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Oxidation of Geosmin and 2-MIB in Water Using $O_3/H_2O_2$: Kinetic Evaluation (오존과 과산화수소를 이용한 Geosmin과 2-MIB 산화: 동력학적 평가)

  • Lee, Hwa-Ja;Son, Hee-Jong;Roh, Jae-Soon;Lee, Sang-Won;Ji, Ki-Won;Yoo, Pyung-Jong;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.7
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    • pp.826-832
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    • 2007
  • Unpleasant tastes and odors in drinking water cause same problems for water utilities across Korea. Even though tastes and odors do not create health problems, they are main concerns for consumers who determine the safety of their drinking water. In this study, two different odor producing compounds(geosmin 2-MIB) in the Nakdong river water and rapid sand filtered rater were treated by advanced oxidation of $O_3/H_2O_2$ process. The experimental results showed that the removal efficiency of geosmin with the use of 5 mg/L of $O_3$ and $H_2O_2$ was higher than efficiency with the use of $O_3$ alone for both the raw water and the sand filtered water. And in general, the removal efficiency of geosmin was higher than 2-MIB in the sand filtered water. Under the range of $O_3$ concentration $0.5\sim2.0$ mg/L, the removal rate constants(k) of geosmin for the raw and sand filtered waters, and the one of 2-MIB in the sand filtered water were increased rapidly as doses of $O_3$, and $H_2O_2$, increased. The removal rate constants(k) do not increase any more when $H_2O_2/O_3$ ratio increases above the optimum ratio. The optimum ratio of $H_2O_2/O_3$, dose was $1.0\sim2.0$ for both geosmin and 2-MIB. The removal rate constant(k) becomes lower when OH radical consuming materials are present in raw water. The half-life of geosmin decreased rapidly as the $O_3$ and $H_2O_2$ doses increase in the sand filtered water. The half life decreased about 8.5 times with the use of 2 mg/L of $O_3$ and 10 mg/L of $H_2O_2$ than with the use of 2 mg/L of $O_3$ alone for the sand filtered water.

Removal of Odorous Compounds Using Ozone and Hydrogen Peroxide (오존과 과산화수소를 이용한 이취미 물질 산화 제거)

  • Lee, Hwa-Ja;Son, Hee-Jong;Roh, Jae-Soon;Lee, Sang-Won;Ji, Ki-Won;Yu, Pyung-Jong;Kang, Lim-Seog
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.12
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    • pp.1323-1330
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    • 2006
  • In this study, five different odor causing compounds in the Nakdong river and rapid sand filtered waters were treated by oxidation from $O_3/H_2O_2$ process. In addition, the change in BDOC formation by the $O_3/H_2O_2$ process was also investigated for considering this advanced oxidation Process as a pre-treatment to the BAC treatment process. The experimental result showed that the removal efficiency of geosmin was higher with the use of 5 mg/L of $O_3$ and 0.2 mg/L of $H_2O_2$ than with the use of 20 mg/L of $O_3$ alone for the sand filtered water. And in general, the removal efficiency of geosmin in raw water was $12{\sim}27%$ lower than the one in sand filtered water. In sand filtered water. the removal efficiencies of geosmin and IPMP decreased when $H_2O_2/O_3$ ratio increases above the optimum ratio. The optimum ratio of $H_2O_2/O_3$ dose was $0.5{\sim}1.0$ for geosmin and $0.2{\sim}1.0$ for IPMP. However, the optimum ratio of $H_2O_2/O_3$ in raw water remove geosmin appealed to $1.0{\sim}3.0$. According to the experimental results for the removal of 5 different odor causing compounds under varied $O_3$ doses, the removal efficiency of IPMP was the highest with 60% and, in overall, $O_3/H_2O_2$ process showed higher removal efficiency than $O_3$ alone process. The BDOC formation by the $O_3/H_2O_2$ process increased from $0.1{\sim}0.25$ to $0.19{\sim}0.34$ comparing to $O_3$ process alone. Therefore, it is concluded that the advanced oxidation process with $O_3/H_2O_2$ can be used as a pretreatment to the BAC treatment process.

Study on the unification between KS I ISO standard and official test method enacted by Korean Ministry of Environment - drinking water and indoor air quality - (환경오염공정시험기준과 KS ISO규격의 일원화에 관한 연구 - 먹는 물 및 실내공기질 -)

  • Lee, Jeong-Il;Lee, Ju-Hee;Lee, Jeong-Hee;Lee, Jun-Hee;Lee, Won-Seok;Kim, Ji-In;Kim, Bo-Kyung;Choi, Sung-Hun
    • Analytical Science and Technology
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    • v.25 no.2
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    • pp.102-113
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    • 2012
  • Our study researched on unification of KS I ISO standard harmonized with ISO and Official Test Method enacted by Korean Ministry of Environment-drinking water and indoor air quality. We reviewed KS methods related to drinking water and indoor air quality for about 23,000 KS methods. KS methods related environmental field are classified as KS I, total 635 methods and 583 KS I methods were harmonized with ISO. For Environmental Standard methods for drinking water, 100 methods were reviewed according to 232 KS methods related to ISO/ TC 147 "Water Quality". Environmental Standard methods for indoor air quality were reviewed according to 95 KS standard methods related to ISO/TC 146 "Air Quality". By reviews and comparison tests for unifiable ES for drinking water and indoor air quality with KS methods harmonized with ISO, it was evaluated that for 100 ES methods for drinking water, 23 ES methods were unification complete, 29 ES methods were unification possible, 12 ES methods were unification impossible, no corresponding methods were found in KS I ISO for 36 ES methods and for 17 ES methods for indoor air quality,1 ES methods were unification complete, 3 ES methods were unification possible, 3 ES methods were impossible, no corresponding methods were found in KS I ISO for 10 ES methods.

