• 제목/요약/키워드: h2 Separation

검색결과 1,281건 처리시간 0.032초

납축전지 극판의 숙성 조건이 양극판의 화학적 조성에 미치는 영향 (Effects of Curing Conditions on the Chemical Compositions of Positive Plate for Lead Acid Battery Plates)

  • 구본근;정순욱
    • 한국응용과학기술학회지
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    • 제23권4호
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    • pp.347-354
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    • 2006
  • Generally, it has been known that positive plate efficiency is the most influential effect on the initial current capacity of lead acid battery. Thus, in this study, we have investigated the curing effect of the positive plate, which is one of the important lead acid battery processes. The curing process of the positive plate is performed either with the separation of each plate with 1mm gap or with no gap of plate. As a result, when there is no interval between each plate, the higher temperature current happened than expected, resulting in the changes in the initial current efficiency of the lead acid battery. The chemical composition and crystal structure of a material coated on the positive plate were identified with XRD and SEM. It was resulted that were only there not a lot of 4BS (tetrabasic-lead sulfate, $4PbO{\cdot}PbSO_4)$ on the plate in case of curing of plates without interval, but a large quantity of $Pb_3O_4$ also formed on the surface. On the other hand, it was observed that 3BS (tribasic-lead sulface, $3PbO{\cdot}PbSO_4{\cdot}H_2O)$ was the main product on the plate in case of typical curing process with some interval. From the initial current capacity test, the positive plate having 3BS was approximately 40% higher in initial current capacity than that having 4BS. It was concluded that 4BS and $Pb_3O_4$ on the plate surface were harmful to the initial current capacity of lead acid battery.

Ni-MH 2차 전지의 상온 및 저온 전극특성 최적화를 위한 첨가제 및 전해질 설계 (Design of Additives and Electrolyte for Optimization of Electrode Characteristics of Ni-MH Secondary Battery at Room and Low Temperatures)

  • 양동철;박충년;박찬진;최전;심종수;장민호
    • 한국수소및신에너지학회논문집
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    • 제18권4호
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    • pp.365-373
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    • 2007
  • We optimized the compositions of electrolyte and additives for anode in Ni-MH battery to improve the electrode characteristics at ambient and low temperatures using response surface method(RSM). Among various additives for anode, PTFE exhibited the greatest influence on the discharge capacity of the anode. Through response optimization process, we found the optimum composition of the additives to exhibit the greatest discharge capacity. When the amount of additives was too small, the anode was degraded with time due to the low binding strength among alloy powders and the resultant separation of powders from the current collector. In contrast, the addition of large amount of the additives increased in the resistance of the electrode. In addition, the discharge capacity of the anode at $-18^{\circ}C$ increased with decreasing the concentration of KOH, NaOH and LiOH in design range of electrolyte. The resistance and viscosity of electrolyte appear to affect the discharge capacity of the anode at low temperature.

두꺼운 난류경계층 내부에 놓인 직사각형 프리즘 주위의 유동구조 (Flow Structure Around a Rectangular Prism Placed in a Thick Turbulent Boundary Layer)

  • 김경천;지호성;추재민;이석호;성승학
    • 대한기계학회논문집B
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    • 제26권4호
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    • pp.578-586
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    • 2002
  • Flow structures around a rectangular prism have been investigated by using a PIV(Particle Image Velocimetry) technique. A thick turbulent boundary layer was generated by using spires arid roughness elements. The boundary layer thickness, displacement thickness and momentum thickness were 650mm, 117.4mm and 78mm, respectively. The ratio between the model height(40mm) and the boundary layer thickness H/$\delta$, was 0.06. The Reynolds number based on the free stream velocity and the height of the model was 7.9$\times$10$^3$. The PIV measurements were performed at three different wall normal planes. Three recirculation regions at forward facing step, top of the roof and backward facing step are clearly seen and show three dimensional features. Dramatic changes of flow patterns are observed in the wake regions in the different spanwise wall normal planes. Instead of reattachment and recirculation zone, rising streamlines are depicted at the normal planes near the side wall due to the interaction with a rising horse shoe vortex. The peak of turbulent kinetic energy occurs at the separation bubble on top of the roof and the magnitude is 2.5 times higher compared with that of the wake region.

