• Title/Summary/Keyword: harmful gas

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Preparation of Hydrazinium 5-aminotetrazolate(HAT) with High Nitrogen Content and Energetic Material (고질소 에너지 물질 Hydrazinium 5-aminotetrazolate (HAT)의 제조)

  • Lee, Woonghee;Kim, Seung Hee
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.5
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    • pp.53-59
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    • 2019
  • Solid fuel reacts with an oxidizer during combustion of a propellant to increase performance. Representative solid fuels are aluminum, cyclotrimethylenetrinitramine (RDX) and octahydro-1, 3,5,7-tetra nitro-1,3,5,7-tetrazocin (HMX). During combustion, these compounds generate white smoke by reacting with moisture and produce materials that are harmful to the environment, such as carbon monoxide, carbon dioxide, and methane gas. This study prepared a high-nitrogen-containing energetic material, hydrazinium 5-aminotetrazolate (HAT), which could be applied as a solid fuel. The compound was characterized by nuclear magnetic resonance (NMR) spectroscopy, and a thermal analysis was measured by differential scanning calorimetry (DSC). Also, the specific impulses and volumes of detonation gases were calculated using the EXPLO5 program.

A study on Development and Application of Sequential Control Algorithm of Ventilation and Air Cleaning System for Improving Indoor Air Quality in School Classroom (학교교실의 실내공기질 개선을 위한 환기장치 및 공기청정기의 연동제어 알고리즘 개발 및 적용 연구)

  • Park, Hwan-Chul;Lee, Dong-Hyeon;Yee, Jurng-Jae
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.36 no.5
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    • pp.187-194
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    • 2020
  • This study presents the energy-saving sequential control algorithm to handle indoor CO2 and PM2.5 for the improvement of the air quality of school classrooms. To solve indoor air quality (IAQ) problems, air cleaning and ventilation systems are mainly used for school classrooms. Although air cleaning is able to collect PM2.5, it is difficult to remove harmful gas substances. The ventilation system is suitable to tackle CO and CO2, the volume ventilation, however, is relatively small. In this paper, to remove CO2 and PM2.5, the pollutant balance equation for improving indoor air quality is reviewed. The sequential control algorithm of the ventilation and air cleaning system with four levels of criteria is introduced for the effective removal of pollutants. The proposed sequential control algorithm confirms that indoor CO2 and PM2.5 can be properly controlled below the standard value. In addition, the sequential operation of air cleaning and ventilation systems has shown significant improvement in IAQ compared to the independent ventilation system operation. Particularly, such systems are efficient when outdoor PM2.5 is high.

Evaluation of Insulation Performance and Structural Integrity of an IMO Type C LNG Storage Tank (IMO Type C LNG 저장 탱크의 단열성능 및 구조적 건전성 평가)

  • Park, Heewoo;Park, Jinseong;Cho, Jong-Rae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.7
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    • pp.1-7
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    • 2021
  • Restrictions on the emissions of nitrogen oxides, sulfur oxides, carbon dioxide, and particulate matter from marine engines are being tightened. Each of these emissions requires different reduction technologies, which are costly and require many pieces of equipment to meet the requirements. Liquefied natural gas (LNG) fuel has a great advantage in reducing harmful emissions emitted from ships. Therefore, the marine engine application of LNG fuel is significantly increasing in new ship buildings. Accordingly, this study analyzed the internal support structure, insulation type, and fuel supply piping system of a 35 m3 International Maritime Organization C type pressurized storage tank of an LNG-fueled ship. Analysis of the heat transfer characteristics revealed that A304L stainless steel has a lower heat flux than A553 nickel steel, but the effect is not significant. The heat flux of pearlite insulation is much lower than that of vacuum insulation. Moreover, the analysis results of the constraint method of the support ring showed no significant difference. A553 steel containing 9% nickel has a higher strength and lower coefficient of thermal expansion than A304L, making it a suitable material for cryogenic containers.

Removal of NOx using electron beam process with NaOH spraying

  • Shin, Jae Kyeong;Jo, Sang-Hee;Kim, Tae-Hun;Oh, Yong-Hwan;Yu, Seungho;Son, Youn-Suk;Kim, Tak-Hyun
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.486-492
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    • 2022
  • Nitrogen oxides (NOx; NO and NO2) are major air pollutants and can cause harmful effects on the human body. Electron Beam Flue Gas Treatment (EBFGT) is a technology that generates electrons with an energy of 0.5-1 MeV using electron accelerators and effectively processes exhaust gases. In this study, NOx was removed using an electron beam accelerator with spraying additives (NaOH and NH4OH). NO and NO2 were 100% and more than 94% removed, respectively, at an electron beam absorbed dose of 20 kGy and an additive concentration of 0.02 M (mol/L). In most cases, NOx was removed better with lower initial NOx concentrations and higher electron beam absorbed doses. As the irradiation strength (mA) of the electron beam increases, the probability of electron impact on the material accordingly rises, which may lead to increase removal efficiency. The results of the present study show that the continuous electron beam process using additives achieved more effective removal efficiency than either individual process (wet-scrubbing or EB irradiation only).

