• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2010.04a
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• pp.195-206
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• 2010

Xylan can be applied to improve the strength properties of paper; however the optical properties, such as brightness, are decreased significantly. To solve that problem, an applicable bleaching process is therefore desired. The aim of this research was to investigate the impact of hydrogen peroxide bleaching on hardwood kraft pulp pretreated with birchwood xylan by measuring optical properties (whiteness, brightness, opacity) as well as physical properties (tensile index, tearing index, bulk) of handsheets made from the bleached pulp. Hydrogen peroxide bleaching, as a kind of totally chlorine free (TCF) bleaching method, is quite important industrially for chemical pulp. In our work, the process variables of peroxide bleaching including bleaching temperature, time, initial pH and $MgSO_4$ dosage were studied. The results showed that both good mechanical properties and optical properties could be achieved when the operating parameters were controlled properly and therefore hydrogen peroxide bleaching was proved to be a suitable method for bleaching hardwood kraft pulp with adsorption of birchwood xylan.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.41 no.4
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• pp.65-72
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• 2009

We investigated the effect of polyelectrolyte types in Layer-by-Layer multilayering and furnish combination on physical properties of paper. Handsheets were made from pulp fibers with different polyelectrolytes composition, and their density, formation, tensile strength, strain, tear strength and burst strength were evaluated. The density of handsheet was slightly decreased by polyelectrolyte multilayering. Formation did not show a significant change, but all mechanical properties were increased by polyelectrolyte multilayering. Remarkable improvement in tensile and tear strengths was obtained when pulp fibers were treated with cationic starch and poly styrene 4-sulfonate. Irrespectively of final ionicity of pulp fiber, tensile index, strain and tear strength of paper could be improved simultaneously by polyelectrolyte multilayering.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.1
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• pp.29-43
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• 1998

This study was to investigate the effect of .compressive load and cyclic humidity(2$0^{\circ}C$, 65% and 90% RH) on the physical and mechanical properties of corrugated board. Corrugated boards in the study were under compressive load and under cyclic humidity, and their properties were compared to those without load. Results were summarized as follows ; 1 Statistically significant correlation was shown between the ring crush of the boards and the compressive strength of cylinder specimen made from the boards. So we could study the compressive behavior of board with cylinder specimen. 2. The boards under the compressive load increased their moisture content and thickness much more than those without load both in constant and in cyclic RH. 3. The compressive and tensile strength of board samples were inversely and closely proportional to the sheet moisture content regardless of their load and humidity history. 4. The moisture content did not show any significant proportionality to the change of burst strength of boards within this experiment. 5. Board reconditioning in standard condition led to the recovery of the strength loss that had occurred under various load and humidity condition. 6. The handsheets prepared from the boards that had experienced compressive load and cyclic humidity, and those with no-load and 65% RH did not show any significant difference in strength properties. No physical damage or load-carrying properties of the wood fiber were observed by the compressive load and cyclic humidity history.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.2
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• pp.1-11
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• 2010

The possibility of applying birchwood xylan in papermaking process to improve dry strength of paper was investigated. Unmodified xylan barely adsorbed onto pulp fibers while cationically modified xylan adsorbed substantially. Adsorption of cationically modified xylan by quaternarization with 3-chloro-2-hydroxypropy trimethylammonium chloride improved dry strength of paper. Chemical structure and degree of substitution of the cationically modified xylan was determined by 400 MHz 13CNMR spectroscopy and elemental analyzer. The amount of adsorbed xylan on cellulose fibers was greater when the cationicity was moderate, and it was interpreted that the conformation of this cationic xylan adsorbed on fiber surface was more favorable for greater adsorption due to its greater loop formation tendency while highly cationic xylan tends to adsorbed in stretched conformation. The physical properties of handsheets increased as the amount of adsorbed cationic xylan increased. On the other hands, the optical properties decreased with xylan adsorption.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.37 no.4 s.112
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• pp.18-25
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• 2005

The mechanical strength is the prime requisite for linerboard and corrugating mediums. Repeatedly recycled OCC fibers show less suitable property for papermaking mostly due to hornification and reduced fiber length. To overcome these problems many researches including fractionation, enzymatic treatment, and chemical or mechanical treatments of fibers have been carried out. In this study, the effect of mechanical treatment by high consistency pulping on the characteristics of recycled fibers as well as mechanical properties of sheets were investigated. Results on the strength properties of handsheets made of recycled fibers that were treated to same freeness level by beating and high consistency pulping, respectively, showed that beating treatment was more efficient in improving strength. Drainage and recycling potential of the fibers treated by high consistency pulping, however, were expected to be superior to beating because fines content and fiber length didn't change significantly.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06a
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• pp.79-84
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• 2006

