• Title/Summary/Keyword: hazardous material

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Kinetic and Thermodynamic Studies of Brilliant Green Adsorption onto Carbon/Iron Oxide Nanocomposite (탄소/산화철 나노복합재료의 Brilliant Green 흡착에 대한 반응속도론적, 열역학적 연구)

  • Ahmad, Rais;Kumar, Rajeev
    • Journal of the Korean Chemical Society
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    • v.54 no.1
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    • pp.125-130
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    • 2010
  • In the present work, we have investigated the adsorption efficiency of carbon/iron oxide nanocomposite towards removal of hazardous brilliant green (BG) from aqueous solutions. Carbon/iron oxide nanocomposite was prepared by chemical precipitation and thermal treatment of carbon with ferric nitrate at $750^{\circ}C$. The resulting material was thoroughly characterized by TEM, XRD and TGA. The adsorption studies of BG onto nanocomposite were performed using kinetic and thermodynamic parameters. The adsorption kinetics shows that pseudo-second-order rate equation was fitted better than pseudo-first-order rate equation. The experimental data were analyzed by the Langmuir and Freundlich adsorption isotherms. Equilibrium data was fitted well to the Langmuir model with maximum monolayer adsorption capacity of 64.1 mg/g. The thermodynamic parameters were also deduced for the adsorption of BG onto nanocomposite and the adsorption was found to be spontaneous and endothermic.

A Study on Damage caused by Space Activity (우주활동으로 인한 손해배상에 관한 법적 고찰)

  • Cho, Hong-Je;Shin, Dong-Chun
    • The Korean Journal of Air & Space Law and Policy
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    • v.27 no.1
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    • pp.103-122
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    • 2012
  • Nowadays, advanced countries and international community in which provide many services and profits due to rapid progress space science and technology whereas there is rising possibility of damage by collision of space object and increase of space debris. I will propose the concept and range of damage in the basis of review of space treaty and space liability convention as form of international order to fair and complete compensate to victim of accident and hazardous space activity. And, I will try to discuss possibility of compensation on personal damage and mental damage, scope of material damage, possibility of compensation about environmental contamination, issue of satellite data sending, place of damage, and so on. Also, I would like to propose establishment of space tribunal and regional cooperative agency.

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Investigation of Ingredients and Hazardous Substances in Disinfectants Used against COVID-19 and Some Livestock Diseases (코로나바이러스감염증-19와 일부 가축전염병 방역소독제품의 함유성분 및 유해물질 조사)

  • Kim, DongHyun;Lim, Miyoung;Lee, Kiyoung
    • Journal of Environmental Health Sciences
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    • v.46 no.4
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    • pp.470-479
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    • 2020
  • Objectives: The Coronavirus Disease 2019 (COVID-19) pandemic has caused the death of 740,000 people around the world as of August 12, 2020. Foot-and-Mouth Disease, Avian Influenza, and African Swine Fever are serious livestock diseases. Government agencies in Korea have provided ingredient information and usage instructions for disinfectants used to counter those infectious diseases. The purpose of this study was to provide information on the chemical ingredients in disinfectant products used against COVID-19 and certain livestock diseases. Methods: We collected information from the Korean government. The Central Disaster Management Headquarters and Central Disease Control Headquarters provided information on disinfectant products used against COVID-19. The Animal and Plant Quarantine Agency of Korea provided information on efficacy-certified disinfectant products for use against selected livestock diseases. Health hazard and environmental hazard information on the ingredients in the disinfectants was collected from the Korea Occupational Safety & Health Agency's Material Safety Data Sheets, and toxicity value information was collected from United States Environmental Protection Agency's CompTox Chemicals Dashboard. Results: There were 76 COVID-19 disinfectant products in use, and the most common ingredients were benzalkonium chloride (51%), alkylbenzyl dimethyl ammonium (30%), and ethanol (3%). There were 216 livestock disease disinfectant products comprised of 89 acidic, 88 oxidic, 30 aldehydic, three alkaline, and six other products. Among the 49 active ingredients used in the disinfectants that were investigated, health and environmental hazard information was provided for many of them, but only 20 chemicals had official toxicological information. Conclusion: Since the disinfectants included numerous chemicals, an understanding of their chemical characteristics could be critical to prevent unintended human or environmental exposure.

