• Title/Summary/Keyword: group ring

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THE HILBERT-KUNZ MULTIPLICITY OF TWO-DIMENSIONAL TORIC RINGS

  • Choi, Sang-Ki;Hong, Seok-Young
    • Journal of the Korean Mathematical Society
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    • v.40 no.2
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    • pp.169-177
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    • 2003
  • Recently, K. Watanabe Showed that the Hilbert-Kunz multiplicity of a toric ring is a rational number. In this paper we give an explicit formula to compute the Hilbert-Kunz multiplicity of two-dimensional toric rings. This formula also shows that the Hilbert-Kunz multiplicity of a two-dimensional non-regular toric ring is at least 3/2.

Synthesis of 4'α-C Phenyl-Branched Carbocyclic Nucleoside Using Ring-Closing Metathesis

  • Hong, Joon-Hee;Ko, Ok-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.24 no.9
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    • pp.1289-1292
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    • 2003
  • An efficient synthetic route for preparing novel $4'{\alpha}$-C phenyl branched carbocyclic nucleoside is described. The installation of phenyl group at the $4'$-position of carbocyclic nucleoside was successfully accomplished via a sequential [3,3]-sigmatropic rearrangement and ring-closing metathesis (RCM) beginning from simple ketone such as 2-hydroxy acetophenone.

2-(Multimethoxyphenyl)-4-methylene-1,3-dioxolane: (III) Polymerization of 2-(2,4-Dimethoxyphenyl)-4-methylene-1,3-dioxolane with Various Cationic Catalysts

  • 장원철;배장순;공명선
    • Bulletin of the Korean Chemical Society
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    • v.20 no.12
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    • pp.1433-1436
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    • 1999
  • The 2-(2,4-dimethoxyphenyl)-4-MDO (2) underwent polymerization with ring opening as well as cyclization reaction in the presence of various cationic catalysts such as boron trifluoride, trifluoromethanesulfonic acid, p-toluenesulfonic acid, hydrochloric acid and trifluoroacetic acid. They afforded a mixture of the ring-opened poly(keto ether) and 3(2H)-dihydrofuranone derivative. Both the methylene group and oxygen atom of 1,3-dioxolane ring were participated in the reaction with cationic catalyst. The contents of the polymer and cyclization product were variable according to the acid strength of the cationic catalysts.

THE APPLICATIONS OF ADDITIVE MAP PRESERVING IDEMPOTENCE IN GENERALIZED INVERSE

  • Yao, Hongmei;Fan, Zhaobin;Tang, Jiapei
    • Journal of applied mathematics & informatics
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    • v.26 no.3_4
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    • pp.541-547
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    • 2008
  • Suppose R is an idempotence-diagonalizable ring. Let n and m be two arbitrary positive integers with $n\;{\geq}\;3$. We denote by $M_n(R)$ the ring of all $n{\times}n$ matrices over R. Let ($J_n(R)$) be the additive subgroup of $M_n(R)$ generated additively by all idempotent matrices. Let ($D=J_n(R)$) or $M_n(R)$. In this paper, by using an additive idem potence-preserving result obtained by Coo (see [4]), I characterize (i) the additive preservers of tripotence from D to $M_m(R)$ when 2 and 3 are units of R; (ii) the additive preservers of inverses (respectively, Drazin inverses, group inverses, {1}-inverses, {2}-inverses, {1, 2}-inverses) from $M_n(R)$ to $M_n(R)$ when 2 and 3 are units of R.

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The Correlation Between Conformations and Activities of ${\omega}$-Pyridylalkenoic Acids (${\omega}$-피리딜 알켄산의 형태와 활성간의 상관관계)

  • Rhee, Jong-Dal;Doh, Seong-Tak
    • YAKHAK HOEJI
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    • v.41 no.3
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    • pp.298-304
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    • 1997
  • Molecular mechanics and conformation search methods were carried oyt to investigate the relationship between conformations and thromboxane synthetase ingibitory activities of om ega-pyridylalkenoic acids. The initial geometries of ${\omega}$-pyridylalkenoic acids and heme part of cytochrome P-450 were obtained from MM+ geometry optimization. The bond lenths and angles were not varied by step during the conformation searching. Stable conformers of some ${\omega}$-pyridylalkenoic acids were obtained by comformational search method. The distances were 8.5~10.8 ${\AA}$- between N atom at 3-position of pyridine ring and C atom at carboxylic group of stable ${\omega}$-pyridylalkenoic acids. The conformations of ${\omega}$-pyridylalkenoic acids and heme part complex were determined by same method. In theses structures, benzene ring and ethylene group in ${\omega}$-pyridylalkenoic acids are making the structure more rigid and increase inhbitory activity. The electron donating groups in C atom shich is connected to pyridine ring also increase activity.

