• Title/Summary/Keyword: hazardous substances discharge

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The development of discharge reactor for water purification and the fundamental study on the change of water characteristics (수질 개선용 방전 리액터의 개발과 기본적 수질 특성 변화 조사)

  • Han, Sang-Bo;Park, Jae-Youn;Kim, Jong-Seog;Jung, Jang-Gun;Koh, Hee-Seog;Lee, Hyun-Woo
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2193-2195
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    • 2005
  • The hybrid discharge reactor was designed for the application of wastewater treatment and the removal of hazardous volatile organic substances in water. This discharge type was similar to the barrier discharge, and the surface discharge on the dielectric surface was propagated to the water surface. That caused the heterogeneous chemical reaction strongly at the interface between the working gases and the water surface. Changes of the conductivity, acidity, and the dissolved ozone with respect to the treatment time and water quantities were studied as the fundamental experiment. The concentration of hydrogen ions largely increased with increasing the treatment time and the conductivity increased with respect to the increase of water quantities under the constant other discharge parameters.

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Electrochemical Disinfection for Ballast Water Treatment (발라스트수 처리를 위한 전기화학적 살균처리)

  • Seo, Won-Hak;Jeon, Sun-Ae;Kim, Ji-Hyun;Lee, Tae-Ho;Sang, Byoung-In
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1162-1167
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    • 2006
  • The discharge of ballast water from the marine vessel without proper treatment causes the ecological disruption. Therefore, International Marine Organization(IMO) has the plan to force the proper treatment of ballast water before its discharge to open sea. To satisfy the IMO's criteria, several processes such as filtration, UV irradiation, and ozonation etc., were introduced. Since the disinfection of ballast water should be conducted within very short hydrolic retention time, electrochemical treatment can be a promissing process. The DSA(dimensional stable anode) electrode for the electrochemical treatment was prepared by thermal deposition method. The disinfection rate of microorganisms increased with the increasing current density and reaction time under low pH condition. The morphology of sterilized microorganisms was shown by SEM and Microscopy.

Characteristics of hazardous oil & liquid fuel waste discharged from various industries (폐유 및 액상연료 공정 폐기물에서 무기물질류의 함량특성)

  • Shin, Sun-Kyoung;Jeong, Seong-Kyeong;Kim, Woo-Il;Jeon, Tae-Wan;Kang, Young-Yeul;Yeon, Jin-Mo;Cho, Yoon-A;Kim, Min-Sun
    • Analytical Science and Technology
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    • v.26 no.4
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    • pp.276-286
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    • 2013
  • This study was performed to investigate the contents characteristics of hazardous oil wastes and wastes of liquid fuels from different industrial process. In order to establish a hazardous waste list, samples of various industrial discharge have been analyzed for 16 non-regulated inorganic hazardous substances (i.e., Cu, Pb, Cd, CN, Hg, As, T-Cr, $Cr^{6+}$, Sb, Ni, F, V, Ba, Zn, Be, Se). In more detail, hazardous waste samples including waste hydraulic oils, waste engine, gear and lubricating oils, waste insulating and heat transmission oils, bilge oils, oil/water separator contents processing were collected from 37 workplaces and analyzed. We observed that the most of the inorganic substances exceeded the proposed criteria in many samples. Especially the concentration of Sb in heat transmission oil, bilge oil and gear & lubricating oils were ranged from 6 to 419 mg/kg whereas the proposed criteria is 50 mg/kg. The assessment result of hazardous waste in Korea according to the EWC showed that the out of 24 processes, 16 belongs to absolute entry and 8 belongs to mirror entry. In conclusion, we expect the outcome of this study to align the classification system of hazardous waste management in South Korea with international legislations, and consequently contribute to reduce environmental pollution as well as health risks by toxic wastes.

A Study on Prevention of Explosion Accidents by Complex Treatment Methods in Semiconductor Exhaust Process (반도체 배기 공정에서 복합 처리 방식으로 인한 폭발 사고 예방대책에 관한 연구)

  • Choi, Se Wook;Lee, Dae Joon;Kim, Sang Ryung;Kim, Sang Gil;Jeong, Jeong Hee;Yang, Won Baek
    • Journal of the Korean Institute of Gas
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    • v.26 no.5
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    • pp.28-34
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    • 2022
  • Since semiconductor factories are located in densely populated areas, safe handling of hazardous materials handled in the manufacturing process is of utmost importance. In particular, the types of hazardous substances discharged after handling in the semiconductor manufacturing process are very diverse, and the treatment methods such as combustion, absorption and adsorption methods for each material are very complicated. Therefore, in recent semiconductor exhaust treatment processes, two or more treatment methods are applied to one treatment facility, and unexpected accidents occur due to the application of such a complex treatment method. In this study, the cause of accidents in treatment facilities that applied both the scrubber method and the electrostatic precipitation method, which are recent accident cases, are identified, and preventive measures are suggested to find out the points to be noted when applying the complex treatment method.

