• Title/Summary/Keyword: h{\bar{o}}$

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The Ir(PPh$_3)_2\;(CO)OClO_3\;and\;Ir(PPh_3)_3N_2Cl$ Mediated Activation of Aldehyde C-H Bonds via Chelate-Assisted Oxidative Addition

  • Ko, Jae-Jung;Joo, Wan-Chul;Kong, Young-Kun
    • Bulletin of the Korean Chemical Society
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    • 제7권5호
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    • pp.338-341
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    • 1986
  • Hydrocarbon solution of $Ir(PPh_3)_2(CO)OClO_3$ reacts with $Ph_2PC_6H_4$-o-CHO and 3-methyl-2-aminopyridinyl aldimine to yield ${\bar{Ir(Ph_2PC_6H_4-o-CO)}}\;(PPh_3)_2(CO)(H)ClO_4$(1) and ${\bar{Ir(NC_6H_6NC}}C_6H_5)(PPh_3)_2(CO)(H)ClO_4$(2), respectively. The compound $Ir(PPh_3)_2N_2Cl$ also reacts with $Ph_2PC_6H_4$-o-CHO and 3-methyl-2-aminopyridinyl aldimine to give ${\bar{Ir(Ph_2PC_6H_4-o-C}}O)(PPh_3)_2(H)Cl(3)$ and $Ir(NC_6H_5NCC_6H_5(PPh_3)_2(H)Cl(4)$, respectively. Compounds 1, 2, 3, and 4 were characterized by infrared, $^1H$ NMR, $^{31}p$ NMR, UV spectra, and conductivity measurements.

Development of Mg-xFe2O3-yNi Hydrogen-Storage Alloys by Reactive Mechanical Grinding

  • Song, Myoung Youp;Kwon, Sung Nam;Park, Hye Ryoung
    • 대한금속재료학회지
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    • 제50권10호
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    • pp.769-774
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    • 2012
  • Mg-x wt% $Fe_2O_3-y$ wt% Ni samples were prepared by reactive mechanical grinding in a planetary ball mill, and their hydrogen-storage properties were investigated and compared. Activations of $Mg-5Fe_2O_3-5Ni$ was completed after one hydriding (under 12 bar $H_2$) - dehydriding (in vacuum) cycle at 593 K. At n = 2, $Mg-5Fe_2O_3-5Ni$ absorbed 3.43 wt% H for 5 min, 3.57 wt% H for 10 min, 3.76 wt% H for 20 min, and 3.98 wt% H for 60 min. Activated $Mg-10Fe_2O_3$ had the highest hydriding rate, absorbing 2.99 wt% H for 2.5 min, 4.86 wt% H for 10 min, and 5.54 wt% H for 60 min at 593 K under 12 bar $H_2$. Activated $Mg-10Fe_2O_3-5Ni$ had the highest dehydriding rate, desorbing 1.31 wt% H for 10 min, 2.91 wt% H for 30 min, and 3.83 wt% H for 60 min at 593 K under 1.0 bar $H_2$.

전기 영화가 인물과 역사를 소환하는 한 방식에 대해 - 영화 <황금시대>를 중심으로 (On a Way in which Biographical Film Summons Character and History - Focusing on the Film, The Golden Era -)

  • 진성희
    • 비교문화연구
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    • 제39권
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    • pp.287-308
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    • 2015
  • Biographical film is a genre narrativizing the actual person and history, and reproducing the character and history in a biographical film is in a dimension different from a film focused on a fiction. Discussion between these methods of narrative composition and image reproduction in a biographical film is also, in line with artistic/aesthetic problems and ethical/philosophical theses of the film text. This study discusses the phase of the way of reproduction of the actual person, $Xi{\bar{a}}o$ $H{\acute{o}}ng$ in the biographical film, The Golden Era and the time she lived in a biographical film and how the audience's discussion of the film and socio-cultural discourse differ depending on their attitude towards the cinematic introspection of the text. The narrative structure, the method of image reproduction and cinematic devices of the film, The Golden Era are completely off the point of the general format of the traditional biographical film. In The Golden Era, $Xi{\bar{a}}o$ $H{\acute{o}}ng$ and the history which she lived in did not revive depending on an omniscient subject's selective statement and meta-film structure. Ann Hui removed general, mythic images of $Xi{\bar{a}}o$ $H{\acute{o}}ng$ formed in the field of traditional Chinese culture and reproduced her through multilateral visions of a real, fictional narrator. Each spectator's judgment and interpretation of the film intervene in the multi-layered and sparse descriptions of the actual person's images and the era of the characters. Through this, it is possible to approach the uniqueness and authenticity a historical character, $Xi{\bar{a}}o$ $H{\acute{o}}ng$ and to have an opportunity of multi-layered reflection on how to secure a critical distance and make a perception in historical judgment.

