• Title/Summary/Keyword: hand-calculated

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Structures of Ammonia Cluster Cations

  • 박종근
    • Bulletin of the Korean Chemical Society
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    • v.20 no.9
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    • pp.1067-1072
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    • 1999
  • Structures of unprotonated [(NH3)n+(n = 1-6)] and protonated [NH4+(NH3)n-1(n = 1-6)] ammonia cluster cations have been optimized with ab initio Hartree-Fock (HF) and second-order MФller-Plesset (MP2)/6-31+G ** levels and the harmonic vibrational frequencies have also been evaluated. In unprotonated cluster cations, NH3+ forms as a central core of the first ammonia solvation shell. In protonated cluster cations, NH4+ forms as a central core. In unprotonated dimer and trimer cations, there are two types of isomers (hydrogen-bonded and head-to-head interactions). In both cluster cations, the hydrogen-bonded isomers are more stable. In the hydrogen-bonded dimer cation, the proton transfer reaction takes place from (NH3-HN+H2) to (NH4+-NH2). But in the other unprotonated cluster cations, the proton transfer does not take place. In unprotonated pentamer and hexamer, a NH3+ core has both interactions in a complex. On the other hand, in unprotonated tetramer a core has only the hydrogen-bonded type combined with neutral ammonia molecules. With increasing cluster cation size, the bond lengths [R(NN)] between two nitrogen atoms and the distances [R(N ...H)] of the hydrogen-bond increase reg-ularly. In the calculated infra-red absorption bands for ammonia cluster cations, the characteristic peaks of the bridged NH vibration of the hydrogen-bonded clusters appear near 2500 cm-1 . With increasing size, the peaks shift from 2306 cm-1 to 2780 cm-1 .

A Time-Series Analysis of the Erosion and Deposition around Halmi-island, Baramarae (안면도 바람아래 할미섬 주변의 시계열적 침식·퇴적환경 변화 분석)

  • Yu, Jae Jin;Kim, Jang-soo;JANG, Dong-Ho
    • Journal of The Geomorphological Association of Korea
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    • v.23 no.1
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    • pp.47-60
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    • 2016
  • In this study, datum points measurement have been collected and then weather data have been analyzed to figure out erosion and deposition environmental change around Halmi-island, Baramarae. First of all, it was difficult to analyze geomorphological change which is caused by climate change because of quite short term of collection period of data. However, differences in spatial distribution of erosion and deposition have locally been shown. In all season, the wind is blowing in north and north-west direction mostly except in summer which is shifted to south direction. However, since its ratio which are above 5m/s is much lower than the north and north-west wind, its effect on geomorphological process is very tiny. In order to look at a tendency of erosion and deposition environmental change around Baramarae Halmi-island, the periphery of Halmi-island was classified to east and west part, then accumulated erosion and deposition values have been calculated. As a result, generally, the datum points are located in the west part which are mostly depositional sites. On the other hand, the datum points are located in east part showed the dominant erosion patterns.

The Effect of Coil Shape on the Electromagnetic Force in the Cylindrical Electromagnetic Pump Using Linear Traveling Traveling Magnetic Field (선형 이동 자기장을 사용한 원통형 전자기 펌프의 전자기력에 미치는 코일 모양의 영향)

  • 이경우;정순효;오영주;조영환;심재동
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.892-899
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    • 1995
  • A numerical simulation program based on the finite elerrent method is developed for calculating electromagnetic field of the cylindrical electromagnetic pump. The calculated results by the developed program show that Lorentz forces show maximum peak at an optimum length ($L_c$) of the induction coil. The value of $L_c$ depends on the radius of the molten metal when the skin depth is large. On the other hand, the value of $L_c$ depends on the skin depth when it is small.

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PMD Tolerance of 10 Gbps Modulated Signals due to SOA-Induced Chirp in SOA Booster Amplifiers

  • Jang, Ho-Deok;Kim, Kyoung-Soo;Lee, Jae-Hoon;Jeong, Ji-Chai
    • Journal of the Optical Society of Korea
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    • v.12 no.4
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    • pp.232-239
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    • 2008
  • We investigated how the polarization-mode dispersion (PMD) tolerance was degraded by semiconductor optical amplifier (SOA)-induced chirp for the 10 Gb/s nonreturn-to-zero (NRZ), duobinary NRZ, return-to-zero (RZ), and carrier-suppressed RZ (CS-RZ) modulation formats. The power penalty was calculated as a measure of the system performance due to PMD for a given SOA-induced chirp. Considering only first-order PMD, all modulation formats have a similar PMD tolerance regardless of SOA-induced chirp. On the other hand, when both first- and second-order PMD are considered, the PMD tolerance of all modulation formats with the exception of the CS-RZ modulation format are degraded by SOA-induced chirp. Among all modulation formats considered here, the NRZ modulation format has the PMD tolerance with the highest sensitivity to SOA-induced chirp. When the peak-to-peak chirp induced by SOAs is $0.28{\AA}$, its PMD tolerance is degraded up to 4 dB for a differential group delay (DGD) of 50 ps. However, the PMD tolerance of the CS-RZ modulation format is largely unaffected by SOA-induced chirp.