The development of the discharge reactor for water purification and a spectroscopic study on its discharge emission (수처리용 방전 리액터의 개발과 방전 발광의 분광학적 분석 연구)

  • Han, Sang-Bo;Park, Jae-Youn;Kim, Jong-Seog;Jung, Jang-Gun;Koh, Hee-Seog;Park, Sang-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.581-582
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    • 2005
  • In order to apply the discharge plasma processing. to industrial areas, the control of the chemical reaction mechanism is necessary. The hybrid plasma reactor was designed for the effective treatment of wastewater and hazardous volatile organic substances. This plasma reactor was similar to the barrier discharge, and surface discharge on the dielectric surface was propagated to the water surface strongly for the heterogeneous chemical reaction at the interface between the working gas and the water surface. The discharge emission in this discharge reactor was mainly $N_2$ second positive band in the case of $N_2$ or air gas atmosphere, and intensities from OH radicals in Ar gas atmosphere were stronger than in $N_2$ or air gas atmosphere. From this result, it is necessary to apply Ar gas for the effective generation of OH radicals in this plasma reactor.

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Evaluation of Physical, Mechanical Properties and Pollutant Emissions of Wood-Magnesium Laminated Board (WML Board) for Interior Finishing Materials

  • PARK, Hee-Jun;JO, Seok-Un
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.1
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    • pp.86-94
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    • 2020
  • This study serves as basic research for the development of a new wood-based building finishing material that improved the weakness of inorganic materials such as gypsum board and magnesium board widely used as interior finishing materials and brought out the strength of the wood. The results of evaluating the physical and mechanical properties and the environmental effect related to hazardous substance discharge having manufactured a wood-magnesium laminated composite are as follows. The thermal conductivity and thermal resistance of WML board was improved by about 28~109 percent over magnesium board due to the low thermal conductivity of wood. The adhesive strength of WML board showed a similar result to that of plywood as it exceeds 0.7N/㎟, the adhesive standard of wood veneer which is presented by KS F 3101. Bending strength and screw holding strength were more improved by manufacturing WML board than magnesium board. The WML board manufactured in this study satisfied the criteria for emissions of hazardous substances prescribed in the Indoor Air Quality Control Act, and confirmed the possibility of development as a new wood-based composite material that can replace existing inorganic materials.

Study on Discharge Characteristics of Water Pollutants among Industrial Wastewater per Industrial Classification and the Probability Evaluation (업종별 산업폐수중 수질오염물질 배출 특성 및 개연성 평가 연구)

  • Ahn, Tae-ung;Kim, Won-ky;Son, Dae-hee;Yeom, Ick-tae;Kim, Jae-hoon;Yu, Soon-ju
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.1
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    • pp.14-24
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    • 2016
  • Information on the lists of pollutants from industrial wastewater discharge are essential not only to specify the key pollutants to be managed in permission process but to design the treatment facilities by the dischargers. In this study, wastewater quality analysis was conducted for three industrial categories including the specified hazardous water pollutants. The general description of the wastewater occurrence, major sources, treatment facilities are also investigated to obtain integrated database on the pollutant inventories for the industrial categories. In addition Based on the analysis of raw wastewater and final effluent, the detected pollutant items are confirmed by analyzing their presence in the raw or supplement materials, the potential of formation as byproducts, and the possibility of inclusion as impurities. The three industrial categories include petrochemical basic compounds, basic organic compounds, and thermal power generation. The water pollutants emitted from petrochemical basic compound manufacturing facilities are 31 items including 16 specified hazardous water pollutants. Basic organic compound manufacturing facilities discharge 30 kinds of pollutants including 14 specified hazardous water pollutants. Thermal power generation facilities emit 20 pollutants, 8 specified hazardous water pollutants among them. These substances were decided as emission inventories of water pollutants finally through the probability evaluation. The compounds detected for each categories are screened through investigation on the possible causes of their occurrence and confirmed as the final water pollutant inventories.

