 제31B권5호
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• pp.50-57
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• 1994

In the non-destructive evaluation techniques using ultrasonic signal, backscattering noise from grain interface decreases the SNR of received signal. In this paper, SSP(split-spectrum processing) based on the constant FBR decomposition method has been applied to enhance the SNR. This algorithm helps to find optimal parameters of filter bank through a simple theory and has an advantage that reduce the signal processing time compared with the conventional constant bandwidth decomposition method. In this experiment, the 304 stainless steel sample is heat-treated and received ultrasonic signal is processed by SSP using the constand bandwidth decomposition method and the constand FBR decomposition method enhanced the SNR by 1.4 dB and reduced the required number of filters by 4 compared with the constant bandwidth decomposition method.

• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2259-2264
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• 2009

A new high-energy organic potassium salt, 2-(dinitromethylene)-1,3-diazepentane potassium salt K(DNDZ), was synthesized by reacting of 2-(dinitromethylene)-1,3-diazepentane (DNDZ) and potassium hydroxide. The thermal behavior and non-isothermal decomposition kinetics of K(DNDZ) were studied with DSC, TG/DTG methods. The kinetic equation is $\frac{d{\alpha}}{dT}$ = $\frac{10^{13.92}}{\beta}$3(1 - $\alpha$[-ln(1 - $\alpha$)]$^{\frac{2}{3}}$ exp(-1.52 ${\times}\;10^5$ / RT). The critical temperature of thermal explosion of K(DNDZ) is $208.63\;{^{\circ}C}$. The specific heat capacity of K(DNDZ) was determined with a micro-DSC method, and the molar heat capacity is 224.63 J $mol^{-1}\;K^{-1}$ at 298.15 K. Adiabatic time-to-explosion of K(DNDZ) obtained is 157.96 s.

• 태양에너지
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• 제15권1호
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• pp.73-84
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• 1995

[ $Ca(OH)_2$ ]의 열분해 반응을 이용하는 화학축열법에서는 $Ca(OH)_2$ 입자 충전층의 열전도성이 나쁘기 때문에 축열과정의 소요시간이 길어 실용화에 커다란 장애가 되고 있다. 본 연구에서는 $Ca(OH)_2$ 입자 충전층의 열전달을 촉진시키기 위해 반응기속에 구리판으로 된 전열핀을 설치하고 열분해 탈수반응 실험을 하였다. 그 결과 전열핀이 없는 경우보다 탈수반응에 소요되는 시간을 1/2 이하로 크게 단축시킬 수 있었다.

• 약학회지
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• 제7권2_3호
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• pp.51-54
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• 1963

In this experiment, it is found that the decomposition reaction of hexamine aqueous solution by heat is the pseudo first order reaction and the calculated decomposition velocity constants of Hexamine aqueous solution are 1.17 * $10^{-5}min.^{-1}(60{\deg}$ C), 1.99 * $10^{-5}min.^{-1}(70{\deg}$ C), 2.35 * $10^{-5}min.^{-1}(80{\deg}$ C), 6.63 * $10^{-5}min.^{-1}(100{\deg}$ C). In the result, the activation energy of decomposition reaction of hexamine aqueous solution is 12 $Cal.mole^{-1}$.

• 환경위생공학
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• 제14권4호
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• pp.93-98
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• 1999

We had investigated combustion properties of rice bran dusts. Decomposition of rice bran dusts with temperature were investigated using DSC and the weight loss according to temperature using TGA in order to find the thermal hazard of rice bran dusts, and the properties of dust explosion in variation of their dust with the same particle size. Using Hartman's dust explosion apparatus which estimate dust explosion by electric ignition after making dust disperse by compressed air, dust explosion experiments have been conducted by varying concentration and size of rice bran dust.According to the results for thermodynamic stability of rice bran dust, there are little change of initiation temperature of heat generation and heating value for used particle size. But initiation temperature of heat generation decreased with high heating rate whereas decomposition heat increased with particle size. Average maximum explosion pressure was $10kgf/cm^2$ for 60/70 mesh and $1.5mg/cm^2$ dust concentration.

