• Title/Summary/Keyword: hazardous waste

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Improvement of DeNOx efficiency of SNCR Process with Chemical Additives in Urea Soution (환원제로 우레아를 사용하는 SNCR 공정에서 첨가제 적용에 따른 탈질효율 향상 연구)

  • Yoo, Kyung Seun;Park, Sung Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.10
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    • pp.663-668
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    • 2017
  • Dye waste water generated in the dye industry is categorized as hazardous waste water that requires appropriate treatment. The pilot scale experimental trials were carried out using dye waste water as an effective additive for the selective non-catalytic reduction (SNCR) of NOx in combustion flue gases. The additives were waste liquor obtained from the dye industry and several purification steps were taken to make a standardized reagents. The dye waste water was shown to possess valuable SNCR qualities (at least 87% NOx reduction efficiency) considering its availability as a waste product, which has to be strictly treated, and have little effects on CO removal. The results indicated that the NO removal efficiency increased first and then decreased with increasing temperature within $750-1150^{\circ}C$. The maximum NO reduction efficiency was approximately 87% at the optimal reaction temperature. A more than 10% increase in NO reduction was achieved in the presence of 1000 ppm Na-additives (dye waste water) compared to that without additives. The Na-based additives have also a significant promoting effect on $N_2O$ reduction and within the SNCR temperature window.

Condensation and coagulation of metallic species with fly ash particles in a waste incinerator (폐기물 소각시 생성되는 유해 중금속물질과 연소실내 비산재와의 응축, 응집 현상에 대한 연구)

  • Yu, Ju-Hyeon;Hwang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.2
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    • pp.264-274
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    • 1997
  • A numerical analysis on condensation and coagulation of the metallic species with fly ash particles pre-existing in an incinerator was performed. Waste was simplified as a mixture of methane, chlorine, and small amounts of Pb and Sn. Vapor-phase amounts of Pb- and Sn -compounds were first calculated assuming a thermodynamic equilibrium state. Then theories on vapor-to-particle conversion, vapor condensation onto the fly ash particles, and particle-particle interaction were examined and incorporated into equations of aerosol dynamics and vapor continuity. It was assumed that the particles followed a log-normal size distribution and thus a moment model was developed in order to predict the particle concentration and the particle size distribution simultaneously. Distributions of metallic vapor concentration (or vapor pressure) were also obtained. Temperature drop rate of combustion gas, fly ash concentration and its size were selected as parameters influencing the discharged amount of metallic species. In general, the coagulation between the newly formed metal particles and the fly ash particles was much greater than that between the metal particles themselves or between the fly ash particles themselves. It was also found that the amount of metallic species discharged into the atmosphere was increased due to coagulation. While most of PbO vapors produced from the combustion were eliminated due to combined effect of condensation and coagulation, the highly volatile species, PbCl$_{2}$ and SnCl$_{4}$ vapors tended to discharge into the atmosphere without experiencing either the condensation or the coagulation. For Sn vapors the tendency was between that of PbO vapors and that of PbCl$_{2}$ or SnCl$_{4}$. To restrain the discharged amount of hazardous metallic species, the coagulation should be restrained, the number concentration and the size of pre-existing fly ash particles should be increased, and the temperature drop rate of combustion gas should be kept low.

Fiber Analysis and Environmental Assessment of Recycled Waste paper for Eco-friendly Corrugated Box Manufacture (친환경 골판지 상자 제조를 위한 재활용 폐지 섬유의 물리적·환경적 특성 평가)

  • Park, Jung-Yoon;Lee, Tai-Ju;Kim, Hyoung-Jin;Kim, Jin-Mu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.4
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    • pp.65-74
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    • 2013
  • In the manufacture of corrugated box, the fibrous raw materials are mainly consisted of recycled papers, such as KOCC(Korean Old Corrugated Container), kraft sack, and AOCC(American Old Corrugated Container). Among these recycled waste paper, the proportion of KOCC is relatively higher than others in fibrous raw materials. Generally, KOCC shows some poor fiber properties and contains hazardous heavy metal sources. Therefore, it is to evaluate the property of recycled paper sources for eco-friendly corrugated box manufacture. In this study, the physical and mechanical properties of 3 kinds of recycled fibers and their mixed stocks were analyzed. The environmental assessment was also evaluated by analyzing the 4 representative heavy metal contents and evaporation residues in waste papers. As the results, KOCC showed the poorest fiber qualities and had the highest heavy metal contents and evaporation residues among the recycled fibers. Finally, the mechanical strength properties were increased by decreasing KOCC proportion of mixed stock conditions. In addition, the heavy metal contents and evaporation residues were also decreased by increasing recycled AOCC and kraft sack proportion.

