• Journal of the Korean Ceramic Society
• /
• v.26 no.1
• /
• pp.51-58
• /
• 1989

Wear and wear transition mechanisms during sliding as a function of time in Al2O3 have been studied to understand the wear behaviour of brittle ceramic materials. Commercial Si3N4 ball was rotated against flat Al2O3 specimens which were hot pressed and polished using upto 1${\mu}{\textrm}{m}$ diamond paste. Paraffin oil was used as a lubricant. Experimental data show that wear of Al2O3 is separated into distinct two stages, i.e., initial stage of slow wear and final stage of rapid wear. Microstructural observations at worn surface show that wear occurs through grooving and grain pull-out in the initial and final stage respectively. TEM observations beneath the worn surfaces show that grain pull-out starts to occur by the propagation of grain boundary cracks induced by dislocation pile-up throughthe surface.

• Korean Journal of Materials Research
• /
• v.4 no.3
• /
• pp.329-333
• /
• 1994

A large number of grain boundaries were seen to crack in near-eutectic solder joints of leadless ceramic chip carriers (LLCC's) during thermal cycling at temperature ranges from -$35^{\circ}C$ to +$125^{\circ}C$ with lhr time period. One potential explanation for this type of cracking might be the presence of embrittling species on the boundary. Although there do not appear to be any instances reported in the literature of solders being embrittled by small amounts of contaminating species, the possibility of such an occurrence exists. The potential presence of impurities located at crack surfaces was inspected using Scanning Auger Microprobe(SAM) and it was found that intergranular cracking could be accomplished by the oxidation of the grain boundary. A physical model for fatigue crack growth was introduced, in which grain boundary separation took place under oxidation facilitated by sliding.

• Transactions of Materials Processing
• /
• v.14 no.8 s.80
• /
• pp.681-688
• /
• 2005

The high-temperature deformation mechanisms of a ${\alpha}+{\beta}$ titanium alloy (Ti-6Al-4V), near-a titanium alloy (Ti-6.85Al-1.6V) and a single-phase a titanium alloy (Ti-7.0Al-1.5V) were deduced within the framework of inelastic-deformation theory. For this purpose, load relaxation tests were conducted on three alloys at temperatures ranging from 750 to $950^{\circ}C$. The stress-versus-strain rate curves of both alloys were well fitted with inelastic-deformation equations based on grain matrix deformation and grain-boundary sliding. The constitutive analysis revealed that the grain-boundary sliding resistance is higher in the near-${\alpha}$ alloy than in the two-phase ${\alpha}+{\beta}$ alloy due to the difficulties in relaxing stress concentrations at the triple-junction region in the near-${\alpha}$ alloy. In addition, the internal-strength parameter (${\sigma}^*$) of the near-${\alpha}$ alloy was much higher than that of the ${\alpha}+{\beta}$ alloy, thus implying that dislocation emission/ slip transfer at ${\alpha}/{\alpha}$ boundaries is more difficult than at ${\alpha}/{\beta}$ boundaries.

• Journal of Powder Materials
• /
• v.3 no.4
• /
• pp.271-278
• /
• 1996

In this study, the effect of the transition elements on the microstructure and mechanical properties of rapidly solidified Al-Mg-X alloys was investigated. As a result of the rapid solidification processing, fine equiaxed grains with a mean diameter of 2 $\mu$m were observed in these alloys. Many fine particles were found to be distributed rather homogeneously throughout the matrix with relatively large particles occasionally at grain boundaries. The ultimate tensile strengths of Al-Mg-X alloys were found to decrease rather remarkably at 150 $^{\circ}C$ without the gain of the ductility at 150 $^{\circ}C$, which may result from segregation of $\beta$ ($Al_{3}Mg_{2}$) precipitates. Fine dimples were observed on the fracture surfaces for all alloy systems and the variation of the size and shape of dimples was not observed upon alloy systems. The ductility at 530 $^{\circ}C$ was found to be ~100%, suggesting that grain boundary sliding did not contribute to ductiliy despite he grain size stabilization. The absence of superplastic behavior may be associated with low boundary misorientation in rapidly solidified Al-Mg-X alloys.