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Evaluation of HIC/SSCC Resistance for API-X70 Pipe Manufactured by JCO Bending Process and SA Welding (JCO 밴딩과 SA용접으로 제조된 API-X70급 강관의 HIC/SSCC 저항성 평가)

  • Ryoo, Hoi-Soo;Kim, Hee Jin;Lee, Dong-Eon
    • Journal of Welding and Joining
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    • v.32 no.5
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    • pp.1-6
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    • 2014
  • This study aims at manufacturing SA welded API-X70 line-pipe with sour gas resistance. A pipe was manufactured by JCO bending process and SA welding using the API-X70 plate guaranteed HIC resistance. SA welded pipe was expanded in order to reduce the residual stress. The evaluation of a pipe for resistance to HIC and SSCC were performed by the RS D 0004 and RS D 0005 standards. For verification that a pipe has acceptable resistance to HIC, fullscale test was carried out. Results showed no cracking for the HIC and SSCC.

Secondary Thickening of the Stem in Amaranthus hybridus subsp. cruentus (L.) Thell.

  • Oladele, F.A.
    • Journal of Plant Biology
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    • v.29 no.2
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    • pp.129-133
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    • 1986
  • Transections of the stem region close to the shoot apex show the occurrence of an outer, complete ring of procambium and an inner group of discrete procambial strands. From the outer ring, small, discrete vascular bundles and vascular cambium originate, while the inner group forms the discrete, medullary vascular bundles with intrafascicular cambium. Secondary thickening is essentially due to the activity of the cylinder or complete ring of vascular cambium that originates from the procambium. The medullary intrafascicular cambia also form some secondary tissues. The vascular cambium produces secondary xylem inwards and secondary phloem outwards as in the normal secondary thickening process. The distinctive feature, however, is perpetual discreteness of the medullary vascular bundles. No successive series of cambia or secondary vascular bundles are found.

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First Total Synthesis of Highly Anti-Inflammatory Active Licochalcone D Through Water-Accelerated [3,3]-Sigmatropic Rearrangement

  • Kim, Si-Jun;Jun, Jong-Gab
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.54-58
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    • 2013
  • Licochalcones, derived from the dried roots of Glycyrrhiza inflata, have been reported to show various biological activities including antitumor, antiparasitic, antileishmanial, antioxidative, superoxide scavenging, antibacterial, and PTP1B activity. Licochalcone D has an allyl group on ring A instead of ring B, however, most other natural licochalcones possess the group on ring B. Total synthesis of licochalcone D has not been reported even possessing the strongest anti-inflammatory activity. Therefore, the first total synthesis of licochalcone D has been developed by using water-accelerated [3,3]-sigmatropic rearrangement method.

[ $SRV^{(R)}$ ]-Testing of the Tribosystem Piston Ring and Cylinder Liner Outside the Engine

  • Woydt Mathias;Ebrecht Johannes
    • KSTLE International Journal
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    • v.6 no.2
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    • pp.58-64
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    • 2005
  • An OEM driven working group started in January 2004 to elaborate the philosophies, concepts and test procedures for testing piston ring and cylinder liner materials as well as engine oils outside the engine using the $SRV^{(R)}$ test equipment. The different $SRV^{(R)}$ test philosophies in use by OEMs are compiled. The working group focuses on a.) ASTM sequence VIB (Fuel economy by aging oils), b.) friction and wear in the top dead region under mixed/boundary lubrication, c.) extreme pressure load under mixed/boundary lubrication and d.) hydrodynamic friction. Tribological test result and precision data are presented.

Theoretical Studies on Phentl Group Migration of Protonated 1,2-Diphenyl Hydrazines

  • Kim, Chan Gyeong;Lee, In Yeong;Kim, Jang Geun;Lee, Ik Chun
    • Bulletin of the Korean Chemical Society
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    • v.21 no.5
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    • pp.477-482
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    • 2000
  • Phenyl group migration within protonated 1,2-diphenyl hydrazines has been studied theoretically using the semi-empirical AM1 method. This reaction proceeds through a 3-membered cyclic transition state and requires high activation energy. In the reactant, there was no resonance stabilization for the moving Z-ring, however, hammett $p_Z^+$ values are large due to the direct involvement of the Z-ring inthe reaction, and the development of a negative charge on the reaction center gives them a posifive value. In the case of the non-moving ring, $p_Y^+$ values are small and negative owing to the smaller positive charge increase in the reaction center. The cross-interaction constant, $p_YZ^+$, was obtained from the activation enthalpies, using the multipe linear regression methdo, and the interaction between two substituents, Y and Z, is examined.