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Study on the Validity of Selection of Hazardous Substances Requiring Management on Industrial Safety and Health Act (산업안전보건법에 의한 관리대상 유해물질 선정의 타당성 연구)

  • Lee, Kwon Seob;Jo, Jihoon;Choi, Jin Hee;Shin, Hyun Hwa;Yang, Jeong Sun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.19 no.2
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    • pp.139-152
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    • 2009
  • According to the third study on the distribution of chemical substances carried out by the Department of Environment in 2006, there were a total of 900 chemical substances whose respective annual usage amount exceeded 1,000 tons and, among them, 90 substances belonged to the 168 hazardous substances requiring management(53.6%). The work-related illnesses caused by hazardous substances requiring management in Korea between $1992{\sim}2005$ can be classified into four groups depending on the type of the chemical substances. These four groups are 23 organic substances including benzene, 12 metals including lead, 3 acids and bases including hydrogen chloride, and 6 gaseous substances including carbon monoxide. These hazardous substances requiring management were again classified depending on the threshold limit values. The chemicals whose TLV was lower than or equal to 0.005 ppm included 4 organic substances including methylene bisphenyl isocyanate and toluene-2,4-diisocyanate (TDI). The chemicals whose TLV was larger than 51 ppm included 22 organic substances including diethyl ether and 1,2-dichloroethylene. When we classified these hazardous substances requiring management according to the categories of GHS health hazards, we found that isobutyl acetate and magnesium oxide didn't belong to the 13 health hazard categories. Among the substances whose TLV is set and whose annual usage amount is more than 0.1 million ton, we recommended 12 chemical species including 4,4'-Methylenedianiline as new hazardous substances requiring management. All the recommended substances were found to be hazardous when we classified their health hazards.

The Effects of Hazardous Chemical Exposure on Cardiovascular Disease in Chemical Products Manufacturing Workers

  • Kim, Ki-Woong;Won, Yong Lim;Ko, Kyung Sun;Heo, Kyung-Hwa;Chung, Yong Hyun
    • Toxicological Research
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    • v.28 no.4
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    • pp.269-277
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    • 2012
  • The purpose of this study was to understand the mechanism of cardiovascular disease (CVD) caused by exposure to hazardous chemicals. We investigated changes in the symptoms of metabolic syndrome, which is strongly related to CVD, and in levels of other CVD risk factors, with a special emphasis on the roles of catecholamines and oxidative stress. The results revealed that neither body mass index (BMI) nor waist and hip circumferences were associated with exposure to hazardous chemicals. Among metabolic syndrome criteria, only HDL-cholesterol level increased on exposure to hazardous chemicals. Levels of epinephrine (EP) and norepinephrine (NEP) were not influenced by exposure to hazardous chemicals; however, the total antioxidative capacity (TAC) reduced because of increased oxidative stress. Both hazardous chemical exposure level and metabolite excretion were related to EP, NEP, and the oxidative stress index (OSI). Logistic regression analysis with these factors as independent variables and metabolic syndrome criteria as dependent variables revealed that EP was associated with blood pressure, and NEP with metabolic syndrome in the chemical-exposed group. In conclusion, the results suggest that reactive oxygen species generated and oxidative stress due to exposure to hazardous chemicals act as mediators and cause changes in the physiological levels of EP and NEP to increase blood pressure. This ultimately leads to the development of CVD through increase in cholesterol, triglyceride, and blood glucose levels by lipid peroxidation.

The Recognition Level of Food Contamination with Residual Pesticides and Hazardous Heavy Metals in Taejon Area (식품의 잔류농약 및 유해중금속의 오염인식도 -대전지역을 중심으로-)

  • 한장일;김성애
    • Korean Journal of Community Nutrition
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    • v.3 no.3
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    • pp.454-465
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    • 1998
  • This study was to investigate the recognition level of food contamination with residual pesticides and hazardous heavy metals from 365 male and female adults in Taejon area using questionnaires. Among the recognizing level of residual pesticides in overall foods, 69.1% were 'serious', 25.6% were 'average' and 5.3% were 'not serious'. Over 94.7% of the subjects recognized residual pesticides pollution infoods. for hazardous heavy metals in food, 47.8% responsed as 'serious', 40.5% as 'average' and 11.8 as ' not serious' . Over 88.3% of the subjects recognized contaminated pesticides seriously in fruits, 72.1% in vegetables and 51.7% in cereals, whereas 55.7% of the subjects recognized hazardous heavy metal contamination seriously in fruits, 53.4% in vegetables, 40.8% in fishes and shellfishes and 35.0% in seaweeds. The subjects recognized residual pesticides contamination more seriously in overall foods, cereal, potatoes and starches, bean, vegetables and fruits, whereas hazardous heavy metal contamination was recognized more seriously in fishes and shellfishes, and seaweeds food groups. Comparisons were shown based on individuial's occupation. Farmer, forester, iner and fisher showed the lowest recognizing level of food contamination in most food groups. The mean score of the dietary effect by mass media's information on food contamination from residual pesticides and hazardous heavy metals were 3.51±0.96 out of 5 points. By Duncan's multiple range test, sex, age, marriage, food cost per month, concerns about health and nutrition knowledge showed significant differences in the mean effect score at p<0.05. According to a pesticides contamination in several food groups were affected by food cost per month, mass media's information on food contamination, health status, and concerns about health, But a recognition level of hazardous heavy metals in food were affected by income and, food cost per month mass media's information on food contamination, health status, concern about health and nutrition knowledge. People who need to take extreme precautions of food contamination were in order of producers, government officials, homemakers, the consumer's association and consumers.