ASSESSMENT AND CONTROL OF TOTAL NUTRIENT LOADS IN WATERSHED AND STREAM NETWORK IN SOUTH-WEST TEXAS

  • Lee, Ju-Young;Choi, Jae-Young
    • Water Engineering Research
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    • v.7 no.1
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    • pp.1-8
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    • 2006
  • Recently, the population growth and agricultural development are rapidly undergoing in the South-West Texas. The junction of three river basins such as Lavaca river basin, Colorado-Lavaca Coastal basin and Lavaca-Guadalupe Coastal basin, are interesting for non-point and point source pollutant modeling: Especially, the 2 basins are an intensively agricultural region (Colorado-Lavaca Coastal/Lavaca-Guadalupe Coastal basins) and several cities are rapidly extended. In case of the Lavaca river basin, there are many range land. Several habitat types wide-spread over three relatively larger basins and five wastewater discharge regions are located in there. There are different hazardous substances which have been released. Total nutrient loads are composed of land surface load and river load as Non-point source and discharge from wastewater facilities as point source. In 3 basins region, where point and non-point sources of poll Jtion may be a big concern, because increasing fertilizers and pesticides use and population cause. This project objective seeks to how to assess and control the accumulation of non-point and point source and discuss the main impacts of agriculture and environmental concern as non-point source with water quality related to pesticides, fertilizer, and nutrients and as point source with wasterwater discharge from cities. The GIS technique has been developed to aid in the point and non-point source analysis of impacts to natural resource within watershed. This project shows the losses in $kg/km^2/year$ of BOD (Biological Oxygen Demand), TN (Total Nitrogen) and TP (Total Phosphorus) in the runoff from the surface of 3 basins. In the next paper, sediment contamination will show how to evaluate in Estuarine habitats of these downstream.

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Reduction and Decomposition of Hazardous NOx by Discharge Plasma with $TiO_2$ ($TiO_2$ 촉매를 이용한 플라즈마반응에 의한 NOx의 분해)

  • Park, Sung-Gug;Woo, In-Sung;Hwang, Myung-Whan
    • Journal of the Korean Society of Safety
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    • v.23 no.5
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    • pp.54-60
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    • 2008
  • The objective of this study is to obtain the optimal process condition and the maximum decomposition efficiency by measuring the decomposition efficiency, electricity consumption, and voltage in accordance with the change of the process variables such as the frequency, maintaining time period, concentration, electrode material, thickness of the electrode, the number of windings of the electrode, and added materials etc. of the harmful atmospheric contamination gases such as NO, $NO_2$, and $SO_2$ etc. with the plasma which is generated by the discharging of the specially designed and manufactured $TiO_2$ catalysis reactor and SPCP reactor. The decomposition efficiency of the NO, the standard samples, is obtained with the plasma which is being generated by the discharge of the combination effect of the $TiO_2$ catalysis reactor and SPCP reactor with the variation of those process variables such as the frequency of the high voltage generator($5{\sim}50kHz$), maintaining time of the harmful gases($1{\sim}10.5sec$), initial concentration($100{\sim}1,000ppm$), the material of the electrode(W, Cu, Al), the thickness of the electrode(1, 2, 3mm), the number of the windings of the electrode(7, 9, 11turns), basic gases($N_2$, $O_2$, air), and the simulated gas($CO_2$) and the resulting substances are analyzed by utilizing FT-IR & GC.

Study on characteristics of specific hazardous substances in the industrial wastewater effluent (사업장 방류수 중 특정수질유해물질 배출 특성 연구)

  • Kim, Seungho;Choi, Youngseop;Kim, Yunhee;Kim, Jongmin;Chang, Gilsik;Bae, Seokjin;Cho, Younggwan
    • Analytical Science and Technology
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    • v.29 no.3
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    • pp.114-125
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    • 2016
  • In this study, 165 wastewater discharge facilities in 10 business types were investigated with regard to 24 specific hazardous substances that included heavy metals, VOCs, CN, and phenol in the Gwangju city. Cu in the range from from 0.008 to 35.420 mg/L was detected in all business types and the detection rate was 46.8 %. Other heavy metals, such as Cd, As, Hg, Pb, and Cr+6 were detected as well. However, their detection rates ranged between 0.6 and 1.8 %. CN and phenol were detected in one and five facilities, respectively. 12 species of VOCs were detected: chloroform 80.6 % (0.42 to 81.60 μg/L), benzene 16.4 % (1.49 to 3.31 μg/L), trichloroethylene 11.5 % (1.78 to 6.02 μg/L), 1,1-dichloroethylene 10.3 % (1.23 to 5.89 μg/L), and dichloromethane 8.5 % (0.28 to 968.86 μg/L) in the detection rate order. The concentration of VOCs was detected in trace amounts, except for dichloromethane that exceeded the effluent quality standard in three business types, namely, metal manufacturing, food industry, and car washing facility. Chloroform was detected in all business types, where 24.88 μg/L were detected in the laundry business and 53.41 μg/L in the water supply business; the mean concentration of chloroform in these two business types was higher than elsewhere. Therefore, for the disposal of non-degradable specific hazardous substances in industrial wastewater, it is necessary to introduce physical and chemical processes, such as activated carbon adsorption, fenton oxidation, ozone treatment, as well as photocatalyst and the UV radiation.