• Title/Summary/Keyword: harmful gases

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Studies on the Accelerated Aging Characteristics of Paper Records by Gaseous Air Pollutants (가스상 대기오염물질에 의한 종이 기록물의 가속열화 특성 연구)

  • Jeong, So-Yoon;Jeon, Soo-Yeon;Baek, So-Ra;Jeong, Hyun-Seok;Lee, Jin-Hee;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.151-159
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    • 2015
  • Paper records were generally degraded by some factors from atmospheric environments, like temperature, relative humidity or air pollutants. In this study, the degradation behavior of paper records by single or mixed gases of $NO_2$, $SO_2$, HCHO and TVOC was evaluated. The mechanical, optical and chemical properties of 4 kinds of paper (acid and neutral-based printing paper, traditional Hanji, and filter paper) were directly and indirectly affected by gaseous harmful materials. The brightness and $L^*$ value in all papers were slightly increased by accelerated aging under gaseous HCHO and TVOCs, but highly decreased by conditions under gases $NO_2$ and $SO_2$. The optical properties of paper records were most vulnerable in acid-based paper and high stable in filter paper and traditional Hanji by air pollutant degradation. The aging treatments under mixed gas pollutants including $NO_2$ resulted in decrease of physical, mechanical and optical properties of paper, so it was supposed that the concentration of $NO_2$ gas would be strictly controlled for optimum indoor air quality management in domestic storage centers for paper records.

Study of Development of Selective Removal Adsorption Ion Exchange Resin Materials for Fabricated with Chemical-biological Cloth by QFD (QFD 기법을 이용한 특정 유해가스 노출제어 이온선택성 보호복 소재개발연구)

  • Song, Hwa Seon;Koo, Il Seob;Kim, In Sik
    • Journal of Korean Society for Quality Management
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    • v.43 no.3
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    • pp.359-372
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    • 2015
  • Purpose: Through studying the expert's and non-experts panel responses to the questions regarding the attributes of chemical-biological protection cloth quality in terms of the levels of customer demand and technical factors has been studied. We are applied to a QFD matrix with find out the relationship between the selective removal efficiency of chemical-biological cloth and the guidelines of technical approach. Methods: We fabricated several composite of ion-exchange resins with selectively permeable performance designed to facilities water vapor transport and selective adsorption of the harmful gases. With these materials, we characterized on the selectively permeable performance to identify ion-exchange resin with chemical-biological protective cloth. Results: Results showed that ion exchange materials possessed performance with selectively efficiencies as NH3, SOx, NOx and HCl gas. The selective adsorption amount of ammonia and hydrogen gases were $90-80{\mu}g/g$ with TRILITE SCR-BH sulfonated ion exchange resin. The PP non-woven/ion exchange resin adsorbent materials possessed performance with water vapor permeability were 1,100-1,350 g/m2/day, it's was two times high value compare with activated carbon. With these materials, we characterized selectively removal efficiency to identify new ion-exchange material with chemical-biological protective capability. Conclusion: This study shows that a QFD aids in deciding with of the adsorption parameters to optimized with chemical-biological protection cloth manufacturing.

Economical Feasibility of Cultivation under Structure Due to the Introduction of New and Renewable Energy -Comparative Analysis of Wood-Pellet, Geothermal Heat and Diesel- (신재생에너지 도입에 따른 시설재배의 경제성 분석 -목재팰릿, 지열과 경유의 비교분석을 중심으로-)

