• Title/Summary/Keyword: grafting process

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Reactive Extrusion of Starch-g-Polyacrylonitrile in the Preparation of Absorbent Materials

  • Yoon, Kee-Jong;Carr, M.E.;Bagley, E.B.
    • Proceedings of the Korean Fiber Society Conference
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    • 1990.06b
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    • pp.8-8
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    • 1990
  • A new method for the graft polymerization of acrylonitrile onto starch is presented. Graft polymerization of acrylonitrile onto starch and the subsequent hydrolysis in sodium hydroxide solution to prepare absorbents is well known. This process has been utilized to produce the commercial product, Super Slurper. In a typical batch process, ~5% starch in water mixture is gelatinized at $95^{\circ}C$ under stirring for 1 hour then cooled to room temperature. The graft polymerization itself is carried out for approximately 2 hours at $25~30^{\circ}C$ on the gelatinized starch by eerie ion initiation. In this study, graft polymerization of acrylonitrile onto starch via a reactive extrusion process which is a continuous, efficient process is described. Initial concentration of starch in water is 35% and the reaction temperatures are between $50~80^{\circ}C$. However, the most significant difference in the reactive extrusion process is the short time in which the graft polymerization takes place. Preliminary results on the properties of graft polymerization products obtained from the reactive extrusion process are compared to those obtained from the batch process as well as the absorbency of the hydrolyzed samples. Absorbent material has also been prepared by sequential grafting and saponification in the extruder followed by a 2 hour heat treatment of the extrudate in an air circulated oven at $100^{\circ}C$.

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Effectiveness of freeze-dried bone grafts on the non-union fracture model of dogs (개의 비유합(非癒合) 골절(骨折) model에 있어서 동결건조골이식(凍結乾燥骨移植)의 효과(效果))

  • Choi, In-hyuk;Kim, Hyeon-gyeong;Kim, Nam-soo;Sasaki, Nobuo
    • Korean Journal of Veterinary Research
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    • v.36 no.2
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    • pp.495-511
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    • 1996
  • To investigate the effectiveness of the freeze-dried allografts and fibrin glue in bone grafts, the status of new bone formation and union of the grafted bone were observed in three types of grafting bones; autogenic bone(AT), allogenic bone(AL), and allogenic bone particles mixed with fibrin glue(FG). These were transplanted into non-union fracture model of 7 adult dogs with 2cm defect made in the proximal metaphysis of both fibulae. The autogenic and allogenic grafting bones had been treated by a modified freeze-dried method. The serial radiogram were observed the repair process of grafted bones biweekly until 17 or 21 weeks after transplantation and the observation of histological aspects, tetracycline double labeling and microradiography in the grafted bones were undertaken at 17 or 21 weeks after transplantation. The incorporation of bone minerals to the non-union fracture models were accomplished in 4 of 5 cases grafted with AL and in 2 of 4 cases grafted with AT. None of 5 cases grafted with FG were incorporated. The process of new bone formation and resorption in the grafted bones were observed three types; resorption of the grafted bones after newbone formation(type A) in 4 cases, new bone formation after resorption(type B) in 2 cases and complete or incomplete resorption without new bone formation(type C) in 8 cases. The modified freeze-dried method used in this study contributed to inhibite the rejection in allogenic grafts but the union period of the grafted freeze-dried bone was more prolonged than that of fresh autografts. Fibrin glue did not contribute to induce a new bone formation ofbone grafts.

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TOOTH MOVEMENTS TO THE SITE OF ALVEOLAR BONE GRAFT (구순구개열 환아에서의 치조골이식)

