• 제목/요약/키워드: h2 Separation

검색결과 1,283건 처리시간 0.023초

In-situ 성장법에 의한 ZIF-8 분리막 합성 및 H2/CO2 분리 특성 (In-situ Growth Synthesis of ZIF-8 Membranes and their H2/CO2 Separation Properties)

  • 이정희;유성종;김진수
    • 멤브레인
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    • 제28권2호
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    • pp.129-135
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    • 2018
  • ZIFs (Zeolitic imdazolate frameworks)은 높은 화학적 열적 안정성, 높은 비표면적과 조절 가능한 기공구조로 최근 분리막 소재로 큰 관심을 받고 있다. 본 연구에서는 두 가지 종류의 다공성 지지체(${\alpha}$-alumina 및 YSZ)를 사용하여 in situ 성장법으로 ZIF-8 분리막을 합성하고, $H_2/CO_2$ 기체 투과 특성을 조사하였다. 결함 없는 ZIF-8층을 합성하는데 있어, 기공이 작은 YSZ 지지체는 ${\alpha}$-alumina 지지체 보다 더 적은 시간이 요구되었다. 합성시간이 3 h인 경우, ${\alpha}$-alumina 및 YSZ 지지체위에 형성된 ZIF-8 분리막은 약 10 정도의 $H_2/CO_2$ 선택도를 보였다.

염산용액(鹽酸溶液)에서 PC88A와 D2EHPA에 의한 Nd와 Pr의 분리추출(分離抽出) (Solvent Extraction Separation of Nd and Pr from Chloride Solution using PC88A and D2EHPA)

  • 박주호;전호석;이만승
    • 자원리싸이클링
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    • 제22권5호
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    • pp.35-42
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    • 2013
  • Nd와 Pr이 함유된 염산용액에서 PC88A와 D2EHPA에 의한 두 금속의 분리에 적합한 조건을 조사하기 위해 용매추출실험을 수행하였다. 본 연구의 실험조건에서 Nd의 분배계수가 Pr의 분배계수보다 컸다. PC88A와 D2EHPA로 추출하는 경우 금속과 추출제와의 농도비의 증가가 두 금속의 추출 및 분리에 큰 영향을 미쳤다. D2EHPA의 비누화율과 초기 pH는 두 금속의 추출에는 큰 영향을 미치지만, 분리인자에는 큰 변화가 없었다.

Detection of Escherichia coli O157:H7 Using Combined Procedure of Immunomagnetic Separation and Test Strip Liposome Immunoassay

  • Kim, Myung-Hee;Oh, Se-Jong;Durst, Richard-A.
    • Journal of Microbiology and Biotechnology
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    • 제13권4호
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    • pp.509-516
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    • 2003
  • A model system for the immnunochemical detection of Escherichia coli O157:H7 using a combined immunomagnetic separation (IMS) and test-strip liposome immunoassay (LIA) procedure was developed. Immunomagnetic beads coated with anti-E. coli O157 IgG antibodies were used to separate the E. coli O157 (including the H7 serotype) from culture. Immunoliposomes, whose surface was conjugated to goat anti-E. coli O157:H7 IgG and which encapsulated the marker dye, sulforhodamine B, were used as a detection label. The test strip, onto which antibodies to goat IgG were immobilized, was the immunosensor capturing immunoliposomes that did not bind to E. coli O157:H7 on the immunomagnetic bead-E. coli O157:H7 complexes. In experiments, pure cell culture suspensions of $10^5 E.$ coli O157:H7 organisms per ml produced a measurable signal inhibition, whereas a weak yet detectable signal inhibition occurred with $10^3CFU/ml$. The inhibition signals increased, when the incubation time for IMS was extended to 90 min and higher IgG-tag density (0.4mol%) was used on the liposomes. With 0.2 and 0.4mol% IgG-tagged liposomes, the IMS-LIA procedure showed more improved signal inhibitions than those of a direct (no IMS) LIA. The combined assay, which measures the instantaneous signal from immunoliposomes, can be completed within 90 min, making it significantly faster than conventional plating methods and enzyme-linked immunosorbent assay (ELISA). Accordingly, it is quite feasible to use the combined immunoassay format of IMS and dye-loaded immunoliposomes for the detection of E. coli O157:H7.

