• Journal of Korean Society for Atmospheric Environment
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• v.24 no.E2
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• pp.63-73
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• 2008

In this study, neural network models (NNMs) were examined as alternatives to dispersion models in predicting the short-term $SO_2$ concentrations in a coastal area because the performances of dispersion models in coastal areas have been found to be unsatisfactory. The NNMs were constructed for various combinations of averaging time and prediction time in advance by using the historical data of meteorological parameters and $SO_2$ concentrations in 2002 in the coastal area of Boryeung, Korea. The NNMs were able to make much more accurate predictions of 1 hr $SO_2$ concentrations at ground level in the morning in coastal area than the atmospheric dispersion models such as fumigation models, ADMS3 and ISCST3 for identical conditions of atmospheric stability, area, and weather. Even when predictions of 24-h $SO_2$ concentrations were made 24 hours in advance, the predictions and measurements were in good accordance(correlation coefficient=0.65 for n=216). This accordance level could be improved by appropriate expansion of training parameters. Thus it may be concluded that the NNMs can be successfully used to predict short-term ground level concentrations averaged over time less than 24 hours even in complex terrain. The prediction performance of ANN models tends to improve as the prediction lagging time approaches the concentration averaging time, but to become worse as the lagging time departs from the averaging time.

• International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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• v.24 no.1
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• pp.29-45
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• 1996

Before (March 26, 1994) or after the occurrence of a downslope windstorm (March 29), the NO, $NO_2$, and $SO_2$ at the ground level of Kangnung city were monitored with high concentrations in the afternoon, due to a large amount of gases emitted from combustion of motor vehicle and heating apparatus, especially near 1600-1800 LST and 2000-2100 LST, but at night, they had low concentrations, resulting from small consumptions of vehicle and heating fuels. When both moderate westerly synoptic-scale winds flow over Mt. Taegwallyang and easterly meso-scale sea breeze during the day, atmospheric pollutants should be trapped by two different wind systems, resulting in higher concentration at Kangnung city in the afternoon. At night, the association of westerly synoptic wind and land breeze can produce relatively strong winds and the dissipation by the winds cause these low concentrations to lower and lower, as nightime goes on. From March 27 through 28, an enforced localized windstorm could be produced along the lee side of the mountain near Kangnung, generating westerly internal gravity waves with hydraulic jump motions. Sea breeze toward inland appartantly confines to the bottom of the eastern side of the mountain, due to the interruption of eastward violent internal gravity waves. As the windstorm moves down toward the ground, an encountering point of two opposite winds approaches Kangnung, and a great amount of NO and $NO_2$ were removed by the strong surface winds. Thus, their maximum concentrations are found to be near 18 and 20 LST, 17 and 21 LST. In the nighttime, the more developed storm should produce very strong surface winds and the NO and $NO_2$ could be easily dissipated into other place. The $SO_2$ concentration had no maximum value, that is, almost constant one all day long, due to its removal by the strong surface winds. Especially, the CO concentrations were slightly lower during the strom period than both before or after the strom, but they were nearly constant without much changes during the during the daytime and nighttime.

• Korean Journal of Materials Research
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• v.24 no.7
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• pp.339-343
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• 2014

$CaWO_4:Sm_x$(x = 0, 0.5, 1.0, 1.5, 2.0 mol%) white phosphors with different concentrations of $Sm^{3+}$ ions were synthesized using the hydrothermal method. The crystal structure, surface, and optical properties of the $CaWO_4:Sm_x$ phosphors were investigated using X-ray diffraction(XRD), field-emission scanning electron microscopy(FE-SEM), photoluminescence(PL) and photoluminescence excitation(PLE). From the XRD results, the crystal structure of the $CaWO_4:Sm$ phosphors was found to be tetragonal. The $CaWO_4:Sm$ phosphors became more cohesive with increasing $Sm^{3+}$-ion concentration. The photoluminescence excitation(PLE) peak of the phosphors, at around 250 nm, was ascribed to the transition from the 1A1 ground-state to the high-vibration level of 1T2 in the $WO{_4}^{2-}$ complex. The maximum emission spectra of the phosphors were observed when the $Sm^{3+}$ concentration was 0.5 mol%. The luminescence intensity of the $CaWO_4$ phosphors was decreased for $Sm^{3+}$ concentrations greater than 0.5 mol%.

• Economic and Environmental Geology
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• v.32 no.6
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• pp.611-631
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• 1999

Enviromental geochemisty and heary metal contamination at the Kongjueil mine creek were underaken on the basis of physicohemical properties and mineralogy for various kinds of water (surface, mine and ground water),soil, precipitate and sediment collected of April and December in 1998. Hydrgeochemical composition of the water samples are characterized by relatively significant enricant of Ca+Na, alkiali ions $NO_3$ and Cl inground and surfore water, wheras the mine waters are relatively eneripheral water of the mining creek have the characteristics of the (Ca+Mg)-$(HCO_3+SO_4)$type. The pH of the mine water is high acidity (3.24)and high EC (613$\mu$S/cm)compared with those of surface and ground water. The range of $\delta$D and $\delta^{18}O$ values (relative to SMOW) in the waters are shpwn in -50.2 to -61.6% and -7.0 to -8.6$\textperthousand$(d value=5.8 to 8.7). Using computer program, saturation index of albite, calcite, dolomite in mine water are nearly saturated. The gibbiste, kaolinite and smectite are superaturated in the surface and ground water, respectively. Calculated water-mineral reaction and stabilities suggest that weathing of silicate minerals may be stable kaolinite owing to the continuous water-rock reaction. Geochemical modeling showed that mostly toxic heavy metals may exist larfely in the from of metal-sulfate $(MSO_4\;^2)$and free metal $(M^{2+})$ in nmine water. These metals in the ground and surface water could be formed of $CO_3$ and OH complex ions. The average enrichment indices of water samples are 2.72 of the groundwater, 2.26 of the surface water and 14.15 of the acid mine water, normalizing by surface water composition at the non-mining creek, repectively. Characteristics of some major, minor and rate earth elements (Al/Na, K/Na, V/Ni, Cr/V, Ni/Co, La/Ce, Th/Yb, $La_N/Yb_N$, Co/Th, La/Sc and Sc/Th) in soil and sediment are revealed a narrow range and homogeneous compositions may be explained by acidic to intermediate igneous rocks. And these suggested that sediment source of host granitic gneiss colud be due to rocks of high grade metamorphism originated by sedimentary rocks. Maximum concentrations of environmentally toxic elements in sediment and soil are Fe=53.80 wt.% As=660, Cd=4, Cr=175, Cu=158, Mn=1010, Pb=2933, Sb=4 and Zn=3740 ppm, and extremely high concentrations are found are found in the subsurface soil near the ore dump and precipitates. Normalizing by composition of host granitic gneiss, the average enerichment indices are 3.72 of the sediments, 3.48 of the soils, 10.40 of the precipitates of acid mine drainage and 6.25 of the soils near the main adit. The level of enerichment was very severe in mining drainage sediments, while it was not so great in the soils. mineral composition of soil and sediment near the mining area were partly variable being composed of quartz, mica, feldspar, chlorite, vermiculite, bethierin and clay minerals. reddish variable being composed of quartz, mica, feldspar, chlorite, vermiculite, bethierin and clay minerals. Reddish brown precipitation mineral in the acid mine drainage identifies by schwertmanite. From the separated mineralgy, soil and sediment are composed of some pyrite, arsenopyite, chalcopyrite, sphalerite, galena, malachite, goethite and various kinds of hydroxied minerals.