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Status of Illegal Hazardous Information for Chemical on Internet - Monitoring Cases of Chemical Cyber Surveillance - (인터넷 상 화학물질 불법 유해정보 현황 고찰 - 화학물질 사이버감시단 신고 사례를 중심으로 -)

  • Hwang, Man Sik;Im, Ji Young;Jeon, Da Young;Song, Ki Bong;Lee, Sang Mok;Ryu, Ji Sung;Lee, Ji Ho
    • Korean Journal of Hazardous Materials
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    • v.6 no.2
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    • pp.13-22
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    • 2018
  • Recently, social crimes using chemicals at home and abroad are increasing. These chemicals are readily available in the internet. Therefore, the NICS(national institute of chemical safety) runs a 'Chemical Cyber Surveillance' to help the public take control of the internet and create a healthy cyberspace through voluntary participation of the public. The study analyzed more than 1,000 sites suspected illegal hazardous information or blocked among cyber surveillance 3,500 case reports in the past yeas. And, the number of illegal hazardous information reported in the past three years is analyzed by type and substance. They want to examine the characteristics of hazardous chemical information on the internet and use it as a basic data to establish illegal information management measures that spread over cyberspace.

Analysis of Hazardous Microbes on the Processing of Surimi-Based Imitation Crab (Surimi-Based Imitation Crab의 가공공정에 대한 위해미생물 분석)

  • 김창남;천석조;노우섭;오두환
    • Journal of Food Hygiene and Safety
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    • v.12 no.4
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    • pp.346-353
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    • 1997
  • This study was undertaken to find out distribution and contamination sources of hazardous microbes through microbial hazard analysis on the processing steps of surimi-based imitation crab (SBIC). As a results of ananlysis of 9 hazardous microbes for 16 raw materials and 8 processing steps, no Samonella spp. and Escherichia coli were detected in all samples. Level and distribution of hazardous microbes in mixed color were similar to those of surimi. Changes of aerobic plate counts (APC), psychrotropic bacteria, coliforms, Staphylococcus aureus and Vibrio parahaemolyticus showed similar trends at different processing steps. Thermotrophic bacteria and aerobic sporeformers were not detected until mixing step and feeding step, respectively and not reduced after cooking step. According to the comparison of APC at each step, it was suggested that surimi, workers and silent cutter at mixing step, and mixed color, workers and bundler at packaging step were the major contamination sources of bacteria.

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Uniaxial Compressive Strength Characteristic of Shotcrete Immersed in Chemical Solution (화학적 침식에 의한 숏크리트의 압축강도 특성)

  • Lee, Gyu-Phil;Kim, Dong-Gyou;Bae, Gyu-Jin;Kim, Hong-Sam
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.1291-1298
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    • 2005
  • Shotcrete for the support of tunnel can contact with groundwater. The hazardous components in the groundwater cause the corrosion of shotcrete. Also, the hazardous components may deteriorate the engineering properties of shotcrete, such as compressive strength, bond strength, and flexural strength. The more the effect of the hazardous components on the shotcrete may increase, the more the stability of tunnel structure may decrease. It was analyzed to find the hazardous components in the ground water. The uniaxial compressive strength test, XRD, SEM were conducted to evaluate the durability and corrosion of shotcrete. These tests were performed on shotcrete specimens at 2, 4, 8, and 16 weeks. The specimens were immersed in various chemical solutions including hazardous components after the specimens were made at the construction site.

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Landfill of Hazardous Wastes in Korea (국내 특정폐기물의 매립현황)

  • Lee, Dong-Soo
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.213-223
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    • 1992
  • Although landfill has been heavily relied upon as a final hazardous waste disposal method in Korea, the legal and technical problems associated with the landfill severely hinder proper disposal of hazardous wastes. The single largest legal problem is simply that, in spite of the recent amendments, the law regulating the hazardous waste landfill is yet in its primitive stage that even the lawful landfill sites cannot be regarded safe. The technical problems include improper selection of landfill sites, poor design and construction of landfill facilities, and lack of QA/AC and post-closure cares. These technical problems stem from inexperience and lack of resources. For the reduction of the potential danger from the improper landfills of hazardous wastes, it is an immediate need to further refine the law and to resolve the technical problems.

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The Development of Hazardous Waste Compact Dump incinerator for Low Emissions (저공해 compact 유해폐기물 dump 소각기 개발)

  • 전영남;채종성;정오진
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.6
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    • pp.653-663
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    • 2000
  • A lot of hazardous wastes are discharged as by-products of working process by industrial development. Hazardous wastes is physical characteristics of difficult destruction at hight temperature. Numerical simulation and combustion experiment performed of dump incinerator for hazardous waste incineration. For the numerical simulation, the SIMPLEST algorithm was used to ensure rapid converge A K-$\varepsilon$ model was incorporate for the enclosure of turbulence flow. Combustion model was used by ESCRS (extended simple chemically reacting system) model available of CHEMKIN thermodynamic data for the source term of species conservation equation or energy equation. Radiation model is used by six flux model. A parametric screening studies was carried out through numerical simulation and experiment. Residence time and concentration in the incinerator was strongly dependent on the parameters of mixture velocity, mixture equilibrium ratio, surrogate velocity and surrogate equilibrium ratio.

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