Effect of Water Impingement Conditions on the Degradation of Epoxy Coatings in Tap Water

  • Kim, D.H.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.21 no.5
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    • pp.327-339
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    • 2022
  • The water-jet technique started by Bridgman can cut metal and alloys without harmful gas and fume. However, while this technique is convenient to cut metals and alloys, in the case of coated pipe, water jet induces the degradation of coatings on the pipes, and may facilitate structural failure, leakage, and loss of products. While there are many reports on the effect of water jet on cut metals and the damage of metallic materials, research on the effect of water impingement on the epoxy coatings has been little studied. In this work, we therefore control the velocity of water jet, distance between nozzle and specimen, and water temperature, and discuss the effect of water impingement on the epoxy coatings. Increasing water velocity and water temperature and reducing nozzle distance increased the degradation rates of three epoxy coatings were increased. Among three test parameters - water velocity, nozzle distance and water temperature, water temperature was relatively effective to increase the degradation rate of epoxy coatings.

CVT system applied pulley consisting of the basic disk and rotational disk

  • Sien, Dong-Gu
    • International journal of advanced smart convergence
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    • v.11 no.3
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    • pp.206-214
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    • 2022
  • Automobile manufacturers in each country are spurring the development of electric vehicles that use electric energy, an eco-friendly energy, as a futuristic vehicle. Electric vehicles have the advantage of no harmful gas or environmental pollution and low noise. Unlike automobiles using existing internal combustion engines using fossil fuels, electric vehicles use the electricity of batteries to cause rotational motion of motors. In the electric vehicle driven by the motor, it is indispensable to develop a controller for controlling the motor. One of the areas where automobile manufacturers are concentrating is the development of small electric vehicles as a personal transportation means. Small electric vehicles such as electric motorcycles, one-seat electric vehicles and two-seat electric vehicles are expanding the market as a means of operating throughout the city. In the domestic road conditions with many hills, it is effective to have a separate transmission system for small electric vehicles to drive smoothly. In this study, we propose a new type of continuously variable transmission(CVT) system to ensure that small electric vehicles can be driven smoothly in hilly domestic terrain. The proposed CVT system is equipped with a basic disk and a rotational disk in the driving pulley and the driven pulley, respectively, and is applied with a sloping spline to rotate the rotational disk. To commercialize the proposed CVT system, an experimental device was developed to examine the power transmission efficiency and the configuration of the CVT system was proposed.

A Proprietary Model of Continuously Variable Transmission System using Spline

  • Gu, Sien Dong
    • International journal of advanced smart convergence
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    • v.11 no.1
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    • pp.87-93
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    • 2022
  • In each country, efforts are being made to replace engine-driven cars and motorcycles using fossil fuels with electric drive. Electrically driven vehicles have the advantage of no harmful gas or environmental pollution and low noise. In the motorcycle market, China accounts for more than 95% of the world, and the electric motorcycle market is being revitalized due to the strengthening of regulations. Japan is actively preparing to include electric motorcycles in ISO 26262, forming a TF team centered on electric motorcycle producers. Therefore, it is necessary to respond to standardization targeting China and Japan in Korea. In this study, we propose a proprietary transmission model that can be applied to small electric vehicles that can be operated in hilly domestic terrain. The proposed continuously variable transmission model is a continuously variable transmission system which moves the pin between the basic disk and the rotary disk using a spline to perform shifting. The proposed continuously variable transmission model is used in the pulley configuration by connecting the linear type spline and the inclined spline with the central axis of the basic disk and the rotational disk, respectively. In addition, it can be divided into two types according to the application of the auxiliary disk, and the production drawing is completed for the practical use of the model.

Development of Mobile Vortex Wet Scrubber and Evaluation of Gas Removal Efficiency (기체상 유해화학물질 제거를 위한 이동형 와류식 세정장치 개발 및 가스 제거효율 분석)