A Study on Harmonized Classification and Categorization for Physical Hazards of Chemicals in Korea (국내 화학물질의 물리적위험성 분류·구분 단일화에 관한 연구)

  • Lee, BongWoo;Shin, Dongil
    • Journal of the Korean Institute of Gas
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    • v.21 no.4
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    • pp.30-41
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    • 2017
  • Although chemical substances have greatly contributed to prosperous human life and industrial development and made a great contribution to humanity, some dangerous substances are harmful to health and the environment. Thus, so long ago developed countries have also established strict safety standards. Korea is growing into a major chemical market, accounting for 3.4% of the global chemical market. The domestic laws related to chemical substances are similar to foreign countries, but there are many differences in detail, posing a lot of risks to safety, health and the environment as well as causing many problems in industry. In order to improve these problems, this study carried out to unify the domestic chemical law and the international standardization system (GHS) and to solve the trade barriers in the export and import by industry. In addition, researchers proposed a unified approach to classification and division of physical hazards, as advanced as developed nations, as a basis for prevention and response to accidents in dangerous goods.

Recycling of the Waste Rock and Tailings from Yangyang Iron Mine (양양철광산 선광 부산물의 순환자원화)

  • Jung, Moon Young;An, Yong Hyeon;Kim, Young Hun
    • Resources Recycling
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    • v.25 no.4
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    • pp.23-31
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    • 2016
  • It was found that there was no problem in recycling by-products (waste rock and tailings) from Yangyang iron mine themselves through matter conversion because they are not hazardous according to results of KSLT method. In case of using tailings as sub-materials of cement, it recommended the use of less than 3% tailings dosage not to exceed 0.6% of total alkali ($R_2O$) content based on standard quality of portland cement (KS L 5201). Non sintered eco-brick corresponding to class 1 quality of recycled clay brick (KS I 3013) can replace 15% of cement with tailings and 100% of general fine aggregate with waste rock from iron mine. As mentioned above, recycling the by-products (waste rock and tailings) as sub-materials of cement and non sintered eco-brick could gain both environmental and economic benefits, that is, reduction of scale and maintenance cost of tailing ponds, decrease of energy use and $CO_2$ emission.

Consumer Awareness Survey for Environmentally Friendly Children's Furniture Development (친환경 아동용 가구 개발을 위한 소비자 인식 조사)

  • Kim, Ja Kyung
    • Journal of the Korea Furniture Society
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    • v.28 no.4
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    • pp.340-354
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    • 2017
  • Currently, the global furniture market can not overlook environmental problems due to changes in environmental regulations. In order to grow into a global corporation, environmentally friendly design became essential. In addition, domestic and foreign consumers are increasingly interested in and spending on children's furniture, and demand for environment - friendly furniture for children's health and emotional development is increasing. In the era of universal consumer tastes due to massive mass production, it has been changed into a multi-product small-volume production period that reflects the preferences of various consumers, so that various types of furniture that meet individual preferences are required. Therefore, in this study, we investigated various personal opinions, perception, preference, propensity to use furniture, purchasing points, etc. for environmentally friendly children's furniture, and provided basic data for environmentally friendly children's furniture development that reflects consumer preference and requirements. Accordingly, 243 parents who have more than one child living in Seoul, Gyeonggi, and Incheon were surveyed about the use of children's furniture and the perception and preference of environmentally friendly children's furniture. According to the survey results, 64.57% of the respondents knew about eco - friendly children's furniture and the most popular way to get to know eco-friendly furniture was Internet advertising (49.48%). The rate of recognizing eco-friendly furniture as healthy furniture with no emission of hazardous substances was high as 56.16%. The purchase intention of eco-friendly children's furniture was very high at 86.01% and the most important factor in purchasing was the harmlessness to the human body (56.88%). 59.50% said that it is not possible to distinguish environmentally friendly furniture, which means that there is not much information to consumers yet. In addition, the preferred price range is 500~1000 thousand won, and the preference for the rest furniture is high. In the preferred form type, unit type modular furniture is 36.13%, in the material, wood is 72.35%, in the color, the color of wood with wood grain is high as 45.56%.

Analytical method for combustible waste contaminated by the HF leakage from industrial process (산업공정에서 불산누출로 오염된 가연성 폐기물의 분석방법 연구)

  • Kang, Young-Yeul;Kim, Yong-Jun;Kim, Woo-Il;Yoon, Cheol-Woo;Yeon, Jin-Mo;Shin, Sun-Kyoung;Oh, Gil-Jong
    • Analytical Science and Technology
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    • v.27 no.3
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    • pp.167-171
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    • 2014
  • Hydrofluoric acid (HF), a typical inorganic acid, has been used in the industry for its various usage and classified as the toxic compound, because it can cause the pneumonia and pulmonary edema when it was exposed to respiratory organs. The official environmental analytical method for fluorine and its compound in waste has not been developed. For this reason, we have faced some problem to treat the contaminated wastes by the HF leakage from industrial process. In this study, prepared for analytical method for combustible waste (crop, trees, etc.) generated from HF leaking accident and to be applied as the official analytical method for fluorine contaminated waste when the fluorine and its compound will be regulated as a hazardous material by the waste management law later.

