• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2867-2872
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• 2010

Two new energetic organic alkali metal salts, 1,1-diamino-2,2-dinitroethylene rubidium salt [Rb(FOX-7)${\cdot}H_2O$] and 1,1-diamino-2,2-dinitroethylene cesium salt [Cs(FOX-7)${\cdot}H_2O$], were synthesized by reacting of 1,1-diamino-2,2-dinitroethylene (FOX-7) and rubidium chloride or cesium chloride in alkali methanol aqueous solution, respectively. The thermal behaviors of Rb(FOX-7)${\cdot}H_2O$ and Cs(FOX-7)${\cdot}H_2O$ were studied with DSC and TG methods. The critical temperatures of thermal explosion of the two compounds are 216.22 and $223.73^{\circ}C$, respectively. Specific heat capacities of the two compounds were determined with a micro-DSC method, and the molar heat capacities are 217.46 and $199.47\;J\;mol^{-1}\;K^{-1}$ at 298.15 K, respectively. The adiabatic times-to-explosion were also calculated to be a certain value of 5.81 - 6.36 s for Rb(FOX-7)${\cdot}H_2O$, and 9.92 - 10.54 s for Cs(FOX-7)${\cdot}H_2O$. After FOX-7 becoming alkali metal salts, thermal decomposition temperatures of the compounds heighten with the rise of element period, but thermal decomposition processes become intense.

• 공업화학
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• 제29권5호
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• pp.541-548
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• 2018

본 연구에서는 $N_2O$를 제거하기 위한 $N_2O$ 분해 촉매와 반응특성에 대한 연구를 수행하고자 한다. 다양한 지지체에 Rh를 활성금속으로 촉매를 제조하여 실험을 수행하였으며, $CeO_2$를 지지체로 하는 $Rh/CeO_2$ 촉매에서 가장 우수한 $N_2O$ 분해활성을 나타내었다. 특히 일정한 소성조건($500^{\circ}C$-4 hr)에서 $Rh/CeO_2$ 촉매를 제조하였을 때 가장 우수한 활성을 나타내었다. 또한 촉매의 특성이 $N_2O$ 분해 반응에 미치는 영향을 확인하고자 $H_2-TPR$ 및 XPS 분석을 수행하였다. 실험결과, 촉매의 redox 특성증진과 $Ce^{3+}$의 비율이 증가함에 따른 촉매의 산소전달능력의 증진이 $N_2O$ 분해반응에 영향을 주는 것으로 확인되었다. 또한, $N_2O$와 NO가 동시에 발생하는 조건에서 $N_2O$ 분해 반응특성과, $N_2O$와 NO를 동시에 처리 가능한 공정에 대하여 연구하고자 한다.

• 한국전기전자재료학회논문지
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• 제27권8호
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• pp.528-534
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• 2014

Thermal batteries are primary reserve batteries that use inorganic salt as electrolytes which are inactive at room temperature. The two principal heat sources that have been used in thermal batteries are heat paper and heat pellets. As soon as the heat paper, which is ignited by the initiator, in turn ignites the heat pellets, all the solid electrolytes are melted into excellent ionic conductors. However, the high combustion temperature by heat papers in thermal batteries causes thermal decomposition at the cathode, eventually leading to a thermal runaway. In this paper, we have attempted to prepare $Zr/BaCrO_4$ heat papers coated with KCl molten salt. We have also investigated the effect of a molten salt coating on the heat papers through the thermal characteristics such as calorimetric value, combustion temperature and burning rate. The calorimetric value and combustion temperature of heat papers were reduced with an increase in the molten salt coating. As a result, the molten salt coating on heat papers greatly reduced risk of a thermal runaway and improved the stability of thermal batteries.

• 한국분말재료학회지
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• 제12권1호
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• pp.36-42
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• 2005

Four different mechanical alloying(MA) processes were employed to fabricate very fine intermetallic compound $Al_3Zr$ particles dispersed Al composite materials(MMC) with Al-4at.%Zr composition. Phase transformations including phase stability during MA and heat treatment processes were investigated. Part of Zr atoms were dissolved into Al matrix and part of them reacted with hydrogen produced by decomposition of PCA(methanol) to form hydride $ZrH_2$ during first MA process. These $ZrH_2$ hydrides disappeared when alloy powders were heat treated at $500^{\circC}$. Stable $Al_3Zr$ dispersoids with $DO_23$ structure were formed by heat treating the mechanically alloyed powders at $400^{\circC}$. On the other hand, metastable $Al_3Zr$dispersoids with $L1_2$ structure were formed during first MA of powers with Al-25at.%Zr composition. These metastable $Al_3Zr$ dispersoids transformed to stable $Al_3Zr$ with $DO_23$ structure when heat treated above $450^{\circC}$.