  • Kwak, Ji Hyun;Hwang, Seung-Ryul;Lee, Yeon-Hee;Kim, Jae-Young;Song, Ki Bong;Kim, Kyun;Kang, Jae Eun;Lee, Sang Jae;Jeon, Junho;Lee, Jin Hwan
    • Korean Journal of Environmental Agriculture
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    • v.34 no.2
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    • pp.134-138
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    • 2015
  • BACKGROUND: In recent years, several researchers have focused on odour control methods to remove the harmful chemicals from chemical accidents and incidents. The present work deals with the system development of the hazardous. METHODS AND RESULTS: For on-site removal of hazardous gaseous materials from chemical accidents, mobile vortex wet scrubber was designed with water vortex process to absorb the gas into the water. The efficiency of the mobile vortex wet scrubber was evaluated using water spray and 25% ammonia solution. The inlet air velocity (gas flow rate) was according to the damper angle installed within the hood and with increase of gas flow rate, consequently the absorption efficiency was markedly decreased. In particular, when 25% ammonia solution was exposed to the hood inlet for 30 min, the water pH within the scrubber was changed from 7 to 12. Interestingly, although the removal efficiency of ammonia gas exhibited approximately 80% for 5 min, its efficiency in 10 min showed the greatest decrease with 18%. Therefore, our results suggest that the ammonia gas may be absorbed with the driving force of scrubbing water in water vortex process of this scrubber. CONCLUSION: When chemical accidents are occurred, the designed compact scrubber may be utilized as effective tool regarding removal of ammonia gas and other volatile organic compounds in the scene of an accident.

Effect of Humidified High Flow CO2 Gas Insufflation on the Coronary Endothelium (가습화한 고유량의 이산화탄소가스 통기가 관상동맥 내피세포층에 미치는 영향)

  • 최재성;김준성;서정욱;김기봉
    • Journal of Chest Surgery
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    • v.37 no.2
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    • pp.131-138
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    • 2004
  • High-flow gas insufflation to get a bloodless field during off-pump coronary artery bypass may have adverse effects on the coronary endothelium. This study was designed (1) to elucidate the effect of carbon dioxide gas insufflations on the coronary endothelium at different flow rates and (2) to assess the protective effect of humidifcation against the coronary endothelial damage. Material and Method: In nine pigs, the left anterior descending coronary artery (LAD) was exposed after a median sternotomy. The LAD was divided into 4 segments and a coronary arteriotomy was made in each LAD segment in the beating heart. The far distal arteriotomy was exposed to room air for 10 minutes and was harvested as a control. Non-humidified carbon dioxide gas at a continuous flow rate of 5 L/min (Group I), humidified carbon dioxide gas at a continuous flow rate of 5 L/min (Group II), and humidified carbon dioxide gas at a continuous flow rate of 10 L/min (Group III) were insufflated for 10 minutes on each coronary arteriotomy site, respectively. After harvesting the coronary segments, hematoxylin-eosin staining, elastic fiber staining, and immunostaining with a CD34 monoclonal antibody were performed to evaluate the depth of endothelial damage and to count the residual endothelial cells, Result: In all three groups (Group I, II, and III), internal elastic laminae were preserved, however, the endothelial layers were significantly damaged by carbon dioxide gas insufflation. The mean percentages of remaining endothelial cells were 20,9$\pm$16.7%, 39.3$\pm$19.6%, and 6.8$\pm$5.3%, in groups I, II, and III, respectively. The percentages of remaining cells were significantly higher in group II than in groups I and III (p=0.008). The percentages of remaining cells were significantly higher in group I than in group III (p=0.008). Conclusions: The harmful effect of carbon dioxide gas insufflation on the coronary endothelium was dependent on the flow rate. The addition of humidification did not protect the coronary endothelium from denudation injury caused by high flow carbon dioxide gas insufflations.

Inhibitory Effects of Toxic Materials on Activation of Microorganisms in Coke Plant Wastewater (코크스폐수에 함유된 $S^{-2}$$SCN^-$이 미생물 활성에 미치는 영향)

  • Kim, Sang-Sik;Lee, Kisay
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.423-427
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    • 2013
  • This research was carried out to identify the characteristics of the wastewater from coke oven gas (COG) purification process of the coke plant, and derive optimal operating conditions for the treatment of wastewater. The coke plant wastewater contains highly concentrated $S^{-2}$ and $SCN^-$ that are harmful to microorganisms, and their concentrations were 6.8~11.2 mg/L and 190~320 mg/L, respectively. When the $S^{-2}$ ion concentration was lower than 10 mg/L, $SV_{30}$ of active sludge was 280~ 340 mL and the sludge sedimentation velocity was very fast. But, when the $S^{-2}$ ion concentration was higher than 15 mg/L, $SV_{30}$ of the active sludge was 560~680 mL and the sludge sedimentation velocity was very slow. Also when the $SCN^-$ ion concentration was lower than 300 mg/L, $SV_{30}$ of the active sludge was 245~320 mL and the sludge sedimentation velocity was very fast. But, when the $SCN^-$ ion concentration was higher than 400 mg/L, $SV_{30}$ of the active sludge was 470~ 567 mL and the sludge sedimentation velocity was slow. To treat the wastewater generated by COG purification process of the coke plant effectively and to maintain microorganism activities in good conditions, the ion concentration of $S^{-2}$ and $SCN^-$ should be lower than 15 mg/L and 400 mg/L, respectively.