• Journal of Korea Foundry Society
• /
• v.37 no.5
• /
• pp.157-163
• /
• 2017

In the present study, the microstructural evolution and deformation behavior of AA 2014 aluminum alloys with different microstructures in a semi-solid state were investigated. For a given alloy, applied load and deformation time, the measured strain was higher at a higher temperature, indicative of a lower solid fraction. When a large proportion of the liquid was present as intragranular droplets, the alloy would not as easily deform because the effective liquid fraction between the solid grains had decreased. Greater deformation was achieved with higher grain boundary misorientations due to the enhanced wetting of the grain boundaries with liquid. A semi-empirical constitutive model is proposed for semi-solid deformation under the conditions in the present study. The mechanism of semi-solid deformation incorporates the initial flow of the liquid in the early stages of deformation, followed by a more gradual increase in the strain due to deformation by grain sliding accompanied by self-diffusion in the solid grains.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 1997.10a
• /
• pp.228-231
• /
• 1997

A series of load relaxation tests was performed to determine stress-strain rate curves at high temperatures. Constitutive parameters of GBS and GMD were evaluated from the curves using the recently proposed inelastic deformation theory. Tensile tests and Microsturcture investigations showed deformation behavior as the relaxation test results predicted.

• Transactions of Materials Processing
• /
• v.18 no.7
• /
• pp.544-549
• /
• 2009

This study aimed to elucidate the deformation mechanism during low-temperature superplasticity of fine-grained Ti-6Al-2Sn-4Zr-2Mo-0.1Si alloy in the context of constitutive equation. For this purpose, initial coarse equiaxed microstructure was refined to $2.2{\mu}m$ via dynamic globularization. Globularized microstructure exhibited large superplastic elongations(434-826%) at temperatures of $650-750^{\circ}C$ and strain rate of $10^{-4}s^{-1}$. It was found that the main deformation mechanism of fine-grained material was grain boundary sliding accommodated by dislocation motion with both stress exponent (n) and grain size exponent (p) values of 2. When the alpha grain size, not sub-grain size, was considered to be an effective grain size, the apparent activation energy for low-temperature superplasticity of the present alloy(169kJ/mol) was closed to that of Ti-6Al-4V alloy(160kJ/mol).

• Journal of the Korean Ceramic Society
• /
• v.28 no.10
• /
• pp.785-792
• /
• 1991

An investigation of the crack propagation behavior of Al2O3-33Vol.% SiCw at 140$0^{\circ}C$ was conducted with various loading frequencies. Higher crack propagation was observed in lower frequency and higher load ratios. Interface sliding fracture due to glassy phase from the oxidation of SiCw and cavitation along grain boundary of diffusional creep appeared to be the main mechanism of fatigue fracture in slower crack propagation while interface sliding and whisker pull out aided by glassy phase formation played main role of fatigue fracture for higher crack growth condition. The frequency effect on deformation behavior was discussed with a Maxwell model.

• Korean Journal of Materials Research
• /
• v.2 no.6
• /
• pp.468-476
• /
• 1992

Stress rupture properties and fracture behavior of Ni microalloyed W were studied using direct load creep tester at 100$0^{\circ}C$, 110$0^{\circ}C$ and 120$0^{\circ}C$ in $H_2$. At the same grain size, 15${\mu}$m, the 100hr. stress rupture strength of W-0.4wt% Ni was 23% higher than that of W-0.2wt%Ni due to the grain growth during test. The minimum creep rate of W-0.2wt%Ni was decreased with an increase in initial grain size. By increasing the Ni content of Ni microalloyed W, rupture time was increased owing to the smaller number and size of cavity. All the specimens showed intergranular fracture by grain boundary sliding and nucleation, growth and coalescence of cavities at grain boundary.

• Korean Journal of Materials Research
• /
• v.4 no.7
• /
• pp.828-836
• /
• 1994

In order to investigate the high temperature deformation characteristics in YBaiCu307-, oxide superconductor, the compression test was performed at temperatures from $890^{\circ}C$ to $930^{\circ}C$ at initial strain rate between $1.0 x 10^{-5}s^{-1}\; and \; 1.0^{-4}s^{-1}$. As the temperature increased and the initial strain rate decreased, the flow stress decreased. The strain rate sensitivity exponent measured as 0.41-0.46, supporting occurence of a superplastic deformation. The activation energy for superplastic deformation was calculated as 500-580KJ/mol, which decreased with increasing Ag content. Microstructure of the superplastically-deformed specimens showed that a grain growth occurred during deformation, and it appeared to be considerable when Ag content increased, but most grains still remained equiaxed after deformation. In this study, the deformation mechanism of YBCO superconductor was the grain boundary sliding with the diffusional accommodation and the contribution of the gram boundary sliding to the total strain was estimated to be 65%.