GENERALIZED H$\ddot{O}$LDER ESTIMATES FOR THE $\bar{\partial}$-EQUATION ON CONVEX DOMAINS IN $\mathbb{C}^2$

  • Cho, Hong-Rae;Seo, Yeon-Seok
    • East Asian mathematical journal
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    • 제25권2호
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    • pp.221-227
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    • 2009
  • In this paper, we introduce the generalized H$\ddot{o}$lder space with a majorant function and prove the H$\ddot{o}$lder regularity for solutions of the Cauchy-Riemann equation in the generalized Holder spaces on a bounded convex domain in $\mathbb{C}^2$.

Solving Sangaku: A Traditional Solution to a Nineteenth Century Japanese Temple Problem

  • Hosking, Rosalie Joan
    • 한국수학사학회지
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    • 제30권2호
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    • pp.53-69
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    • 2017
  • This paper demonstrates how a nineteenth century Japanese votive temple problem known as sangaku from Okayama prefecture can be solved using traditional mathematical methods of the Japanese Edo (1603-1868 CE). We compare a modern solution to a sangaku problem from Sacred Geometry: Japanese Temple Problems of Tony Rothman and Hidetoshi Fukagawa with a traditional solution of ${\bar{O}}hara$ Toshiaki (?-1828). Our investigation into the solution of ${\bar{O}}hara$ provides an example of traditional Edo period mathematics using the tenzan jutsu symbolic manipulation method, as well as producing new insights regarding the contextual nature of the rules of this technique.

HÖLDER ESTIMATES FOR THE CAUCHY-RIEMANN EQUATION ON PARAMETERS

  • Cho, Sang-Hyun
    • 대한수학회지
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    • 제48권2호
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    • pp.241-252
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    • 2011
  • Let $\{\Omega_{\tau}\}_{\tau{\in}I}$ be a family of strictly convex domains in $\mathbb{C}^n$. We obtain explicit estimates for the solution of the $\bar{\partial}$-equation on $\Omega{\times}I$ in H$\ddot{o}$lder space. We also obtain explicit point-wise derivative estimates for the $\bar{\partial}$-equation both in space and parameter variables.

구중질환(口中疾患)의 침구치료(鍼灸治療)에 관한 고찰(考察) (A study of Literature Review on the acupuncture and moxibution treatments for stomatopathy)

  • 윤현민;안창범;김철홍
    • Korean Journal of Acupuncture
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    • 제21권1호
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    • pp.175-199
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    • 2004
  • Objectives : To study acupuncture and moxibution treatments for stomatopathy( aphthae, oral ulceration, mycolic stomatitis, halitosis, thirst, bitter) the ancient and the present literatures were reviewed. Methods : We've got compared and analyzed 55 kinds of literatures. Results and Conclusions : 1. The acupuncture meridians used frequently for stomatopathy were $Su-yangmy\bar{o}ng-Taejang-ky\bar{o}ng(LI),\;Chok-yangmy\bar{o}ng-Wi-Ky\bar{o}ng(S),\;Immaek-Ky\bar{o}ng(CV)$. 2. The acupoints used frequently for aphthae were $Sungjang(CV_{24}),\;Yomchon(CV_{23}),\;Hapkok(LI_4),\;Nogung(P_8),\;Chok-samni(S_{36}),\;Hyopko(S_6),\;Sugu(GV_{26})$. 3. The acupoints used frequently for oral ulceration were $Hapkok(LI_4),\;Nogung(P_8),\;Chok-samni(S_{36}),\;Kokchi(LI_{11}),\;Sotaek(SI_1),\;Pisu(B_{20}),\;Wisu(B_{21}),\;Samgan(LI_3),\;Yomchon(CV_{23}),\;Chichang(S_4)$. 4. The acupoints used frequently for mycolic stomatitis were $Hapkok(L_4),\;Chichang(S_4),\;Hyopko\;(LI_4),\;Sungjang(CV_{24}),\;Samumgyo(SP_6)$. 5. The acupoints used frequently for halitosis were $Naejong(S_{44}),\;Chok-samni(S_{36}),\;Chung-wan\;(CV_{12}),\;Sang-wan(CV_{13}),\;Hawan(CV_{10}),\;Kongson(SP_4),\;Wisu(B_{21}),\;Nogung(P_8),\;Sugu(GV_{26}),\;Sungjang(CV_{24})$. 6. The acupoints used frequently for thirst were $Sosang(L_{11}),\;Sangyang(LI_1),\;Sotaek(SI_1),\;Kwanch'ung(TE_1),\;Ch'\bar{o}kt'aek(L_5),\;T'ae-gye(K_3),\;Kokt'aek(P_3),\;Sugu(GV_{26}),\;Samgan(LI_3),\;Igan(LI_2),\;T'aech'ung(Liv_3),\;Sojangsu(B_{27})$. 7. The acupoints used frequently for bitter were $Yangn\bar{u}ngch'\bar{o}n(G_{34}),\;Hy\bar{o}njong(G_{39}),\;Kwanch'ung(TE_1),\;Tamsu(B_{19}),\;Chokkyu\bar{u}m(G_{44}),\;Y\bar{o}n-gok(K_2),\;Shinmun(H_7),\;Chok-Samni(S_{36})$.

