• Smart Structures and Systems
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• v.31 no.2
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• pp.113-130
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• 2023

Hybrid simulation (HS) has attracted community attention in recent years as an efficient and effective experimental technique for structural performance evaluation in size-limited laboratories. Traditional hybrid simulations usually take deterministic properties for their numerical substructures therefore could not account for inherent uncertainties within the engineering structures to provide probabilistic performance assessment. Reliable structural performance evaluation, therefore, calls for stochastic hybrid simulation (SHS) to explicitly account for substructure uncertainties. The experimental design of SHS is explored in this study to account for uncertainties within analytical substructures. Both computational simulation and laboratory experiments are conducted to evaluate the pseudo-random Sobol sequence for the experimental design of SHS. Meta-modeling through polynomial chaos expansion (PCE) is established from a computational simulation of a nonlinear single-degree-of-freedom (SDOF) structure to evaluate the influence of nonlinear behavior and ground motions uncertainties. A series of hybrid simulations are further conducted in the laboratory to validate the findings from computational analysis. It is shown that the Sobol sequence provides a good starting point for the experimental design of stochastic hybrid simulation. However, nonlinear structural behavior involving stiffness and strength degradation could significantly increase the number of hybrid simulations to acquire accurate statistical estimation for the structural response of interests. Compared with the statistical moments calculated directly from hybrid simulations in the laboratory, the meta-model through PCE gives more accurate estimation, therefore, providing a more effective way for uncertainty quantification.

• Applied Chemistry for Engineering
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• v.26 no.3
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• pp.319-325
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• 2015

Submicron-sized $CeO_2:Er^{3+}/Yb^{3+}$ upconversion phosphor particles were synthesized by spray pyrolysis, and their luminescent properties were characterized by changing the concentration of $Er^{3+}$ and $Yb^{3+}$. $CeO_2:Er^{3+}/Yb^{3+}$ showed an intense green and red emission due to the $^4S_{3/2}$ or $^2H_{11/2}{\rightarrow}^4I_{15/2}$ and $^4F_{9/2}{\rightarrow}^4I_{15/2}$ transition of $Er^{3+}$ ions, respectively. In terms of the emission intensity, the optimal concentrations of Er and Yb were 1.0 % and 2.0%, respectively, and the concentration quenching was found to occur via the dipole-dipole interaction. Upconversion mechanism was discussed by using the dependency of emission intensities on pumping powers and considering the dominant depletion processes of intermediate energy levels for the red and green emission with changing the $Er^{3+}$ concentration. An energy transfer from $Yb^{3+}$ to $Er^{3+}$ in $CeO_2$ host was mainly involved in ground-state absorption (GSA), and non-radiative relaxation from $^4I_{11/2}$ to $^4I_{13/2}$ of $Er^{3+}$ was accelerated by the $Yb^{3+}$ co-doping. As a result, the $Yb^{3+}$ co-doping led to greatly enhance the upconversion intensity with increasing ratios of the red to green emission. Finally, it is revealed that the upconversion emission is achieved by two photon processes in which the linear decay dominates the depletion of intermediate energy levels for green and red emissions for $CeO_2:Er^{3+}/Yb^{3+}$ phosphor.

• Magazine of the Korea Concrete Institute
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• v.10 no.6
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• pp.223-231
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• 1998

Existing cast in place piles made by grouting cement mortar have many problems that cracks by autogeneous and drying shrinkage bring about the deterioration of force for piles, segregations by the submersion of ground water occur and also, high cement contents lead to rise the manufacturing cost. Therefore, this study is intended to investigate the mechanical properties of high performance mortar, incorporating expansive additives and fly ash. for cast in place piles. According to the experimental results, as the contents of expansive additives increase in mortar mixture, fluidity decrease and air contents shows inverse tendency. Setting time is delayed. Although compressive strength at 7days shows a decline tendency. compressive strength at 28days and 91days increase slightly with 5% of expansive additives. As fly ash increase in mortar mixture, high fluidity is shown, air contents increase and setting time is delayed at fresh state, and additives are, the larger length change is, whereas shrinkage decrease with the increase of fly ash.

• Journal of the Korean Chemical Society
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• v.42 no.6
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• pp.629-637
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• 1998

The HF-SCF, MP2 and B3LYP calculations have been performed on the two conceivable clusters $(HF)_2(CO)$ trimers as well as their dimer complexes FH…FH, FH…CO and FH…OC applying $6-31+G^{\ast}^{\ast}$, and $6-311+G^{\ast}^{\ast}$ basis sets. A variety of ground state properties of these trimer complexes have been listed, and compared with corresponding properties of isolated monomers and combined dimers. It was calculated that FH…CO is more stable than FH…OC by average 0.85 kcal/mol and F-H…F-H…C≡O is more stable than F-H…F-H…O≡C by 1-2 kcal/mol. The C≡O stretching bands of the F-H…F-H…C≡O and F-H…F-H…O≡C were red shifted by 24, $37\;cm^{-1}$ compared with the FH…CO and FH…OC respectively. Also, H-F stretching bands were red shifted by 54 and $353\;cm^{-1}$.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.457-464
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• 2005

In the case of tunneling, the equilibrium state of hydro-geologic environments destroy and change abruptly in some section of whole works. Specially, it's very possible for seawater to intrude toward the site of tunnel if the field is nearly located in a costal region. In this study, we have evaluated the mechanism related between groundwater flow and seawater intrusion that by impacts of tunneling. Various hydro-geological field tests have performed for getting four representative hydrogeologic properties of geologic formations such as transmissivity (T), storativity(S), longitudial dispersity(${\alpha}_L$), and effective porosity($n_e$). For the effect of tunneling, the numerical model was first simulated based on the governing equation of groundwater flow. The results showed that the maximum drawdown was 17.2m and the total inflow into the tunnel had the range from 0.48 to $3.63m^3/day/m$. Secondly, the three dimensional numerical model was analyzed to investigate a characteristic of seawater intrusion based on the previous simulated results of groundwater flow. The results showed the seawater moved as the range of $200{\sim}220m$ from the initial interface between seawater and groundwater toward the tunnel.