  • Kim, Hyung Woo;Yoon, Sung-Yee
    • Korean Journal of Organic Agriculture
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    • v.22 no.2
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    • pp.255-268
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    • 2014
  • We are now currently facing serious climate changes such as super typhoon, flood, intense heat, severe cold, super hurricane, drought, desertification, destruction of ecosystem, marine pollution, reduction of food production, destruction of tropical forests, exhaustion of water resources, climate refugees, etc. All of the above mainly derive from greenhouse gas exhaustion. Such harmful consequence might directly affect mankind's sustainable development. If we keep using resources that emits greenhouse gases, the global temperature will rise about $3.2^{\circ}C$ by year 2050. In case of $3^{\circ}C$ rise in temperature, it will result in abnormal climate which will bring about severe property damage. Moreover, 20~50% of the ecosystem will become extinct. As Korea's economy increasingly expands, so do our energy consumption rises. And because of the consequences that can be driven by increasing rate of resource use, not just Korea itself, but also the whole world should seriously concern about greenhouse gases. Although agricultural division only takes up about 3.2% of total greenhouse gas emission, the ministry of Agriculture, Food and Rural Affairs are taking voluntary actions to gradually reduce $CO_2$ and so does each and every related organizations. In order to reduce $CO_2$, introduction of new and renewable energy in farm house warming is crucial. In other words, implementing wood-pellet boiler and geothermal heat boiler can largly reduce $CO_2$ emission compared to diesel boiler. More importantly, not only wood-pellet and geothermal heat is pollution-free but they also have economic advantages some-what. In this thesis, the economic advantage and sustainablity will be introduced and proved through comparing practical analysis of surveyed farm house under structure employing wood-pellet boiler and geothermal heat boiler with Agriculture-Economic Statistic of 2012 who uses diesel boiler.

Literature review of the Reduction of Hydrogen Sulfide and Ammonia in Livestock Pen: Comparison between Korean and Chinese cases (축사 내 황화수소와 암모니아의 저감방안 고찰: 한중비교)

  • Yan, Ding;Moon, Chan-Seok
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.29 no.4
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    • pp.442-451
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    • 2019
  • Objectives: The aim of this study was to review the reduction methods for ammonia (NH3) and hydrogen sulfide (H2S) exposure in livestock. Methods: By reviewing domestic and international research reports from Korea and China, reducing ammonia and hydrogen sulfide in livestock pens was analyzed in terms of ventilation, deodorant, and feed additives. In addition, exposure limits in Korea and China were examined through a comparison between 'TLV-TWA and STEL under the Industrial Safety and Health Act in Korea' and 'Management Standards for Air of Livestock Pens in China'. Results and Discussion: In order to effectively control hazardous gases and odors in livestock pens, the enhancement of natural ventilation or the addition of ventilation fans at the pollution source are being examined. Deodorants are used as adsorbents or masking deodorants. Additives to feed were zeolite powder, FeSO4·7H2O, enzymes, and microbial preparations. Use of feed additives was low-cost and had significant effects compared to other methods. Zeolite was the most commonly used in feed additive in Chinese cases and proved to be low-cost and effective for reducing harmful gases. Enzyme preparations were shown to stimulate the growth of livestock, but were expensive. Conclusions: This study reviewed and examined domestic and international research papers in Korea and China for reducing ammonia and hydrogen sulfide concentrations in livestock pens. More diverse research and the development of feed additives are needed.

Evaluation of Short-Term Exposure Levels on Ammonia and Hydrogen Sulfide During Manure-Handling Processes at Livestock Farms

  • Park, Jihoon;Kang, Taesun;Heo, Yong;Lee, Kiyoung;Kim, Kyungran;Lee, Kyungsuk;Yoon, Chungsik
    • Safety and Health at Work
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    • v.11 no.1
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    • pp.109-117
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    • 2020
  • Background: Ammonia and hydrogen sulfide are harmful gases generated during aerobic/anaerobic bacterial decomposition of livestock manure. We evaluated ammonia and hydrogen sulfide concentrations generated from workplaces at livestock farms and determined environmental factors influencing the gas concentrations. Methods: Five commercial swine farms and five poultry farms were selected for monitoring. Real-time monitors were used to measure the ammonia and hydrogen sulfide concentrations and environmental conditions during the manure-handling processes. Monitoring was conducted in the manure storage facility and composting facility. Information on the farm conditions was also collected through interview and walk-through survey. Results: The ammonia concentrations were significantly higher at the swine composting facilities (9.5-43.2 ppm) than at other manure-handling facilities at the swine and poultry farms, and high concentrations of hydrogen sulfide were identified during the manure agitation and mixing process at the swine manure storage facilities (6.9-19.5 ppm). At the poultry manure-handling facilities, the ammonia concentration was higher during the manure-handling processes (2.6-57.9 ppm), and very low hydrogen sulfide concentrations (0-3.4 ppm) were detected. The air temperature and relative humidity, volume of the facility, duration of manure storage, and the number of animals influenced the gas concentrations. Conclusion: A high level of hazardous gases was generated during manure handling, and some levels increased up to risk levels that can threaten workers' health and safety. Some of the farm operational factors were also found to influence the gas levels. By controlling and improving these factors, it would be possible to protect workers' safety and health from occupational risks.