고비로부터 Cinnamtannin B-1의 분리 및 함량 분석 (Isolation and Quantitative Analysis of Cinnamtannin B-1 from Osmunda japonica Thunb)

  • 김민석;우경완;이기호;이현주;이선유;강병만;전병훈;조정희;조현우
    • 생약학회지
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    • 제47권3호
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    • pp.232-236
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    • 2016
  • In traditional Korean medicine, Osmunda japonica Thunb has been used as hemostasis and antipyretic treatment. The main compound "cinnamtannin B-1" was obtained by column chromatographic separation, and its structure was determined by spectroscopic methods, including $^1H$, $^{13}C$ NMR, and IT-TOF-ESI MS. Ash, moisture and extract content and acidinsoluble ash were monitored as identification test to establish the analytical methods. The optimum reflux extraction condition was 100% methanol extracted 30 min for 2 times. A quantitative analysis using HPLC method exhibited that the main compound at 24.7 min and its content was 0.96% in methanol extraction.

곡물(穀物)의 공기선별(空氣選別)에 관(關)한 공기동력학적(空氣動力學的) 연구(硏究)(I) -수직풍동(垂直風胴)의 설계(設計)에 관(關)한 실험적(實驗的) 연구(硏究)- (Aerodynamic Study on Pneumatic Separation of Grains(I) -An Experimental Study on The Vertical Wind Tunnel-)

  • 이종호;조용진;김만수
    • Journal of Biosystems Engineering
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    • 제14권4호
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    • pp.272-281
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    • 1989
  • It is desirable for the vertical wind tunnel which can build uniform air flow across the vertical duct to be used for the purpose of the investigation of the aerodynamic properties of grains. This study was conducted to examine how the air velocity profile in the vertical duct is influenced by the various alternations of the elements of the wind tunnel, and to prepare design guidance of the vertical wind tunnel which can be used for investigating aerodynamic properties of grains. In addition, several tests were conducted to locate the test section which can be applicable for determining the terminal velocity of grain. The following conclusions were obtained from the study: 1. The size and the location of the outlet of the plenum chamber should be determined such that the outlet air flow is less affected by the air flow and the back pressure by the side wall of the chamber. 2. The honeycomb was not helpful for attaining uniform air flow in case that the air flow profile at the bottom of the vertical duct is serverely different from the ideal one. 3. Even though considerable pressure drop was resulted from the screens installed within the vertical duct, the screens were helpful for attaining uniform air flow in the duct. 4. It is desirable for the test section to be located at the position that not only the air flow of the duct is not disturbed by the distorted back pressure in the plenum chamber, but also less boundary layer is developed.

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항만내 파도응답과 계류선박의 운동해석(I) (Wave Responses and Ship Motions in a Harbor Excited by Long Waves(I))

  • 조일형;최항순
    • 대한조선학회논문집
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    • 제29권2호
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    • pp.38-47
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    • 1992
  • 본 연구에서는 항만내 파도응답과 항만안에 계류된 선박의 운동응답을 선형포텐셜이론으로 해석하고 모형시험을 수행하여 항만공진문제의 물리적 특성과 항만내 계류된 선박의 운동특성을 밝혔다. 유체영역을 해양과 항만영역으로 나누어 각 영역에서 경계치문제를 독립적으로 푼 다음, 두 영역의 해를 항만입구에서 정합하여 미지수를 구함으로써 선박에 입사하는 항만내 파도응답을 유도하였다. 선박에 작용하는 파기진력을 계산하고 선체운동에 따르는 동유체력을 해석하였다 얻어진 유체력을 이용하여 운동방정식을 풀어 선박의 운동변위를 구하였다. 사각형 항만안에 계류된 선박의 운동응답에 대한 실험을 수행한 결과 계산치와 실험치는 정성적으로 서로 비슷한 경향을 보이나 정량적으로 차이를 보이고 있음을 확인하였다. 여기서는 우선 선체운동중 대칭운동(전후동요-수직동요-종동요)만을 취급하였다. 비대칭운동(좌우동요-횡동요-선수동요)과 실험결과는 다음 기회에 발표할 예정이다.