Effect of accelerators with waste material on the properties of cement paste and mortar

  • Devi, Kiran;Saini, Babita;Aggarwal, Paratibha
    • Computers and Concrete
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    • v.22 no.2
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    • pp.153-159
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    • 2018
  • Accelerators are used to speed up the construction by accelerating the setting time which helps in early removal of formwork thus leading to faster construction rate. Admixtures are used in mortar and concrete during or after mixing to improve certain properties of material which cannot be achieved in conventional cement mortar and concrete. The various industrial by products make nuisance and are hazardous to ecosystem as well. These wastes can be used in the construction industries to reduce the consumption of cement/aggregates, cost; and save the energy and environment by utilising waste and eliminate their disposal problem as well. The effect of calcium nitrate and triethanolamine (TEA) as accelerators and marble powder (MP) as waste material on the various properties of cement paste and mortar has been studied in the present work. The replacement ratio of MP was 0-10% @ 2.5% by weight of cement. The addition of calcium nitrate was 0% and 1%; and variation of addition of TEA was 0-0.1@ 0.025% and 0.1-1.0@ 0.1% by weight of cement. On the basis of setting time, some mix proportions were selected and further investigated. Setting time and soundness of cement paste; compressive strength and microstructure of mortar mix of selected mix proportions were studied experimentally at 3, 7 and 28 days aging. Results showed that use of MP, calcium nitrate, TEA and their combination reduced setting time of cement paste for all the mixes. Addition of calcium nitrate increased the compressive strength at all curing ages while MP and TEA decreased the compressive strength. The mechanism of additives was discussed through scanning electron microscope (SEM) and energy dispersive X-ray spectroscopy (EDS) analysis of the specimens.

Physicochemical Effect on Ultra Thermophilic Aerobic Composting Process (초고온 호기성 퇴비화의 물리·화학적 인자 평가)

  • Park, Seyong;Yoo, Euisang;Chung, Daihyuck;Lee, Jin;Kim, Moonil
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.11
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    • pp.27-36
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    • 2010
  • This study was conducted to evaluate physicochemical parameters; temperature, pH, C/N ratio, water content, organic contents and volume in a pilot-scale(capacity : $100m^3$) ultra thermophilic aerobic composting. There were three types input: municipal wasted sludge, livestock manure and slurry, and food waste produced in Jung-Eb city. Each target material was carried out by the first fermentation(organic waste + seed culture) and the second one(organic waste + seed culture + recycle compost), respectively. During composting, only with supply of air and mixing, the temperature increased $90{\sim}105^{\circ}C$ after every mixing in both periods. The changes of pH, $O_2$, $CO_2$ and $NH_3$ represented typical organic decomposition pattern by microorganisms. Also, all other physicochemical parameters of ultra thermophilic aerobic composting process showed similar or better performance than these of general aerobic composting. Heavy metal concentration of fermented compost adapted to compost fertilizer regulation standard in the heavy metal and hazardous analysis.

Health Risk Related to Waste Incineration (폐기물 소각시설에 의한 주민 건강 영향)

  • Choi, Young-Sook;Ochirpurev, Bolormaa;Chae, Hee-Yun;Eom, Sang-Yong;Kim, Yong-Dae;Kim, Heon
    • Journal of Environmental Health Sciences
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    • v.47 no.1
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    • pp.20-35
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    • 2021
  • Objectives: Waste treatment by incineration is gradually increasing as the emission of harmful substances has decreased owing to developments in incineration technology. However, residents living near incinerators continue to express anxiety regarding the effects on their health. Therefore, we attempted to summarize the health impact of incinerators by comprehensively reviewing the recently reported literature. Methods: Sixty-two epidemiological research papers related to incineration and health effects were selected from the Google Scholar database and analyzed (from between January 2001 and December 2019). Results: When compared to older incinerators, newer incinerators established after 2000 are considered relatively safe in terms of health effects. Nevertheless, there have been some studies that have linked them to various diseases, such as malignant tumors including soft tissue cancer and non-Hodgkin's lymphoma, reproductive disorders, respiratory diseases, and more. In addition, incinerator workers and local residents are considered to be exposed to dioxins and some heavy metals from the incinerator. Since most studies included subjects exposed to older incinerators, it is difficult to apply these results to the health impact assessment of new incinerators. However, it is not appropriate to conclude that new incinerators made with state-of-the-art technology are safe, as chronic environmental diseases caused by hazardous substances tend to appear only after prolonged exposure. Conclusions: In terms of environmental health, it is necessary to continuously monitor the health effects of incinerators. Also, there is a need to develop a research methodology that can minimize various confounders in incineration-related epidemiological study.