A Trial for Improvement of Energy Efficiency of Plasma Reactor by Superposing Two Heterogeneous Discharges - Characteristics of Surface and Corona Discharge Combined Plasma Reactor - (이종방전 중첩에 의한 방전 플라스마반응기의 효율개선의 시도 - 연면.직류코로나 방전 중첩형 반응기의 특성 -)

  • ;Mizuki Yamaguma
    • Journal of the Korean Society of Safety
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    • v.15 no.3
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    • pp.66-70
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    • 2000
  • In order to cope with environmental problems caused by harmful gases emitted from various industrial sources, a new technology which employs discharge plasma formed in ordinary atmospheric pressure has been intensively investigated in many industrialized nations. Although a plenty of useful outcomes and suggestions have been made public by scientists in this field, few commercial products which effectively decompose pollutant gases have appeared as yet. This is partly because that the energy efficiency of a most effective plasma reactor has not reached a satisfactory level in comparison with those of devices using conventional technologies. In an attempt to solve the problem mentioned above, we noticed to combine heterogeneous electrical discharges. This concepts is based on that each plasma reactor has its specific spatial region in which chemical reaction are active and by electrically affected with another reactor of different type, the activated region would increase - which may lead to cutting down the energy consumption. To prove this concept experimentally, two different discharge equipments, a plane ceramic-based surface discharge electrode and a corona electrode with tungsten needle may, are selected and combined to fabricate a hybrid plasma reactor. The results are summarized as follows; (1) Ozone concentration generated in the plasma region drastically increases when the positive corona discharge is added to the surface discharge. The rate of increase of ozone depends on the frequency of the surface discharge. The negative corona, however, does not contribute to the improvement of the ozone generation. (2) NO(nitrogen monoxide) decomposition rate also improves by simultaneously applying the surface and the positive corona discharges. The effect of the corona superposition is more evident when the level of the surface discharge is moderate. (3) By adjusting the corona level, the net energy efficiency during NO decomposition improves in comparison with the simple surface discharge reactor.

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Investigation of Emission Gas by using the Intake Manifold Gasket Blade (흡기 매니폴드 가스켓 블레이드 적용에 따른 배출가스 고찰)

  • Lee, Minjung;Kim, Taejung;Shin, Yunchan;Cho, Honghuyn
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.54-61
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    • 2018
  • Incomplete combustion in automotive engines is a major cause of harmful exhaust gases. In this study, to prevent incomplete combustion and reduce exhaust gas emissions, a gasket blade for increasing the air velocity was applied to the intake manifold, and the change in exhaust gas was investigated theoretically and experimentally. First, simulation analysis for flow according to the number and angle of the gasket blade was performed using a 3D flow analysis program. As an analysis result, the internal average velocity of the gasket blade was optimum at 6-blade with an angle of $30^{\circ}$. Based on the simulation results, experiments were conducted to verify the effects of the gasket blades on the exhaust gas in a non-load engine simulation system. As the engine speed was increased from 2000 to 4000 rpm, exhaust gases of HC, CO, and NOx decreased by 23.4%, 16.5%, and 3.8%, respectively, and the emission decreasing effect was reduced.

Research on the Working Environment and Personal Protective Equipment of Korean Native Cattle Raising Farmers (한우 사육자 작업환경 및 작업복과 보호구 착용 실태 분석)