• 한국응용과학기술학회지
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• 제20권4호
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• pp.353-357
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• 2003

Sodium azide (SA) is commonly used as propellant for inflating automatic safety bags and other chemical manufacturing purposes. The investigation of potentially thermal hazard of sodium azide and its mixture with polymers are very important because it can occur an expected traffic accident so we took a experiment s using different scanning calorimeter (DSC) in nitrogen atmosphere. The decomposition temperature were about $350{\sim}450^{\circ}C$. We could find not only exothermic reaction was remarkably decreased in mixture s of acrylonitrile-butadiene-styrene (ABS) and polyvinyl chloride (PVC), but also increasing mixed rate of ABS, polyvinyl alcohol (PVA) and polymethyl methacrylate (PMMA) decreased thermal decomposition heat.

• 한국표면공학회지
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• 제32권6호
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• pp.686-694
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• 1999

Insoluble anodes of the Ta/Ir mixed metal oxide for electrodeposition of Ni-W alloy in ammoniacal citrate bath were prepared by thermal decomposition method. Ti plate was etched in boiling oxalic acid solution and coated with ethanol solution of $TaCl_{5}$ and $IrCl_4$ mixed in a fixed ratio, followed by drying and treating at various temperatures. The coating layer of these insoluble anode was characterized by SEM, EDX, XRD and DSC. The decomposition rate of citric acid in plating bath was determined by measuring the $CO_2$ gas evolved at the anodes with Gas Chromatography. Evolution of $CO_2$ gas from Ta/Ir oxide anodes decreased about 5% compared with that of Pt. The $CO_2$ gas evolution was increased with the amount of Ir-oxide in the coatings. The coatings which have more than 40% ratio of Ta content and heat-treated at the temperature higher than $400^{\circ}C$ showed better efficiency

• Journal of Pharmaceutical Investigation
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• 제20권3호
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• pp.145-152
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• 1990

Zirconium pyrithione complex was prepared by reaction of sodium-pyrithione solution and zirconyl chloride solution. The physico-chemical properties of the complex was examined by means of IR, XRD, DSC and NMR. And the stability of Zr-complex was investigated on the basis of accelerated stability analysis under conditions of temp. elevation, UV radiation and pH dependence. The result indicates that the ratio of the ligand to metal in Zr-pyrithione complex was determined 4:1, and its stability constant was $4.643{\times}10^4$. The rate order of decomposition of the complex was apparent first-order reaction of which rate constant and the decomposition rate was not only accelerated by effect of heat and UV radiation but was catalyzed by specific acid-base catalysis considered the pH dependence for the hydrolysis of the complex and the suspension was most stable over the range pH 4-8 indicating that solvent catalysis is the primary made of reaction in this region.

• Journal of Advanced Marine Engineering and Technology
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• 제23권5호
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• pp.671-677
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• 1999

This study has been performed to investigate REW(relative electrode wear) in condition of vari-ous pulse-on duration using the copper and graphite electrode with change of the electrode size on the heat treated STD11 which is extensively used for metallic molding steel with the EDM. The results obtained are as follows; a) Graphite has much benefits than copper electrode when rapid machining is done without electrode wear, b) Neative REW result from the electrode that is very liable attach to decomposition carbide c)Increasing of machining time cause to increase wear length of the copper electrode and decrease wear length of the graphite electorde d)The more pulse-on duration copper electrode has the less REW. e) The edge portion of the electorde wears remarkably at the beginning of machining,.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2010년도 제34회 춘계학술대회논문집
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• pp.113-122
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• 2010

고체추진기관의 연소 환경에서 복잡한 형상을 갖는 내열 복합재료의 온도, 밀도분포 및 삭마두께를 예측할 수 있는 방법을 개발하였다. 복합재료의 내부 열반응은 Arrhenius 모델을 이용하였으며, 표면 삭마반응은 Zvyagin 이론을 사용하였다. 표면 삭마에 의한 경계조건 및 격자 이동은 상용해석 코드에서 활용되는 Rezoning-remeshing 기법을 사용하였다. 형상이 복잡한 부품으로 이루어진 2차원 축대칭 노즐 조립체에 적용된 방법은 향후 3차원 FEM 열구조 해석에 활용을 목표로 발전될 것이다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
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• pp.107-108
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• 2015

The acoustic optimization of a swirl coaxial jet injector mounted upstream a combustion chamber is investigated to tackle combustion instabilities. The least damped modes are extracted with the help of the dynamic mode decomposition (DMD). The sensitivity of the heat release perturbation to the velocity perturbation for the second longitudinal mode is investigated by combining the Crocco's equation and the inhomogeneous wave equation and computing the flame transfer function (FTF). DMD and FTF results agree in terms of the optimized injector length.