  • Cho, Hae-Sung;Park, Jae-Hong;Kim, Gwang-Chul;Choi, Seong-Chul;Lee, Keung-Ho;Choi, Yeung-Chul
    • Journal of the korean academy of Pediatric Dentistry
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    • v.34 no.1
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    • pp.140-149
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    • 2007
  • Cleft lip and palate are congenital craniofacial malformation. Reconstruction of dental arch in patient with alveolo-palatal clefts is very important, because they have many problems in functions and esthetics. Malnutrition, poor oral hygiene, respiratory infections, speech malfunctions, maxillofacial deformity, and psychological problems may be occured without proper treatment during the long period of management of the cleft lip and palate. So the treatment should be managed with a multidisciplinary approach. Bone grafting is a consequential step in the dental rehabilitation of the cleft lip and palate patient A complete alveolar arch should be achieyed of the teeth to erupt in and to form a stable dentition. And the presence of the cleft complicate the orthodontic treatment. Therefore bone grafting in patients with cleft lip and palate is a widely adopted surgical procedure. Grafted bone stabilizes the alveolar process and allows the canine or incisor to move into the graft site. After the bone grafting, orthodontic closure of the maxillary arch has become a common practice for achieving dental reconstruction without any prosthodontic treatment. Various grafting materials have been used in alveolar clefts. Iliac bone is most widely fovoured, but tibia, rib, cranial bone, mandible have also been used. And according to its time of occurrence, the bone graft may be divided into primary, early secondary, secondary, late secondary. Bone grafting is called secondary when performed later, at the end of the mixed dentition. It is the most accepted procedure and has become part of treatment of protocol A secondary bone graft is performed preferably before the eruption of the permanent canine in order to provide adequate periodontal support for the eruption and preservation of the teeth adjacent to the cleft. In this report, we report here on a patient with unilateral cleft lip and palate, who underwent iliac bone graft. The cleft was fully obliterated by grafted bone in the region of the alveolar process. The presence of bone permitted physiologic tooth movement and the orthodontic movement of adjacent tooth into the former cleft area. Satisfactory arch alignment could be achieved in by subsequent orthodontic treatment.

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Study about implementation of the production management system that used RFID (RFID를 이용한 생산관리 시스템의 구현에 관한 연구)

  • Nam, Sang-Yep;Hun, Teak-Young;Park, In-Jung
    • Proceedings of the IEEK Conference
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    • 2006.06a
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    • pp.811-812
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    • 2006
  • This study is study about implementation of the production work management system that used RFID. A RFID Card system is used, and a collection totalizes and all data by real time, and, in production planning and work indication, work process time analyzes production present situation information by line by process automatically, and it is solution to be able to do an inquiry. The production related time that was hard to be measured are produced in the existing production management system exactly, and a grafting with solution of ERP, SCM, CMMS, etc is the study that is going to establish the possible most suitable system.

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'Brine Management through brine mining of trace metals' for developing Secondary sources of nuclear fuel

  • T.L. Prasad
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.674-680
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    • 2023
  • The brine and seawater are important and largely untapped sources of critical trace metals and elements. The coupling of selective recovery of trace metals from seawater/brine with desalination plants gives an added advantage of energy credits to desalination plants and as well as reduce the cost of desalinated water. In this paper, status review on recovery of important trace metals and other alkali metals from seawater is presented. The potential of Indian desalination plants for recovery of trace metals, based on recovery ratio of 0.35 is also highlighted. Studies carried out by the process based on adsorption using Radiation Induced Grafted (RIG) polymeric adsorbents and then fractional elutions are presented. The fouling factors due to bio fouling and dirt fouling have been estimated for various locations of interest through field trails. The pay loader in the form of compact Contactor Assembly with minimum pressure drop, for loading specially designed radiation grafted sorbent in leaflet form has been briefed, as required for plant scale facility. The typical conceptual process design details of farm assembly of project CRUDE are described.

Preparation of Protein Adsorptive Anion Exchange Membrane Based on Porous Regenerated Cellulose Support for Membrane Chromatography Application (단백질 흡착성을 갖는 막 크로마토그래피용 재생 셀룰로오스 기반 음이온 교환 다공성 분리막의 제조)

