• Title/Summary/Keyword: grain size evolution

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Development of the 925 Silver Alloyed Tension Jewelry with Press Forming Process (가압성형법을 이용한 925 은합금의 텐션형 주얼리 개발)

  • Song, Oh-Sung;Kim, Sang-Yeob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.5
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    • pp.805-810
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    • 2006
  • Defects in the conventional casting process of silver jewelry can result in famished products of mediocre hardness. To overcome the shortcomings of conventional methods, we proposed new press forming process, which involves applying uniaxial pressure on casting 92.5%Ag-6.5%Cu-1%Zn ring elements and shaping with a lath. We investigated Vickers hardness, density, and microstructure evolution by changing the applied uniaxial pressure. We report that our newly proposed process can increase the hardness up to 2.3 times and decrease average grain size by 50%. Our method leads to drastic mechanical property enhancements, and is thus suitable for casting tension-style jewelry.

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Evolution of Microstructure in Al-4.0%Zn-1.5%Mg-0.9%Cu Alloy by Extrusion, Rolling and Heat Treatment (Al-4.0%Zn-1.5%Mg-0.9%Cu 합금의 압출, 압연 및 열처리에 따른 미세조직 변화)

  • Kwon, Hyeok Gon;Park, Jong Moon;Oh, Myung Hoon;Park, No Jin
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.2
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    • pp.41-48
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    • 2018
  • In this study, microstructural changes due to extrusion, rolling and heat treatment were studied to fabricate Al-4.0wt%Zn-1.5wt%Mg-0.9wt%Cu alloys with homogeneous microstructure suitable for metal cases of smart phones and electronic products fabricated through plastic working. After extrusion microstructure and texture were developed very differently on the surface and inside. Inside, coarse grains were formed and a strong Cube component orientation was developed. On the surface, a weak texture was developed with small grains. After 72% cold rolling the intensity of the Cube component orientation was lower, and uniform texture was developed in all the layers and the R-value was uniformly predicted. After recrystallization, the grain size difference between at the surface and the inside is smaller, when 72% rolling was performed, indicating that a uniform structure is formed. Texture develops almost randomly after recrystallization and exhibits uniform R-values at all layers.

Development of Micro-Tubular Perovskite Cathode Catalyst with Bi-Functionality on ORR/OER for Metal-Air Battery Applications

  • Jeon, Yukwon;Kwon, Ohchan;Ji, Yunseong;Jeon, Ok Sung;Lee, Chanmin;Shul, Yong-Gun
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.425-431
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    • 2019
  • As rechargeable metal-air batteries will be ideal energy storage devices in the future, an active cathode electrocatalyst is required with bi-functionality on both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) during discharge and charge, respectively. Here, a class of perovskite cathode catalyst with a micro-tubular structure has been developed by controlling bi-functionality from different Ru and Ni dopant ratios. A micro-tubular structure is achieved by the activated carbon fiber (ACF) templating method, which provides uniform size and shape. At the perovskite formula of $LaCrO_3$, the dual dopant system is successfully synthesized with a perfect incorporation into the single perovskite structure. The chemical oxidation states for each Ni and Ru also confirm the partial substitution to B-site of Cr without any changes in the major perovskite structure. From the electrochemical measurements, the micro-tubular feature reveals much more efficient catalytic activity on ORR and OER, comparing to the grain catalyst with same perovskite composition. By changing the Ru and Ni ratio, the $LaCr_{0.8}Ru_{0.1}Ni_{0.1}O_3$ micro-tubular catalyst exhibits great bi-functionality, especially on ORR, with low metal loading, which is comparable to the commercial catalyst of Pt and Ir. This advanced catalytic property on the micro-tubular structure and Ru/Ni synergy effect at the perovskite material may provide a new direction for the next-generation cathode catalyst in metal-air battery system.

Impacts of wave and tidal forcing on 3D nearshore processes on natural beaches. Part II: Sediment transport

  • Bakhtyar, R.;Dastgheib, A.;Roelvink, D.;Barry, D.A.
    • Ocean Systems Engineering
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    • v.6 no.1
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    • pp.61-97
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    • 2016
  • This is the second of two papers on the 3D numerical modeling of nearshore hydro- and morphodynamics. In Part I, the focus was on surf and swash zone hydrodynamics in the cross-shore and longshore directions. Here, we consider nearshore processes with an emphasis on the effects of oceanic forcing and beach characteristics on sediment transport in the cross- and longshore directions, as well as on foreshore bathymetry changes. The Delft3D and XBeach models were used with four turbulence closures (viz., ${\kappa}-{\varepsilon}$, ${\kappa}-L$, ATM and H-LES) to solve the 3D Navier-Stokes equations for incompressible flow as well as the beach morphology. The sediment transport module simulates both bed load and suspended load transport of non-cohesive sediments. Twenty sets of numerical experiments combining nine control parameters under a range of bed characteristics and incident wave and tidal conditions were simulated. For each case, the general morphological response in shore-normal and shore-parallel directions was presented. Numerical results showed that the ${\kappa}-{\varepsilon}$ and H-LES closure models yield similar results that are in better agreement with existing morphodynamic observations than the results of the other turbulence models. The simulations showed that wave forcing drives a sediment circulation pattern that results in bar and berm formation. However, together with wave forcing, tides modulate the predicted nearshore sediment dynamics. The combination of tides and wave action has a notable effect on longshore suspended sediment transport fluxes, relative to wave action alone. The model's ability to predict sediment transport under propagation of obliquely incident wave conditions underscores its potential for understanding the evolution of beach morphology at field scale. For example, the results of the model confirmed that the wave characteristics have a considerable effect on the cumulative erosion/deposition, cross-shore distribution of longshore sediment transport and transport rate across and along the beach face. In addition, for the same type of oceanic forcing, the beach morphology exhibits different erosive characteristics depending on grain size (e.g., foreshore profile evolution is erosive or accretive on fine or coarse sand beaches, respectively). Decreasing wave height increases the proportion of onshore to offshore fluxes, almost reaching a neutral net balance. The sediment movement increases with wave height, which is the dominant factor controlling the beach face shape.