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Synthesis, Characterization and Functionalization of the Coated Iron Oxide Nanostructures

  • Tursunkulov, Oybek;Allabergenov, Bunyod;Abidov, Amir;Jeong, Soon-Wook;Kim, Sungjin
    • 한국분말재료학회지
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    • 제20권3호
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    • pp.180-185
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    • 2013
  • The iron oxides nanoparticles and iron oxide with other compounds are of importance in fields including biomedicine, clinical and bio-sensing applications, corrosion resistance, and magnetic properties of materials, catalyst, and geochemical processes etc. In this work we describe the preparation and investigation of the properties of coated magnetic nanoparticles consisting of the iron oxide core and organic modification of the residue. These fine iron oxide nanoparticles were prepared in air environment by the co-precipitation method using of $Fe^{2+}$: $Fe^{3+}$ where chemical precipitation was achieved by adding ammonia aqueous solution with vigorous stirring. During the synthesis of nanoparticles with a narrow size distribution, the techniques of separation and powdering of nanoparticles into rather monodisperse fractions are observed. This is done using controlled precipitation of particles from surfactant stabilized solutions in the form organic components. It is desirable to maintain the particle size within pH range, temperature, solution ratio wherein the particle growth is held at a minimum. The iron oxide nanoparticles can be well dispersed in an aqueous solution were prepared by the mentioned co-precipitation method. Besides the iron oxide nanowires were prepared by using similar method. These iron oxide nanoparticles and nanowires have controlled average size and the obtained products were investigated by X-ray diffraction, FESEM and other methods.

Recycling of rayon industry effluent for the recovery and separation of Zn/Ca using Thiophosphinic extractant

  • Jha, M.K.;Kumar, V.;Bagchi, D.;Singh, R.J.;Lee, Jae-Chun
    • 한국자원리싸이클링학회:학술대회논문집
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    • 한국자원리싸이클링학회 2006년도 춘계임시총회 및 제27회 학술발표대회
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    • pp.78-85
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    • 2006
  • In textile industries, waste effluent containing zinc is generated during the manufacture of rayon yarn from the wood pulp or cotton linters. Due to the strict environmental regulations and the presence of toxic metallic and other constituents, the discharge of industrial effluents in the sewage or disposal of solid sludge as landfill is restricted. Before recycling of zinc as zinc sulphate solution to the spinning-bath of the rayon manufacturing plant the zinc sulphate solution must be free from calcium, which is deleterious to the process as gypsum precipitates with the increase in concentration and forms scale in the bath. In the present work an attempt has been made to develop a process following solvent extraction technique using thiophosphinic extractants, Cyanex 272 and 302 modified with isodecanol and diluted in kerosene to recover zinc from rayon effluent. Various process parameters viz. extraction of zinc from different concentration of solution, distribution ratio, selective extraction, O/A ratio on extraction and stripping from the loaded organic, complex formation in the organic phase etc. have been studied to see the feasibility of the process. The extractant Cyanex 302 has been found selective for the recovery of 99.99% of zinc from the effluent above equilibrium pH 3.4 maintaining the O/A ratio of 1/30 leaving all the calcium in the raffinate. It selectively extracted zinc in the form of complex $[R_{2}Zn.3RH]_{org}$ and retained all the calcium in the aqueous raffinate. The zinc from the loaded Cyanex 302 can be stripped with 10% sulphuric acid at even O/A ratio of 10 without affecting the stripping efficiency. The stripped solution thus obtained could be recycled in the spinning bath of the rayon plant. The raffinate obtained after the recovery of zinc could be disposed safely without affacting environment.