  • Seo, Jeong-Hyeon;Lee, Hong-Tae;Kim, Tae-Kyung;Cho, Young-Hoon;Oh, Taek-Keun;Park, HoSik
    • Membrane Journal
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    • v.32 no.5
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    • pp.348-356
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    • 2022
  • With the development of the bio industry, membrane chromatography with a high adsorption efficiency is emerging to replace the existing column chromatography used in the downstream processes of pharmaceuticals, food, etc. In this study, through the deacetylation reaction of two commercial cellulose acetate (CA) membranes with different pore sizes, the porous regenerated cellulose (RC) supports for membrane chromatography were obtained to attach the anion exchange ligands. The adsorptive membranes for anion exchange were prepared by attaching an anion exchange ligand ([3-(methacryloylamino) propyl] trimethylammonium chloride) containing quaternary ammonium groups on the RC supports by grafting and UV polymerization. The protein adsorption capacities of the prepared membranes were obtained through both the static binding capacity (SBC) and the dynamic adsorption capacity (DBC) measurement. As a result, the membrane chromatography with the smaller the pore size, the larger the surface area showed the highest protein adsorption capacity. Membrane chromatography which was prepared by using deacetylated commercial CA support with MAPTAC ligand (i.e., RC 0.8 + MAPTAC: 43.69 mg/ml, RC 3.0 + MAPTAC: 36.33 mg/ml) showed a higher adsorption capacity compared to commercial membrane chromatography (28.38 mg/ml).

Morphological Analysis Study for the Development of DB on the Manufacture Process of Prescription and Medicinal Food (처방 및 약선요리 제조 과정의 데이터베이스 구축을 위한 형태소 분석 연구)

  • Kim, Thae-Yul;Hwang, Su-Jung;Kim, Ki-Wook;Lee, Byung-Wook
    • Journal of Korean Medical classics
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    • v.29 no.2
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    • pp.79-90
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    • 2016
  • Objectives : Treatment using foods has already been recorded since the time of Zhou Dynasty of China. Modifications in the cooking process of medicinal food or manufactural process of herbal medicines are accompanied by the alterations in the ingredients that affect the actual efficacies of medicinal food or herbal medicine, and may have marked effects on the patients including the difficulties that may be experienced in consuming the food or taking the medicine. Therefore, systemic management is essential in such processes. Accordingly, management of such knowledge system must be standardized and conveniently administered by grafting IT technology. This study aims to overcome the problem of the failure of the knowledge system on the material-oriented medicinal herbs to apply the knowledge on the cooking process that impart marked influence on the actual efficacies of the medicinal herbs. Methods : Therefore, analysis of the cooking process or manufacturing processes of prescriptions was executed by using the morphological analysis method in natural language. In this study, we aimed to make data structure of the terminologies that represent manufacture process of prescription and medicinal food. The data structure is combinations of smallest unit in natural language. We made the database by analyzing morpheme of the natural language to express the manufacture process of prescription and medicinal food. Results & Conclusions : As the results, we can express making process of Cheonjin-won, Guseon-wangdogo and Sanyagbaegboglyeongtalagjuk in DB. It was concluded that the development of DB through the extraction of a total of 15 types of concepts including 'order', 'action' and 'continuous action', etc. was helpful in systematization of the knowledge on medicinal herbs including the manufacturing process.

Studies on the Interspecific Grafting of Almond (Almond의 종간접목(種間接木)에 관(關)한 연구(硏究))