해외연구소의 효과적 운영에 대한 기존 연구 및 사례를 통한 탐색적 연구

  • 김영배;이대우
    • Proceedings of the Technology Innovation Conference
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    • 1996.12a
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    • pp.27-62
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    • 1996
  • As an exploratory attempt, this study examines the patterns of global R&D activities of industrial firms, focusing on the management of overseas R&D centers in terms of their location, primary missions, management style, organizational structure and communication and global human resource management system Based on a review of existing studies mainly undertaken in advanced countries and cases of foreign MNCs, several hypothetical relationships are postulated : 1) There appears a strong relationship between the purpose and location of R&D activities : 2) Different levels of global management and technological capability lead to different types of overseas R&D organizations : 3) The relationship between autonomy of overseas R&D organizations and their R&D performance will be moderated by organization size, development time pressure, and a need for internal efficiency : 4) Frequent communication between the headquarter and overseas R&D organizations will increase R&D performance 5) Mutual exchange of R&D professionals between the headquarter and overseas R&D organizations will be positively related with R&B performance. In addiction, this study explores the current state of global R&D activities of selective firms in Korea, based on ie-depth interviews, and analyzes the sources of problems in their global R&D management. Finally, theoretical and managerial implications of this study are discussed and future research directions are proposed.

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A Study on Efficient Improvement Method of Rainwater Utilization Facilities in Jeju Island (제주지역 빗물이용시설의 효율적 개선방안 연구)

  • Park, Won-Bae;Moon, Deok-Cheol;Koh, Gi Won
    • Journal of Soil and Groundwater Environment
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    • v.17 no.6
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    • pp.1-8
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    • 2012
  • This study is to suggest a few efficient ways of rainwater utilization, through monitoring and analyzing 143 rainwater storage systems and 110 artificial recharge systems, which are installed in the recommended facilities by law, among the rainwater harvesting systems in Jeju Island. In the case that catchment facilities are damaged, rainwater could be contaminated by leaves and debris so that the rates of rainwater usages come to be lower. It is possible that contaminated rainwater could contaminate artificial recharge wells or rainwater discharging out of the rainwater harvesting system could result in flood and damage for the downgradient area. For maintaining high quality of rainwater and increasing rainwater utilization rate, it is necessary to install screening facilities and purification plant functioning precipitation and filtration. Also, in order to efficiently preclude the overflowing rainwater exceeding storage capacity, it is recommended to associate rainwater storage tanks with artificial recharge well or infiltration trench facilities.

A Case of Seismic Crosshole Tomography Applying Borehole Deviation Correction (시추공 편차 보정을 적용한 탄성파시추공토모그래피 사례)

  • Kang, Jong-Seok;Cha, Young-Ho;Jo, Churl-Hyun;Choi, Jong-Ho;Shim, Weon-Hum;Park, Yong-Sung
    • 한국지구물리탐사학회:학술대회논문집
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    • 2006.06a
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    • pp.221-224
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    • 2006
  • seismic crosshole tomography works applying borehole deviation correction were performed at a test site to detect a small cavity. Two correction methods were applied. The one is the constant distance correction which adds constant distance to surface borehole distance and the other is the constant angle correction which considers an angle between surface borehole location and bottom borehole location. After applying the corrections, the distortions of the image diminished while its resolution improved. Though the constant angle correction is the most appropriate correction method, the constant distance correction can delineate the small cavity sufficiently.

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Thermal Shock Durability Test of a Gasoline Turbocharger Waste Gate Valve Assembly Manufactured by a Metal Injection Molding (금속분말사출성형공법을 이용한 가솔린 터보차저의 웨이스트 게이트 밸브 어셈블리 열 충격 내구 시험)

  • Nam, Chungwoo;Han, Manbae;Chun, Bongsu;Shin, Jaesik;Kim, Jongha;Min, Doosik
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.13 no.4
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    • pp.69-74
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    • 2014
  • A waste gate valve (WGV) assembly for a gasoline turbocharger is typically manufactured by means of precision casting. In this study, however, it was newly manufactured in a more innovative way, metal injection molding (MIM) using Inconel 713C alloy, and its performance was tested in a 1.6L direct injection gasoline engine by a thermal shock durability test that lasted 300 hours, after which the results were compared to those of a precision-cast WGV assembly with regard to the engine intake boost pressure, turbine wheel speed, and transient intake pressure. It was found that the two WGV assemblies showed similar performance levels throughout the durability test.

An Evaluation of Critical Speed for Draft Gear using Variable Formation EMU (도시철도차량의 가변편성을 고려한 고무완충기의 임계속도 평가)

  • Cho, Jeong Gil;Kim, Y.W.;Han, J.H.;Choi, J.K.;Seo, K.S.;Koo, J.S.
    • Journal of the Korean Society of Safety
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    • v.34 no.5
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    • pp.139-143
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    • 2019
  • In this study, we tried to derive the most severe scenario and its critical speed by 1-D collision simulation with a variable formation vehicle in order to prepare for the change of demand in Seoul Metropolitan Subway Line 3, which is operated by fixed arrangement. After establishing various collision scenario conditions, the friction coefficient between the wheel and the rail was evaluated as 0.3, which is considered to be severe. As a result of analysis according to all scenarios, the most severe scenario conditions were confirmed by comparing rubber shock absorber performance and vehicle collision deceleration. In addition, a typical wheel-rail friction coefficient was derived through accident cases, and the analysis was performed again and compared. Finally, the criterion of the critical speed in the condition of the friction coefficient of the normal wheel - rail condition was confirmed.