Effect of Virtual Reality Rehabilitation Program with RAPAEL Smart Glove on Stroke Patient's Upper Extremity Functions and Activities of Daily Living (라파엘 스마트 글러브를 이용한 가상현실 재활프로그램이 뇌졸중환자의 상지 기능과 일상생활활동 수행에 미치는 영향)

  • Kim, Koun
    • Journal of The Korean Society of Integrative Medicine
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    • v.7 no.2
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    • pp.69-76
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    • 2019
  • Purpose : This study examined the effects of a virtual reality rehabilitation program on stroke patients' upper extremity functions and activities of daily living (ADL). Methods : The subjects were equally and randomly divided into an experimental group (n=16) to whom a virtual reality rehabilitation program was applied and a control group (n=16) who received traditional occupational therapy. The intervention was applied five times per week, 30 minutes per each time, for six weeks. Jebsen-Taylor hand function test was conducted and the subjects' Manual Function Test was measured to examine their upper extremity functions before and after the treatment intervention, and a Korean version of modified Barthel index was calculated to look at their activities of daily living. Results : After the intervention, the upper extremity functions and activities of daily living of the participants in both groups significantly improved (p<.05). However, the improvements in these parameters among the participants in the virtual reality rehabilitation program were significantly greater than those in the control group (p>.05). Conclusion : The virtual reality rehabilitation program is a stable and reliable intervention method for enhancing the upper limb functions and activities of daily living of stroke patients.

Comparisons of Test-Retest Reliability of Strength Measurement of Gluteus Medius Strength between Break and Make Test in Subjects with Pelvic Drop

  • Jeon, In-Cheol
    • The Journal of Korean Physical Therapy
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    • v.31 no.3
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    • pp.147-150
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    • 2019
  • Purpose: The purpose of this study was to compare the reliability of unilateral hip abductor strength assessment in side-lying with break and make test in subjects with pelvic drop. Hip abduction muscles are very important in the hip joint structures. Therefore, it is essential to evaluate their strength in a reliable way. Methods: Twenty-five subjects participated in this study. Unilateral isometric hip abductor muscle strength was measured in side-lying, with use of a specialized tensiometer using smart KEMA system for make test, of a hand held dynamometer for break test. Coefficients of variation, and intra class correlation coefficients were calculated to determine test-retest reliability of hip abductor strength. Results: In make test, maximal hip abductor strength in the side-lying position was significantly higher compared with break test (p<0.05). Additionally, Test-retest reliability of hip abductor strength measurements in terms of coefficients of variation (3.7% for make test, 16.1% for break test) was better in the side-lying position with make test. All intraclass correlation coefficients with break test were lower than make test (0.90 for make test, 0.73 for break test). Conclusion: The side-lying body position with make test offers more reliable assessment of unilateral hip abductor strength than the same position with break test. Make test in side-lying can be recommended for reliable measurement of hip abductor strength in subjects with pelvic drop.

Motor Skill Learning on the Ipsi-Lateral Upper Extremity to the Damaged Hemisphere in Stroke Patients

  • Son, Sung Min;Hwang, Yoon Tae;Nam, Seok Hyun;Kwon, Yonghyun
    • The Journal of Korean Physical Therapy
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    • v.31 no.4
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    • pp.212-215
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    • 2019
  • Purpose: This study examined whether there is a difference in motor learning through short-term repetitive movement practice in stroke survivors with a unilateral brain injury compared to normal elderly participants. Methods: Twenty-six subjects who were divided into a stroke group (n=13) or sex-aged matched normal elder group (n=13) participated in this study. To evaluate the effects of motor learning, the participants conducted a tracking task for visuomotor coordination. The accuracy index was calculated for each trial. Both groups received repetitive tracking task training of metacarpophalangeal joint for 50 trials. The stroke group performed a tracking task in the upper extremity insi-lesional to the damaged hemisphere, and the normal elder group performed the upper extremity matched for the same side. Results: Two-way repetitive ANOVA revealed a significant difference in the interactions ($time{\times}group$) and time effects. These results indicated that the motor skill improved in both the stroke and normal elder group with a tracking task. On the other hand, the stroke group showed lesser motor learning skill than the normal elder group, in comparison with the amount of motor learning improvement. Conclusion: These results provide novel evidence that stroke survivors with unilateral brain damage might have difficulty in performing ipsilateral movement as well as in motor learning with the ipsilateral upper limb, compared to normal elderly participants.