• Korean Journal of Materials Research
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• v.8 no.3
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• pp.219-223
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• 1998

Spectroscopic properties of $Eu^{3+}$, $Sm^{3+}$, $Tb^{3+}$ ions in silicate glasses have been studied. The absorption and emission properties were investigated with the wavelength and rare-earth element concentration. The results showed that the emission spectrum of $Sm^{3+}$ was a transition from $^{5}D_{o}$ excited level to ^{7}F$ ground state and $Sm^{3+}$ was from $4F_{5/2}$ to $^{6}H$ and $Tb^{3+}$ was from $^{5}D_{4}$ to ^{7}F$ The emission intensity was linearly increased with rare-earth element concentrations up to 10wt%.

• Journal of the Korean Geotechnical Society
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• v.32 no.11
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• pp.31-42
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• 2016

Usually the seismic stability analysis of slope uses the pseudostatic analysis considering the inertial force by the earthquake as a static load. Geostructures such as slope include the uncertainty of soil properties. Therefore, it is necessary to consider probabilistic method for stability analysis. In this study, the probabilistic stability analysis of slope considering the uncertainty of soil properties has been performed. The fragility curve that represents the probability of exceeding limit state of slope as a function of the ground motion has been established. The Monte Carlo Simulation (MCS) has been implemented to perform the probabilistic stability analysis of slope with pseudostatic analysis. A procedure to develop the fragility curve by the pseudostatic horizontal acceleration has been presented by calculating the probability of failure based on the Artificial Neural Network (ANN) based response surface technique that reduces the required time of MCS. The results showed that the proposed method can get the fragility curve that is similar to the direct MCS-based fragility curve, and can be efficiently used to reduce the analysis time.

• Journal of the Korean Chemical Society
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• v.37 no.4
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• pp.408-415
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• 1993

Systematic ab initio SCF calculations have been performed on the hydrogen-bonded dimers of fluoromethanes involving $CH_4,\;CH_3F,\;CH_2F_2\;and\;CHF_3$ with ammonia and water applying basis sets of 9s5p/5s and 9s5p1d/5p1d. Various ground state properties of these stable dimeric complexes have been evaluated. We compared these with corresponding properties of isolated monomers. We report equilibrium geometries, stabilization energies, dipole moments and force constants of intermolecular bonds. The effects arising as a consequence of the non-additive behavior of hydrogen bonding in chain-like oligomers are discussed. Systematic, methodical errors due to the use of the SCF approximation and the basis set dependence of the computed results are pointed out.

• Geomechanics and Engineering
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• v.33 no.2
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• pp.175-182
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• 2023

In general, the design of structures and its construction processes are fundamentally dependent on their foundation and supporting ground. Thus, it is imperative to understand the behavior of the soil under certain stress and drainage conditions. As it is well known that certain characteristics and behaviors of soils with fines are highly dependent on water content, it is critical to accurately measure and identify the status of the soils in terms of water contents. Liquid limit is one of the important soil index properties to define such characteristics. However, liquid limit measurement can be affected by the proficiency of the operator. On the other hand, dynamic properties of soils are also necessary in many different applications and current testing methods often require special equipment in the laboratory, which is often expensive and sensitive to test conditions. In order to address these concerns and advance the state of the art, this study explores a novel method to determine the liquid limit of cohesive soil by employing video-based vibration analysis. In this research, the modal characteristics of cohesive soil columns are extracted from videos by utilizing phase-based motion estimation. By utilizing the proposed method that analyzes the optical flow in every pixel of the series of frames that effectively represents the motion of corresponding points of the soil specimen, the vibration characteristics of the entire soil specimen could be assessed in a non-contact and non-destructive manner. The experimental investigation results compared with the liquid limit determined by the standard method verify that the proposed method reliably and straightforwardly identifies the liquid limit of clay. It is envisioned that the proposed approach could be applied to measuring liquid limit of soil in practical field, entertaining its simple implementation that only requires a digital camera or even a smartphone without the need for special equipment that may be subject to the proficiency of the operator.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.4C
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• pp.229-238
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• 2006

Observed field behaviors are frequently different from the behaviors predicted in the design state due to several uncertainties involved in soil properties, numerical modeling, and error of measuring system even though a sophisticated numerical analysis technique is applied to solve the consolidation behavior of drainage-installed soft deposits. In this study, genetic algorithms are applied to back-analyze the soil properties using the observed behavior of soft clay deposit composed of multi layers that shows complex consolidation characteristics. Utilizing the program, one might be able to appropriately predict the subsequent consolidation behavior from the measured data in an early stage of consolidation of multi layered soft deposits. Example analyses for drainage-installed multi-layered soft deposits are performed to examine the applicability of proposed back-analysis method.