• 대한기계학회논문집A
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• 제32권10호
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• pp.836-843
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• 2008

An efficient domain/boundary decomposition method is applied for heat transfer problems with non-linear thermal radiation boundaries. The whole domain of solids or structures is considered as set of subdomains, an interface, and radiation interfaces. In a variational formulation, simple penalty functions are introduced to connect an interface or radiation interfaces with neighboring subdomains that satisfy continuity conditions. As a result, non-linear finite element computations due to the thermal radiation boundaries can be localized within a few subdomains or radiation interfaces. Therefore, by setting up suitable solution algorithms for the governing finite element equations, the computational efficiency can be improved considerably. Through a set of numerical examples, these distinguishing characteristics of the present method are investigated in detail.

• 한국유체기계학회 논문집
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• 제14권1호
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• pp.34-41
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• 2011

Fire characteristics can be analyzed more realistically by using more accurate properties related to the fire dynamics and one way to acquire these fire properties is to use one of the inverse property estimation techniques. In this study two optimization algorithms which are frequently applied for the inverse heat transfer problems are selected to demonstrate the procedure of obtaining pyrolysis properties of charring material with relatively simple thermal decomposition. Thermal decomposition is occurred at the surface of the charring material heated by receiving the radiative energy from external heat sources and in this process the heat transfer through the charring material is simplified by an unsteady 1-dimensional problem. The basic genetic algorithm(GA) and repulsive particle swarm optimization(RPSO) algorithm are used to find the eight properties of a charring material; thermal conductivity(virgin, char), specific heat(virgin, char), char density, heat of pyrolysis, pre-exponential factor and activation energy by using the surface temperature and mass loss rate history data which are obtained from the calculated experiments. Results show that the RPSO algorithm has better performance in estimating the eight pyrolysis properties than the basic GA for problems considered in this study.

• 융복합기술연구소 논문집
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• 제5권1호
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• pp.1-5
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• 2015

SI thermochemical hydrogen production process achieves water splitting into hydrogen and oxygen through three chemical reactions. The process is comprised of three sections and one of them is HI decomposition into $H_2$ and $I_2$ called as Section III. The production of $H_2$ included processes involving EED for concentrating a product stream from Section I. Additionally an $I_2$ crystallization would be considered to reduce burden on EED by removing certain amount of $I_2$ out of a process stream prior to EED. In this study, the current thermodynamic model of SI process was briefly described and the calculation results of the applied Electrolytes NRTL model for phase equilibrium calculations was illustrated for ternary systems of Section III. We calculated temperature and heat duty of an $I_2$ crystallizer and heat duty of heaters using UVa model and heat balance equation of simulation tool. The results were expected to be used as operation information in optimizing HI decomposition process and setting up material balance throughout SI process.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 제33회 추계학술대회논문집
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• pp.93-96
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• 2009

고속 비행기술의 발전과 엔진효율의 향상은 비행체와 엔진의 열적부하를 증가시킨다. 극초음속까지 비행체의 속도가 빨라지면 공기흐름을 이용한 냉각이 어렵기 때문에 항공유를 주요 냉각제로서 사용하게 된다. 연료가 열 흡수원(Heat sink)으로서 사용될 때 열분해반응 또는 촉매분해반응과 같은 흡열반응(Endothermic reaction)을 거쳐 분해가 되는데 이러한 특성을 지닌 연료를 흡열연료(Endothermic fuels)라고 한다. 흡열반응은 촉매를 통해 개선될 수 있지만, 코킹침적이 형성되기 이전까지의 온도로 제한된다. 본 연구에서는 흡열연료에 관련된 주요 기술을 조사하여 기초연구에 활용하고자 하였다.

• 한국태양에너지학회 논문집
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• 제37권2호
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• pp.13-22
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• 2017

Two-step water splitting thermochemical cycle with $CeO_2/ZrO_2$ foam device was investigated by using a solar simulator composed of 2.5 kW Xe-Arc lamp and mirror reflector. The hydrogen production of $CeO_2/ZrO_2$ foam device depending on heat recovery of Thermal-Reduction step and Water-Decomposition step was analyzed, and the hydrogen production of $CeO_2/ZrO_2$ and $NiFe_2O_4/ZrO_2$ foam devices was compared. Resultantly, the quantity of hydrogen generation increased by 52.02% when the carrier gas of Thermal-Reduction step is preheated to $200^{\circ}C$ and, when the $N_2/steam$ is preheated to $200^{\circ}C$ in the Water-Decomposition step, the quantity of hydrogen generation increased by 35.85%. Therefore, it is important to retrieve the heat from the highly heated gases discharged from each of the reaction spaces in order to increase the reaction temperature of each of the stages and thereby increasing the quantity of hydrogen generated through this.