  • Park, Kyo Soo
    • Journal of Korean Society of Forest Science
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    • v.41 no.1
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    • pp.7-18
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    • 1979
  • Almonds are one of the oldest sources of food and oil for man as used the ice cream, candy, roast, salting, chocolate, breads, backed, cookies, and flavoring ect. So, we wish to plant Almond in our country at the most parts of mountains. In this purpose we must be find out of both root stock of more compatibility and new techniques of grafting was rather simples as compared with the many steps of machinary involved today. This investigation has been carried out to reveral compatibility and practical controls of environment effectives involved in the occurence of each difference combination results in interspecific grafting of Almonds on the root stock of Prunus mandshurica and Prunus persica as materials during the 9 months period from March to November in 1978. With these selected scions were 4 varieties of Almond employing as the Hal1's hardy, Nonpareil, and Thompson grafted in the polyethylene green house with almost identical provision made for effective controls of automatical supplying to heating and mistsprayers as the $22{\sim}25^{\circ}C$ of temperature and 70~90% humidity. Following results have been obtained. Those environmental controls were more effective and practical to grafting unions and success by means veneer-grafting at the green house. 1. Hall's hardy Almond grafted on the root stock of Prunus persica was more compatibility than Prunus mandshurica. 2. The survival percentages as follows of the 95.33% of Hall's hardy/Prunus persica and 92.66% of Hall's hardy/Prunus mandshurica. And those were no significant between root stock of both species. 3. The 3 varieties of sweet Almond grafted on the root stock of P. mandshurica. And those were no significant between root stock of both species. 4. And the survival percentages as fellows. Thompson 92.66%, Nonpareil 90.66% and Kapareil 89.33% those grafted on the root stock of Prunus persica. 5. And then the survival percentage of interspecific grafts on the root Prunus mandshurica as follows of the materials of Thompson 89.66%, Nonpareil 87%, Kapareil 85%. 6. The analysis of variance were no significant among the interactions between 3 varieties Almond and 2 species of root stock plants. 7. And the growth of interspecific grafts of the high 161cm, diameter 12.3mm and length of roots 21.5cm growth as the Hall's hardy Almond grafted on the root stock of Prunus persica. 8. The root stock plants of Prunus mandshurica more effected to 6~8 days early developed leafing of scions and dark green colour than the Prunus persica. 9. The identical provision of automatic systems was more effective to graft unions and grafting process. 10. The veneer-grafting method at the green house was more effective and practical method for the mass production of Almond grafts.

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Surface Modification of Colloidal Silica Nanoparticles: Controlling the size and Grafting Process

  • He, Wentao;Wu, Danhua;Li, Juan;Zhang, Kai;Xiang, Yushu;Long, Lijuan;Qin, Shuhao;Yu, Jie;Zhang, Qin
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2747-2752
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    • 2013
  • Surface modification of colloidal silica nanoparticles without disrupting the electric double layer of nanoparticles is a major challenge. In the work, silane was employed to modify colloidal silica nanoparticles without inducing bridge flocculation obviously. The effect of pH value of the silica sol, the amount of silane in feed, and reaction temperature on the graft amount and the final size of modified particles was investigated. The increased weight loss by TG and the appearance of $T_2$ and $T_3$ except for $Q_2$ and $Q_3$ signals by CP/MAS $^{29}Si$ NMR of the modified samples verified the successful grafting of silane. The graft amount reached 0.57 mmol/g, which was slightly lower than theory value, and the particle size remained nearly the same as unmodified particles for acidic silica sol at the optimum condition. For alkaline silica sol after modification, aggregates composed of several nanoparticles connected together with silane moleculars as the bridge appeared.

EXPERIMENTAL STUDY OF EFFECTS OF THE PERIOSTEUM ON BONE FORMATION PROCESS AFTER FREEZE DRIED DEMINERALIZED ALLOGENEIC BONE GRAFTS (냉동 건조 탈회 동종골 이식후 골막이 골 형성 과정에 미치는 영향에 관한 실험적 연구)

  • Kwon, Hyeok-Do;Lee, Dong-Keun;Um, In-Woong;Min, Seung-Ki
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.17 no.4
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    • pp.337-349
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    • 1995
  • Periosteum in general is described as a specialized fibrous membrane of mesenchymal origin consisting of two basis layers : outer fibrous layer consists of irregularly arranged dense connective-tissue with fibroblasts, and inner osteogenic or cambial layer is composed of more loosely arranged fibers, greater vascularity and flatted spindle-shaped pre-osteoblasts. This periosteum may serve in controlling bone growth, especially mandibular growth has been emphasized. But, the periosteum enwrapping the facial skeleton have been studied for many years leaving a controversy in opinion regarding the function of these structures. We evaluated the bone formation activity of te periosteum in allogeneic bone grafts which bones are made of freeze-dried preparation preoperatively. We made the calvarial bone defects, 5 ${\times}$ 7mm sized, amd grafted with allogeneic bone in rats, which a half of specimens has dissected the overlying periosteum and a rest intacted. After bone grafting, we evaluated the capacity ofbone formation of periosteum, 1, 2, 4, 6, 8 weeks postoperatively. There are subtle differences of bone formation during early healing period after demineralized allogeneic bone grafting between control groups with periosteum and experimental groups without periosteum.

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