Fabrication of TFA-MOD YBCO Films Using Y2Ba1Cu1Ox Process (Y2Ba1Cu1Ox공정을 이용한 TFA-MOC YBCO 박막 공정 개발)

  • Lim, Jun-Hyung;Jang, Seok-Hern;Kim, Kyu-Tae;Lee, Jin-Sung;Yoon, Kyung-Min;Ha, Hong-Soo;Joo, Jinho;Nah, Wansoo
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.98-105
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    • 2006
  • YBCO film was synthesized by using a new approach to the TFA-MOD method. In the fabrication process, $Y_2Ba_1Cu_1O_x\;and\;Ba_3Cu_5O_8$ powders were used as precursors (the so called '211 process'), instead of Y-, Ba-, and Cu-based acetates, and dissolved in trifluoroacetic acid followed by calcining and firing heat treatment. Consequently, we successfully fabricated YBCO film and evaluated the phase formation, texture evolution, and critical properties as a function of the calcining and firing temperature and humidity, in order to explore its possible application in coated conductor fabrication. The films were calcined at $430-460^{\circ}C$ and then fired at $750-800^{\circ}C\;in\;a\;0-20\%$ humidified $Ar-O_2$ atmosphere. We observed that $BaF_2$ phase was effectively reduced and that a sharp and strong biaxial texture formed under humidified atmosphere leading to increased critical properties. In addition, we found that the microstructure varied significantly with the firing temperature: the grain grew further, the film became denser, and the degree of texture and phase purity varied as the firing temperature increased. For the film fired at $775^{\circ}C$ after calcining at $460^{\circ}C$, the critical current was obtained to be 39 A/cm-width (corresponding critical current density is $2.0\;MA/cm^2$ which was probably attributed to such factors as the enhanced phase purity and out-of-plane texture, the moderate film density and grain size, and crack-free surface.

Fractals and Fragmentation of Survivor Grains within Gouge Zones along Boundary Faults in the Tertiary Waeup Basin (제3기 와읍분지 경계단층을 따라 발달하는 단층비지 내 잔류입자의 프랙탈과 파쇄작용)

  • Chang, Tae-Woo
    • The Journal of Engineering Geology
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    • v.20 no.2
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    • pp.183-189
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    • 2010
  • Fault gouge samples were collected from the fault cores of the boundary faults between the Cretaceous Basement and the Tertiary Waeup Basin. Fractal dimensions (D) were obtained by using survivor grains which were analysed from six thin sections of the gouges under the optical microscope. The elliptical survivor grains show a shape preferred orientation almost parallel to clay foliation in matrix, suggesting that it was formed by the rotation of the survivor grains in abundant fine-grained matrix during repeated fault slips. The size distributions of the survivor grains follow power-laws with fractal dimensions in the 2.40-3.02 range. D values of all samples but one are higher than a specific D value equal to 2.58 which predicts the self similarity of fragmentation process in constrained comminution model (Sammis et al., 1987), which indicates large fault slip and multiple faulting. Probably the higher D values than 2.58 mean the non-self-similar evolution of cataclastic rocks where fragmentation mechanism changed from constrained comminution to the grain abrasion accompanying selective fracture of larger grains.

Mineral Composition and Grain Size Distribution of Fault Rock from Yangbuk-myeon, Gyeongju City, Korea (경주시 양북면 단층암의 광물 조성과 입도 분포 특징)