The Analysis of the Painting Work Clothes Clothing Comfort and Wearer Mobility Considering the Work Environment in the Machine and Shipbuilding Industries

  • Park, Gin-Ah;Park, Hye-Won;Bae, Hyun-Sook
    • Journal of Fashion Business
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    • v.16 no.3
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    • pp.13-31
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    • 2012
  • The purpose of the study was to analyze the work clothes' clothing comfort and wearer mobility of painting workers with the consideration of the work environment features in the machine and shipbuilding industries in South Korea. A questionnaire survey was conducted for the study, which consisted of questions on the clothing comfort and wearer mobility aspects of painting work clothes by clothes types and body parts. The work clothes' clothing comfort and wearer mobility levels were scaled in 5 points i.e. 1(: very tight/very uncomfortable) to 5(: very slack/very comfortable). The painting work environmental hazardous features were considered as high impact levels of workplace temperature, oxygen deficiency, organic solvent, toxic gas factors while metal fragment factor only impacts 'low' in the painting processes with the findings throughout this study. Since the painting work consisted of surface washing and the spray and touch-up painting processes, which was carried out in an outdoor work place, the painting work clothes should meet high performance of waterproofing from the painting material and air permeability specially in summer as well as thermal performance in winter. The subjects painting workers' assessment of the existing work clothes' clothing oppression was in the levels between 3 (i.e. moderate) and 4 (i.e. comfortable) in a range of 1 to 5 points. The existing painting work clothes' wearer mobility was evaluated 'very uncomfortable' in all work clothes parts, especially, armhole length, biacromial breadth, sleeve length of the jumper; and body rise, waist, hip, thigh and knee circumferences of the pants.

A Study on the Efficient Operation of Self-audit in Large-scale PSM Workplace (대규모 PSM 사업장의 자체감사에 대한 효율적 운영 연구)

  • Min, Se-Hong;Kim, Seok-Won
    • Fire Science and Engineering
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    • v.27 no.6
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    • pp.115-121
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    • 2013
  • Industrial facilities are becoming bigger and more up to date, And a kind of the hazardous material used in the industrial filed is diversified. Therefore, serious accidents such as leakage of toxic materials, fire and explosion, is continuously occurred. There is Process Safety Management (PSM) system of the several preventive systems, but it is supposed to be a limitation to ensure safety or huge PSM industrial sites where have potential to catastrophically invisible and unexpected risks because it is still being managed by instruction and inspection of authority having jurisdiction other than self-regulating management differing from the primarily aim of PSM system. To verify safety management system of work-place, supplementation of existing system is urgently required. In this study, it suggests that PSM self-audit be emphasized significantly analyzing problems of the current systems for enhancing self-audit be emphasized significantly analyzing problems of the current systems for enhancing self-control safety through efficient self-audit management and improving the existing system and improving the existing as verifying the system there of, as well as studying methods which can support institutionally.

Development of a 3-Dimensional Turbulent Reaction Computer program for the Incineration of a Carbon Tetrachloride($CCl_4$) ( I ) (사염화탄소($CCl_4$) 소각을 위한 로타리 킬른 소각로 3차원 난류반응 컴퓨터 프로그램 개발( I ))

  • 엄태인;장동순
    • Journal of the Korean Society of Safety
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    • v.9 no.1
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    • pp.100-109
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    • 1994
  • In this study, it is investigated that the possibility of the numerical simulation for the incineration of the hazardous material, crbon tetrachloride($CCl_4$). A 3-dimensional numerical technology is applied for turbulent reacting flows of the full-scale Dow Chemical incinerator. The calculations are made by a CRAY-2S, super computer. The major parameters considered in this study are kiln revolution rate (rpm), filling ratio of the solid waste(f), burner Injection velocity and angle, and turbulent air jets for swirl. And the employed turbulent reaction model is the eddy break-up model which is a kind of fast chemistry model assuming general equilibrium and used for a premixed flame. The calculated flow fields are presented and discussed. 1) The presence of turbulent air nozzles for swirl gives rise to visible increase of the convective motion over the region of the solid waste. This implies the possibility to enhance the mixing of the waste with the surrounding all and thereby to reduce thermal and species stratification, which were reported in a large rotary kiln operation. 2) Considering that the location of the recirculation region has a strong relation with the heating rate of the solid waste, the control of the recirculation region by the burner injection angle Is quite desirable in the sense of the flexible design of the rotary kiln incinerator for a carbon tetrachloride. 3) Finally, it is found that the eddy break-up model Is not suitable for carbon tetrachloride($CCl_4$) because this model is not incorporated the flame inhibition trend due to the presence $CCl_4$compound.

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