Output Control Simulation of Variable Speed Wind Power System using Real Data (실제 데이터를 이용한 가변속 풍력발전시스템의 출력제어 시뮬레이션)

  • Han, Sang-Geun;Park, Min-Won;Yu, In-Keun
    • Proceedings of the KIEE Conference
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    • 2002.07b
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    • pp.1342-1344
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    • 2002
  • Wind is a significant and valuable renewable energy resource. It is safe and abundant and can make an important contribution to future clean, sustainable and diversified electricity supplies. Unlike other sources of energy, wind does not pollute the atmosphere nor create any hazardous waste. In some countries wind energy is already competitive with fossil and nuclear power even without accounting for the environmental benefits of wind power. The cost of electricity from conventional power stations does not usually take full account of its environmental impact (acid rain, oil slick clean up, the effects of climate change, etc). In this paper, a transient phenomenon simulation method for Wind Power Generation System(WPGS) under real weather conditions has been proposed. The simulation method is expected to be able to analyze easily under various conditions with considering the sort of wind turbine, the capacity of system and the converter system. Wind turbine connected to the synchronous generator and power converter was simulated.

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A study on the Concentrations of Sulfur compounds using a GC/FPD from Industrial Hazardous Waste Incinerators. (GC/FPD를 이용한 산업폐기물 소각시설의 황 화합물 농도분포특성 연구)

  • 김덕현;유병대;김완중;김선태;박민수;전의찬;박종호
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.279-280
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    • 2003
  • 환경부에서 발표한 2001년도 사업장 배출시설계 폐기물 발생현황을 보면 소각에 의한 처리량이 1995년도에 5,691톤/일에서 2001년도에 7,875톤/일로 꾸준히 증가하는 추세를 보이고 있다(환경부 2001). 이러한 산업폐기물 소각장에서 발생하는 유해오염물질은 매우 다양하다. 그 중 최근 사회적 이슈로 떠오르는 것이 악취이다. 악취는 황화수소ㆍ메르캅탄류 아민류 등 기타 자극성 있는 기체상 물질이 사람의 후각을 자극하여 불쾌감과 혐오감을 주는 냄새로, 주로 인체 위해성 보다는 정신적ㆍ심리적 피해를 끼치는 감각공해이다(환경부, 2000). (중략)

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Solidification/stabilization of Hazardous Wastes Using Cementitious Materials(III) (특수시멘트 고형화재를 이용한 지정폐기물의 고형화/안정화(III))

  • Lim, Chae-Yong;Ku, Ki-Dae;Um, Tae-Sun;Lee, Jong-Ryul;Choi, Long;Oh, Byoung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.289-294
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    • 2001
  • This study concerns the cement-solidification/stabilization of the waste with high concentration heavy metals. Compressive strength and leaching test of heavy metals were evaluated for ing types of cements and the effect of the additives of Hauyne clinker and slag were also cussed. Using ordinary portland cement, rapid hardening portland cement and the cement with additives solidification materials, it shows that the strength and stability of concrete is satisfactory and superiority is in the order of rapid hardening portland cement > the cement with additives > nary portland cements.

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Dyeing of Natural Fibers with Extract of Ginkgo biloba Bark(I) - Pigments Analysis and Dyeability - (은행나무 수피 추출액에 의한 천연섬유의 염색( I ) -색소분석 및 염착성-)

  • 최순화;조용석
    • Textile Coloration and Finishing
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    • v.13 no.5
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    • pp.306-311
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    • 2001
  • Natural colorants haute attracted much attention all over the world because of their non-hazardous nature. The world is becoming increasingly aware of environmental Issues, such as ozone layer depletion, water pollution and waste disposal problems. The use of synthetic dyestuffs for their synthesis and application in the dyeing industries has been criticized due to introduction of contaminants into the environment. This has led to the desire to turn to the traditional, and more natural way of life. In this study, the colorants of extract of Ginkgo biloba bark were analysed and their dyeing properties on silk, wool and cotton were studied. It was found that uv-visible absorption spectra of extract of Ginkgo biloba bark showed two strong absorption Peaks in the range of 240 ∼400 In. From the result of IR spectra, the major ingredient of extract of Gikgo biloba bark seems to be the flavon which is one of the flavonoid derivatives. Silk, wool, and cotton dyed with the extract of Ginkgo biloba bark showed a reddish yellow color. Their color differences were increased drastically with repetition of dyeing by three times.

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