경사각을 갖는 적층판식 유수분리기의 유수분리 효율에 관한 연구 (A Study on the Oil/Water Separation Efficiency of Laminated Plate Type Oily water Separator with Inclined Angle)

  • 한원희;김준효;최민선
    • Journal of Advanced Marine Engineering and Technology
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    • 제25권2호
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    • pp.365-374
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    • 2001
  • Its a tendency to strengthen related international was as the importance on marine oil pollution recently becomes the issue. According to the regulation of IMO, oil discharge from ships is allowed under 15PPM only and oil filtering equipment is essential. Oily water separator of laminated plate type which is one of gravity type separator can be use as assistant equipment for the oil filtering system to meet the present IMO standard, because it fits well to process large amount of rich oil with high specific gravity. The purpose of this paper is to investigate an efficiency of oil/water separation with the characteristics of laminated plate arrangement. The analyse of oil contents for oil-water mixture were carried out in order to find an efficiency of oil/water separation and an experimental study was simultaneously carried out to investigate internal flow characteristics of separator by visualization method and PIV(Particle Image Velocimetry) measurement at three spaces of plates for 5, 10 and 15 mm with variation of inlet flow rates of $0.25m^3$/h and $0.5m^3$/h. The experimental results showed that the space of the plates acts a significant role in the separating process.

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Gas Separation Membranes - Current Status

  • Puri, Pushpinder S.
    • 멤브레인
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    • 제6권3호
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    • pp.117-126
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    • 1996
  • Membrane-based gas separation systems are now widely accepted and employed as unit operation in industrial gas, chemical, and allied industries. Following their successful commercialization in the late seventies to recover hydrogen from ammonia purge gas streams, membrane-based systems have gained acceptance in a wide variety of applications. Numerous systems are in operation today to: recover hydrogen from other purge gas and hydrocarbon streams; adjust the $H_{2}/CO$ ratio in syngas; remove $CO_{2}$ from natural gas; recover helium; dry gas streams; and separate air. Lower cost, ease of operation, operational flexibility and portability are a few of the reasons membrane-based systems are chosen over absorption and cryogenic-based separations in certain applications.

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Proteome Approach as a Tool for the Efficient Separation of Seed Storage Proteins from Buckwheat

  • Cho, Seong-Woo;Kwon, Soo-Jeong;Roy, Swapan Kumar;Woo, Sun-Hee
    • 한국작물학회지
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    • 제60권1호
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    • pp.29-32
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    • 2015
  • Two-dimensional electrophoresis (2-DE) was executed to separate the seed storage proteins from the buckwheat. The proteins extracted from the whole seed proteins were better separated and observed in the use of lysis buffer. Using this method, the highly reproducible isoelectric focusing (IEF) can be obtained from polyacrylamide gels, and IEF from the polyacrylamide gel at all the possible pH range (5.0-8.0) was more easily separated than IPG (immobilized pH gradient) gels. The polyacrylamide gels in the first dimension in 2-DE was used to separate and identify a number of whole seed proteins in the proteome analysis. In this new apparatus using 2-DE, 27cm in length of plate coated with polyacrylamide gel was used and the experiment was further investigated under the various conditions.

HPLC에 의한 시호(柴胡) Saponin의 분리 및 정량 (Separation and Determination of Saikosaponins in Bupleuri Radix with HPLC)

  • 한대석;이덕근
    • 생약학회지
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    • 제16권3호
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    • pp.175-179
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    • 1985
  • The optimal condition for the determination of saikosaponin a and d, the major pharmacologically active saponins of the roots of Bupleurum falcatum, was studied with the conversion of these saponins into diene saponins $(saikosaponin\;b_1\;and\;b_2)$. The complete separation and quantitative analysis of these saponins were performed by the method of high performance liquid chromatography using $NH_2$ column. The conversion of saikosaponin a and d into diene saponins under gastric pH was calculated. Thirty-three percent of saikosaponin a was converted to saikosaponin $b_1$ and 63 percent of saikosaponin d was converted to saikosaponin $b_2$.