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Effects of Titratable Acidity and Organic Acids on Enamel Erosion In Vitro

  • Kim, Eun-Jeong;Jin, Bo-Hyoung
    • 치위생과학회지
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    • 제19권1호
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    • pp.1-8
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    • 2019
  • Background: Erosion is a gradual process that occurs fairly quickly, and the full extent of the erosive effects of acidic beverages is not yet clear. The present study aimed to determine the differences in the erosive potentials among four naturally acidic fruit nectars within the same range of titratable acidity and to determine the influence of the components of organic acids on tooth erosion. Methods: Diluted fruit nectars (mandarin 1:1.1, orange 1:1.7, lemon 1:15, grapefruit 1:20) with the same range of titratable acidity (7.9 ml) and their corresponding organic acids (0.05%, 0.1%, 0.3%, and 0.5% citric acid, malic acid, and a citric and malic acid mixture [pH 2.8], respectively) were used. Specimens were placed in conical tubes with 50 ml of each of the test solutions for 1 hour. A microhardness test and scanning electron microscopy were used to measure enamel erosion. Acid separation was carried out using high-performance liquid chromatography to analyze the composition of each test solution. Results: Similar decreases in the Vickers hardness number (VHN) were observed among the groups treated with the following diluted fruit nectars: diluted mandarin nectar ($75.9{\Delta}VHN$), diluted lemon nectar ($89.1{\Delta}VHN$), diluted grapefruit nectar ($91.7{\Delta}VHN$), and diluted orange nectar ($92.5{\Delta}VHN$). No statistically significant differences were found in the enamel surface hardness after erosion (p>0.05). Citric and malic acids were the major organic acids in the test fruits. The lemon and orange groups had the highest malic acid concentrations, and the mandarin group had the lowest malic acid concentration. Conclusion: The titratable acidity and the citric and malic acid contents of the fruits could be crucial factors responsible for enamel erosion. Therefore, fruit-based drinks should be regarded as potentially erosive.

Experimental Applications of in situ Liver Perfusion Machinery for the Study of Liver Disease

  • Choi, Won-Mook;Eun, Hyuk Soo;Lee, Young-Sun;Kim, Sun Jun;Kim, Myung-Ho;Lee, Jun-Hee;Shim, Young-Ri;Kim, Hee-Hoon;Kim, Ye Eun;Yi, Hyon-Seung;Jeong, Won-Il
    • Molecules and Cells
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    • 제42권1호
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    • pp.45-55
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    • 2019
  • The liver is involved in a wide range of activities in vertebrates and some other animals, including metabolism, protein synthesis, detoxification, and the immune system. Until now, various methods have been devised to study liver diseases; however, each method has its own limitations. In situ liver perfusion machinery, originally developed in rats, has been successfully adapted to mice, enabling the study of liver diseases. Here we describe the protocol, which is a simple but widely applicable method for investigating the liver diseases. The liver is perfused in situ by cannulation of the portal vein and suprahepatic inferior vena cava (IVC), with antegrade closed circuit circulation completed by clamping the infrahepatic IVC. In situ liver perfusion can be utilized to evaluate immune cell migration and function, hemodynamics and related cellular reactions in each type of hepatic cells, and the metabolism of toxic or other compounds by changing the composition of the circulating media. In situ liver perfusion method maintains liver function and cell viability for up to 2 h. This study also describes an optional protocol using density-gradient centrifugation for the separation of different types of hepatic cells, allowing the determination of changes in each cell type. In summary, this method of in situ liver perfusion will be useful for studying liver diseases as a complement to other established methods.