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요폐환자(尿閉患者) 1례(例)에 대한 임상적(臨床的) 고찰(考察) (Clinical Study on 1 Case of patient with Urinary Retention)

  • 김재형;조충식;김철중
    • 혜화의학회지
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    • 제14권1호
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    • pp.43-49
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    • 2005
  • One case of patient with urinary retention was reported in this clinical study. After the study, the results were as follows: 1. Anulesis belongs to l$\acute{o}$ng-bi(癃閉) in oriental medicine and the patient of this case belongs to chronic anulesis. 2. The patient of this case was thought as broke out anuresis by vesical nerve palsy of diabetic bladder pathy and sequela of stroke, and ischuria of long lie down 3. The patient of this case changeable process is supposed to urinary frequency, 'bi(閉)', 'l$\acute{o}$ong(癃)', urinary incontinence and urinary frequency. 4. First time of drug treatment is GAMIPHALJENG-SAN(ji$\bar{a}$-w$\grave{e}$i-b$\bar{a}$-h$\bar{e}$ng-s$\check{a}$n) by oral administration that action of alleviate a fever, water utilization and metaphase, convalescence time of drug treatment is PHALMIWANGAMI (b$\bar{a}$-w$\grave{e}$i-w$\acute{a}$n-ji$\bar{a}$-w$\grave{e}$i), YIKLUENG-TANG(yi-ling-t$\bar{a}$ng), CHUKYOO-TANG(s$\grave{u}$-ni$\grave{a}$o-t$\bar{a}$ng) that action of recreation. 5. Accupuncture treatment is s$\bar{a}$n-x$\bar{i}$ng-xuw$\acute{e}$, zw$\acute{u}$-s$\bar{a}$n-li, qi-h$\check{a}$i, gu$\bar{a}$n-yu$\acute{a}$n, zh$\bar{o}$ng-ji by mild supplementing and reducing manipulation of needle and heat accupuncture is qi-h$\check{a}$i, gu$\bar{a}$n-yu$\acute{a}$n, zh$\bar{o}$ng-ji-xu$\acute{e}$. 6. The other treatment is a sitz bath that prevent of urinary tract infection, and relieve of initial acute auresis by using of urethral catheterization.

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과산화수소/케로신 점화용 분사기 설계 및 분무특성에 관한 연구 (A Study of Design of $H_2O_2$/Kerosene Ignition Injector and Spray Characteristics)

  • 김보연;황오식;이양석;고영성;김유;김선진
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2009년도 춘계학술대회 논문집
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    • pp.37-40
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    • 2009
  • 본 연구에서는 케로신/과산화수소 점화용 분사기의 설계/제작하여 분무특성에 관한 연구를 수행하고자 하였으며, 이에 앞서 촉매점화방식으로 적용할 때 가장 적합한 분사기를 설계하고자 하였다. 설계/제작된 분사기를 수류시험을 통해 질량 유량 및 분산각을 측정하였다. 그 결과 케로신의 목표 질량유량(12.88 g/s)은 설계 차압과 같은 차압인 3 bar에서 측정되었으며, 이 때 분산각은 $40^{\circ}$을 확인하였다. 또한 과산화수소의 목표 질량 유량(94.39 g/s)은 설계 차압(3 bar) 보다 작은 1 bar에서 측정됨을 확인하였다.

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한개의 산소다리를 가진 몰리브덴(V) 착물의 산소고리화 반응 (제 3 보). 2 성분 혼합용매에서 용매물과 $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$의 반응 (Oxygen Ring Formation Reaction of Mono-Oxo Bridged Binudear Molybdenum (Ⅴ) Complex (Ⅲ). Reaction of $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ with solvent Water in Binary Aqueous Mixtures)

  • 오상오;석휘영
    • 대한화학회지
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    • 제32권6호
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    • pp.528-535
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    • 1988
  • 이성분 혼합용매 속에서 $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$의 산소고리화 반응에 대한 속도론적 연구는 분광광도법으로 수행되었다. 이 때 온도는 $20^{\circ}C$ 에서 $40^{\circ}C$, 압력은 1bar에서 1500 bar로 변화시켰다. 관찰된 속도 상수는 수소이온 농도의 증가에 따라 증가하고 티오시안이온 농도의 증가에 따라서는 감소한다. 공용매의 유전상수가 증가할수록 더욱 안정한 중간체가 형성된다. 관찰된 속도상수는 $k_{obs}^{-1} = k^{-1} (1 + K^{-1}[H_2O]^{-1})로 주어진다. 모든 활성화파라미터는 양의 값이다. [Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$의 산소고리화 반응은 Id 메카니즘에 의해 진행된다.

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