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부유선별법에 의한 제련용 몰리브덴 정광의 회수 (Recovery of Roasting-Molybdenite Concentrate by Froth Flotation)

  • 박철현;전호석;김병곤;한오형
    • 한국재료학회지
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    • 제19권12호
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    • pp.661-666
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    • 2009
  • Froth flotation has been carried out in order to produce roasting-molybdenite concentrate from molybdenite ore in the Shin-yeomi mine. In our study, roasting-molybdenite (Mo 0.43%) from Shin-yeomi mine was recovered by varying the conditions of regrinding time, dosage of collector and alkalinity. Liberation and flotation efficiency more were effective at regrinding time of six minutes than at single grinding. Mo recovery curves increased considerably as dosage of kerosene increased, whereas Mo grade curves decreased gradually. The separation efficiency of molybdenite was effective when the dosage of collector (kerosene) was adjusted to 300 g/t. The molybdenite concentrate was agglomerated in the range of pH 5-7 and its separation efficiency increased to pH 9-10. The concentrate of 49.5% Mo grade ($MoS_2$, 82.6%) with 81.5% recovery from Shin-yeomi molybdenite ores was obtained under conditions of 20% pulp concentration, 300 g/t kerosene 325 g/t frother (AF65), 2.5 kg/t depressant ($Na_2SiO_3$), pH 9-10 and four cleaning times. In the future, a trial run that can separate up to 50% Mo grade from Shin-yeomi molybdenite ores will be performed.

THE EFFECT OF CHICK SEPARATION ON PRODUCTIVITY OF THE HEN AND CHICK

  • Huque, Q.M.E.;Ebadul, M.H.;Rigor, E.M.
    • Asian-Australasian Journal of Animal Sciences
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    • 제3권2호
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    • pp.121-123
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    • 1990
  • A CRD experiment with unequal numbers of hens were assigned at random to three treatment groups, 1) separation of chicks from hen at 21 days after hatching 2) separation of chicks from hen at 7 days and 3) hens were allowed to brood the chicks(no separation) up to 10 weeks of age, to determine the productive and reproductive performance of hens and their chicks. The mean cycle length (one hatch to another) was 72.8 days for the 7-day group as compared with 87.7 days and 83.4 days for the 21-day and the no separation groups, respectively (p<.0l). The broody period was 28.5 days for the 7-day group compared with 43.9 and 42.6 days for the 21 days and the no separation groups, respectively (p<.0l). The end of the broody period to the start of lay varied from 8.0 to 8.7 days. The number of eggs laid per clutch were 12.3 for the 21-day group, compared with 11.5 and 10.1 for the 7-day and no separation groups, respectively (p<.05). This is due to the longer (p<.05) clutch length of the 21-day group as compared with the 7-day and no separation groups, respectively. The chicks separated from the hens at 21 and 7 days were heavier (p<.01) than the chicks not separated from the hens. Mortalities were highest (p<.05) for chicks separated at 7 days as compared with chicks separated at 21 days and those not separated. We concluded that separating chicks at 7 days from the hen gave the shortest cycle length and broody period, separating the chicks at 21 days gave the longest clutch length and the maximum number of eggs, separating the chicks at 21 and 7 days resulted in heavier chicks and separating the chicks at 7 days resulted in the highest mortality.

IPA 수용액으로부터 수분제거를 위한 침지형 모듈 제조와 투과증발 특성 (Pervaporation Performance of Submerged Type Membrane for the Separation of Water from Aqueous Isopropanol Solution)

  • 우승문;박윤환;남상용
    • 멤브레인
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    • 제28권4호
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    • pp.279-285
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    • 2018
  • 이소프로필알코올/물 혼합물은 가교된 폴리비닐알코올 복합막을 이용하여 투과특성평을 알아보았다. 검화도가 다른 3종 PVA를 이용하여 고분자의 농도와 GA 농도에 따라서 투과특성을 확인하였다. 복합막은 PVA 용액을 PAN 지지체 위에 캐스팅한 후, 열가교를 통해 제조하였다. PVA 농도가 증가할수록 투과도는 감소하지만 선택도는 증가하는 것을 확인하였다. PVA-3이 7 wt% 농도로 코팅된 복합막에서 $209g/m^2h$의 투과도를 가지고, 100 이상의 선택도를 가지는 것을 확인하였다. 침지형 분리막을 제조하여 feed tank 온도와 feed 용액의 IPA 농도에 따라서 투과실험을 확인하였다. 또한 IPA 수용액에 농축실험을 지속적으로 한 결과, 60시간 후에 IPA의 농도가 99%까지 증가하는 것을 확인하였다.