In order to improve filler-fiber bonding in paper, starch-filler composites were prepared by a starch-fatty acid complex formation method. These composites were used as a papermaking filler to improve the physical properties of the paper, filler retention and the sizing effect. The solubility of the starch-fatty acid complex in water at different temperatures was measured. The results indicated that the starch-fatty acid complexes have very low solubility in water below $70^{\circ}C$, which can be easily coated on clay surface to modify clay-fiber bonding ability. The clay-starch composite filled handsheets showed that paper strength could increase more than $100{\sim}200%$ compared to untreated clay. It was found that ZDT of the handsheet decreased as the clay content increased when unmodified clay was used, but it increased when the starch-fatty acid composite modified filler was used. It was also found that the presence of fatty acide in the complex increased the water-repellant property of the handsheet, which can be used to aid in sizing during papermaking. Filler distribution and bonding characteristics between the composite and fiber were investigated using Scanning Electron Microscopy(SEM).

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.39 no.4
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• pp.14-20
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• 2007

The effects of blending starches with different gelatinization temperatures on the development of ply-bond strength were systematically investigated using a three component mixture design technique. Oxidized corn starches with different gelatinization temperatures were blended with natural corn starch and sprayed for plybonding. Optimum blend ratio for maximizing plybond strength improvement for the starch blends was 40% of natural starch, 27% of oxidized starch with low gelatinization temperature and 33% of oxidized starch with high gelatinization temperature. Starch granules with the lowest gelatinization temperature gelatinizes at the lowest temperature, while the natural corn starch gelatinizes at later stage of drying. The improvement of plybond strength with starch blends were verified on machine trial as well. Plybond strength improvement obtained from the machine trial was lower than that achievable with handsheets, which was attributed to the lower internal bond strength of the linerboards made from recycled fibers.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.39 no.5
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• pp.1-6
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• 2007

Formation which is one of the most fundamental characteristic of paper quality is affected by a number of variables. Fiber flocculation in the headbox has been recognized as the most important variable influencing formation. Consistency and crowding number of head box stock are known to represent the flocculation potential of stocks. The effects of consistency and crowding number on paper formation were studied by measuring the flocculation of fiber suspensions. Increasing consistency increased the degree of fiber flocculation. Especially the consistency of long fiber fraction was the most crucial factor of flocculation. Tensile strength of handsheets was furnish dependent rather than flocculation dependent. Crowding number of a furnish can be used for the characterization of stock flocculation.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.47 no.3
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• pp.18-23
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• 2015

In this study, the effects of cationic fatty acid bulky promotor on the properties of BCTMP (bleached chemithermomechnical pulp) handsheet including bulk and strength were elucidated. As results, it was observed that the bulk of BCTMP handsheet increased with the increases of the concentration of cationic fatty acid bulky agent, while mechanical properties such as tensile strength and burst strength decreased. The opacity of BCTMP handsheet also increased with the increases of the concentration of cationic fatty acid bulky agent, while brightness was almost not changed. The effectiveness of bulky agent with SwBCTMP (softwood) was higher than that with HwBCTMP (hardwood). Compared with previous research on the effect of bulky agent on BKP handsheet, the bulk increase of BCTMP handsheet was greater compared to that of BKP handsheet. However, the reduction of mechanical property in BCTMP handsheet was lower than that of BKP handsheet.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.3
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• pp.11-20
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• 2011

The conditions to which pulp fibers are exposed during paper production, converting, storage, use, and recycling can induce various changes in fiber morphology, surface characteristics, and suitability for paper production by recycled fibers. Most of those changes can be described by hornification. Paper has highly hygroscopic properties which affect dimensional change by relative humidity variation of surrounding condition. The purpose of this study was to investigate the dimensional stability, moisture contents and dip elongation of handsheets at different relative humidity conditions of recycled kraft pulp and BCTMP. By using recycled fibers, dimensional stability was increased because hygroscopic properties of fibers decreased with repeated recycling treatment. Dip elongation of recycled pulp was higher than that of virgin pulp because of its weak fiber-to-fiber bonding. By recycling pulp, the relative bonded area was decreased because fiber could not swell more than virgin pulp. Dimensional stability largely depended on the equilibrium moisture contents of paper, the fiber-to-fiber bonding strength, and the relative bonded area.