Development of a reference framework to assess stylized human intrusion scenarios using GENII Version 2 considering design features of planned near-surface disposal facility in Korea

  • Kwon, Ki Nam;Cheong, Jae Hak
    • Nuclear Engineering and Technology
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    • v.51 no.6
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    • pp.1561-1574
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    • 2019
  • A standard form of six stylized human intrusion scenarios for a near-surface disposal facility (e.g. the planned Korean repository, Gyeongju Phase II) is proposed through re-categorization of totally thirty-one past cases reported in public literature. A reference assessment framework for inadvertent human intrusion is newly developed using GENII Version 2 conforming to the ICRP Publication 60 and thereafter. Calculated dose from the assessment framework is verified by comparing with hand calculation results for simplified model equations independently derived. Results from GENII Version 2 and 1.485 show inevitable differences, which is mainly attributed to the difference in the external dose assessment model. If intake dose coefficients in GENII Version 1.485 are modified, the difference can be reduced but still exist to an extent. Through deterministic and probabilistic sensitivity analysis, most affecting four parameters are derived and uncertainties of the parameters are quantified. It is expected that the reference assessment framework together with representative stylized scenarios can be used to do a human intrusion impact assessment for a specific repository using site-specific information. Especially, the past practice of human intrusion impact assessment using GENII Version 1.485 with or without modification may be replaced with the new assessment framework developed in this study.

A Baseball Batter Evaluation Model using Genetic Algorithm

  • Lee, Su-Hyun;Jung, Yerin;Moon, Hyung-Woo;Woo, Yong-Tae
    • Journal of the Korea Society of Computer and Information
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    • v.24 no.1
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    • pp.41-47
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    • 2019
  • In this paper, we propose a new batter evaluation model that reflects the skill of the opponent pitcher in Korean professional baseball. The model consists of evaluation factors such as Run Value, Contribution Score and Ball Consumption considering the pitcher grade. These evaluation factors are calculated as different data. In order to include the evaluation factors having different characteristics into one model, each evaluation factor is weighted and added. The genetic algorithms were used to calculate the weights, and the data were based on the 2016 records of Korea Professional Baseball and the salary data of the players of 2017. As a result of calculation of the weight, the weight of the Run Value was high and the weight of the Contribution Score was very low. This means that when calculating the annual salary, it reflects much of the expected score according to the batting result of the batter. On the other hand, the contribution score indicating the degree to which the batting result contributed to the victory of the team according to the state of the economy is not reflected in the salary or point system.

Surface Treatment of Eggshells with Low-Energy Electron Beam

  • Kataoka, Noriaki;Kawahara, Daigo;Sekiguchi, Masayuki
    • Journal of Radiation Protection and Research
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    • v.46 no.1
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    • pp.8-13
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    • 2021
  • Background: Salmonella enteritidis (SE) was the main cause of the pandemic of foodborne salmonellosis. The surface of eggs' shells can be contaminated with this bacterium; however, washing them with sodium hypochlorite solution not only reduces their flavor but also heavily impacts the environment. An alternative to this is surface sterilization using low-energy electron beam. It is known that irradiation with 1 kGy resulted in a significant 3.9 log reduction (reduction factor of 10,000) in detectable SE on the shell. FAO/IAEA/WHO indicates irradiation of any food commodity up to an overall average dose of 10 kGy presents no toxicological hazard. On the other hand, the Food and Drug Administration has deemed a dose of up to 3 kGy is allowable for eggs. However, the maximum dose permitted to be absorbed by an edible part (i.e., internal dose) is 0.1 Gy in Japan and 0.5 Gy in European Union. Materials and Methods: The electron beam (EB) depth dose distribution in the eggshell was calculated by the Monte Carlo method. The internal dose was also estimated by Monte Carlo simulation and experimentation. Results and Discussion: The EB depth dose distribution for the eggshells indicated that acceleration voltages between 80 and 200 kV were optimal for eggshell sterilization. It was also found that acceleration voltages between 80 and 150 kV were suitable for reducing the internal dose to ≤ 0.10 Gy. Conclusion: The optimum irradiative conditions for sterilizing only eggshells with an EB were between 80 and 150 kV.