  • Song, Su Jeong;Choo, Chang Oh;Chang, Chun-Joong;Chang, Tae Woo;Jang, Yun Deuk
    • Economic and Environmental Geology
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    • v.45 no.5
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    • pp.487-502
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    • 2012
  • This paper is focused on mineral compositions, microstructures and distributional characters of remained grains in the fault rocks collected from a fault developed in Yongdang-ri, Yangbuk-myeon, Gyeongju City, Korea, using X-ray diffraction (XRD), optical microscope, laser grain size analysis and fractal dimension analysis methods. The exposed fault core zone is about 1.5 meter thick. On the average, the breccia zone is 1.2 meter and the gouge zone is 20cm thick, respectively. XRD results show that the breccia zone consists predominantly of rock-forming minerals including quartz and feldspar, but the gouge zone consists of abundant clay minerals such as chlorite, illite and kaolinite. Mineral vein, pyrite and altered minerals commonly observed in the fault rock support evidence of fault activity associated with hydrothermal alteration. Fractal dimensions based on box counting, image analysis and laser particle analysis suggest that mineral grains in the fault rock underwent fracturing process as well as abrasion that gave rise to diminution of grains during the fault activity. Fractal dimensions(D-values) calculated by three methods gradually increase from the breccia zone to the gouge zone which has commonly high D-values. There are no noticeable changes in D-values in the gouge zone with trend being constant. It means that the bulk-crushing process of mineral grains in the breccia zone was predominant, whereas abrasion of mineral grains in the gouge zone took place by continuous fault activity. It means that the bulk-crushing process of mineral grains in the breccia zone was predominant, whereas abrasion of mineral grains in the gouge zone took place by continuous fault activity. Mineral compositions in the fault zone and peculiar trends in grain distribution indicate that multiple fault activity had a considerable influence on the evolution of fault zones, together with hydrothermal alteration. Meanwhile, fractal dimension values(D) in the fault rock should be used with caution because there is possibility that different values are unexpectedly obtained depending on the measurement methods available even in the same sample.

Ring-shear Apparatus for Estimating the Mobility of Debris Flow and Its Application (토석류 유동성 평가를 위한 링 전단시험장치 개발 및 활용)

  • Jeong, Sueng-Won;Fukuoka, Hiroshi;Song, Young-Suk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.1
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    • pp.181-194
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    • 2013
  • Landslides are known as gravitational mass movements that can carry the flow materials ranging in size from clay to boulders. The various types of landslides are differentiated by rate and depositional features. Indeed, flow characteristics are observed from very slow-moving landslides (e.g., mud slide and mud flow) to very fast-moving landslides (e.g., debris avalanches and debris flows). From a geomechanical point of view, shear-rate-dependent shear strength should be examined in landslides. This paper presents the design of advanced ring-shear apparatus to measure the undrained shear strength of debris flow materials in Korea. As updated from conventional ring-shear apparatus, this apparatus can evaluate the shear strength under different conditions of saturation, drainage and consolidation. We also briefly discussed on the ring shear apparatus for enforcing sealing and rotation control. For the materials with sands and gravels, an undrained ring-shear test was carried out simulating the undrained loading process that takes place in the pre-existing slip surface. We have observed typical evolution of shear strength that found in the literature. This paper presents the research background and expected results from the ring-shear apparatus. At high shear speed, a temporary liquefaction and grain-crushing occurred in the sliding zone may take an important role in the long-runout landslide motion. Strength in rheology can be also determined in post-failure dynamics using ring-shear apparatus and be utilized in debris flow mobility.

Present Status and Future Management Strategies for Sugarcane Yellow Leaf Virus: A Major Constraint to the Global Sugarcane Production

  • Holkar, Somnath Kadappa;Balasubramaniam, Parameswari;Kumar, Atul;Kadirvel, Nithya;Shingote, Prashant Raghunath;Chhabra, Manohar Lal;Kumar, Shubham;Kumar, Praveen;Viswanathan, Rasappa;Jain, Rakesh Kumar;Pathak, Ashwini Dutt
    • The Plant Pathology Journal
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    • v.36 no.6
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    • pp.536-557
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    • 2020
  • Sugarcane yellow leaf virus (SCYLV) is a distinct member of the Polerovirus genus of the Luteoviridae family. SCYLV is the major limitation to sugarcane production worldwide and presently occurring in most of the sugarcane growing countries. SCYLV having high genetic diversity within the species and presently ten genotypes are known to occur based on the complete genome sequence information. SCYLV is present in almost all the states of India where sugarcane is grown. Virion comprises of 180 coat protein units and are 24-29 nm in diameter. The genome of SCYLV is a monopartite and comprised of single-stranded (ss) positive-sense (+) linear RNA of about 6 kb in size. Virus genome consists of six open reading frames (ORFs) that are expressed by sub-genomic RNAs. The SCYLV is phloem-limited and transmitted by sugarcane aphid Melanaphis sacchari in a circulative and non-propagative manner. The other aphid species namely, Ceratovacuna lanigera, Rhopalosiphum rufiabdominalis, and R. maidis also been reported to transmit the virus. The virus is not transmitted mechanically, therefore, its transmission by M. sacchari has been studied in different countries. SCYLV has a limited natural host range and mainly infect sugarcane (Sachharum hybrid), grain sorghum (Sorghum bicolor), and Columbus grass (Sorghum almum). Recent insights in the protein-protein interactions of Polerovirus through protein interaction reporter (PIR) technology enable us to understand viral encoded proteins during virus replication, assembly, plant defence mechanism, short and long-distance travel of the virus. This review presents the recent understandings on virus biology, diagnosis, genetic diversity, virus-vector and host-virus interactions and conventional and next generation management approaches.