  • Kim, Insoo;Lee, Kyung-Suk;Chae, Hye-Seon;Kim, Kyungsu;Choi, Dong-Phil;Kim, Hyo-Cher
    • The Korean Journal of Community Living Science
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    • v.27 no.4
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    • pp.891-906
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    • 2016
  • This study examined the working site environment of Korean native cattle raising farmers and their actual condition of wearing personal protective equipment as part of preventing disasters during agricultural work. To this end, 160 Korean cattle raising farmers were surveyed and a site visit was performed on 10 farms. According to an examination of the cattle breeding environment, the major harmful factors were in the following order: fine dust (12.8%), organic feed dust (10.3%), contact with cattle (9.7%), manure (8.2%), germs and viruses (8.1%), harmful gases (7.4), contact with obstacles (6.7), and temperature (6.6%). The current status of the rate of wearing protection was in the order of gloves (20.9%), working hats (19.7%), boots (19.6%), masks (10.9%), protective clothing (8.9%), and specialized working clothing (6.6%). Nevertheless, most Korean cattle raising farmers recognized the risks when they did not wear protective equipment and the need for wearing protectors, but they mostly did not wear personal protective equipment due to a lack of knowledge on the selection of appropriate personal protective equipment and the discomfort they experience when they put on protectors. Even when they put on protective equipment, 38% was inappropriate for the farming work environment. Given the research results, improvements on and the development of specialized working clothing and personal protective equipment to protect farmers from harmful and dangerous materials from the cattle nurturing environment is necessary. Overall, based on the study data, objectified data collection, a determination of the necessary performance elements of personal protective equipment, and R&D will be needed through an on-site current status investigation.

A Case Study on the Development of New Process for Treatment of Waste Waters from Ships (선박폐수 처리공정의 개발에 관한 사례)

  • Choi, Sang-Mo;Heo, In-Seok;Yang, Seok-Jun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.1
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    • pp.71-78
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    • 2009
  • Korea Marine Environment Management Corporation (KOEM) has waste oil facilities in 13 ports to collect and treat waste oil, bilge, etc. from ships based upon the Marine Environment Management Act of Korea and MARPOL 73/78 convention. Those facilities were designed and have been operated simply to discharge water under the level 15 ppm of oil contents. However, bad smells occurred from rotten organic matters in waste water and direct discharge of harmful substances to receiving water caused civil appeals. Therefore, KOEM tried to develop new process for treatment of oily waste water from ships, which could mitigate harmful substances, save cost, calm down civil appeals and contribute to marine environment preservation. This process consists of 3 steps to remove oil contents via gravity variation at first, $O_3$ input to contact water and organism deposition by inputting condensate deposits. Then finally upper water will be discharged, and the deposited substances in the bottom will be compressed through spinning machine to transfer to the designated contractors for treatment of wastes. This is very effective and innovative in that it could reduce 3 or 4 steps compared with existing process and mitigate not only waste oil concentration but also hard resolving materials such as colloid, ABS, phosphorus, nitrogen and bad smells. This method is expected to minimize bad smells and harmful gases, to save more than 10% of maintenance cost, and to arrange the good base for garbage treatment business dealing with waste water and bad smell.

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Assessments of the VOCs and Smells Compounds Emitted from Properties Exhumed at Sim Seol Tomb (심설(沈偰)묘 출토유물에서 발현되는 VOCs 및 냄새물질의 특성 평가)

  • Seo, Yong-Soo;Lee, Young-Eun
    • Journal of Conservation Science
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    • v.28 no.1
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    • pp.63-73
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    • 2012
  • In this study, the 89 components of the gases emitted from grave goods at Sim Seol(1570-1630) tomb identified and quantitatively analyzed using a thermal desorption system integrated with gas chromatography-mass spectrometer. The concentration of major components show the levels of alpha-pinene 4,113ppbv, beta-pinene 2,510ppbv and limonene 2,424ppbv, that of the others orderly show p-menth-2-ene, acetone, isolongifolene and isoborneol. The functional groups of high concentration level cover 65% of terpenes and 25.8% of alcohols. The expected odor intensity orderly show 35.1% of terpenes, 33.4% of aldehydes and 8.8% of alcohols. Terpenes have generally effect of a perfume, antifungal and antimicrobial activity, and could come out of the pine(Pinus densiflora) coffin, aldehydes and alcohols could be come out of both the Sim Seol mirra and Pinus densiflora for a long time. The analyses of gases emitted from a excavated properties or a tomb are assessed that it can pc001 provide a scientific basis on a counterplan against harmful gases, a method of conservation treatments and a evaluation of effectiveness in conservation of cultural properties in a tomb.