• 제목/요약/키워드: gradient composition

검색결과 218건 처리시간 0.023초

SmBCO 초전도 선재 특성에 대한 Sm:Ba:Cu 조성비의 영향 (Effects of Sm:Ba:Cu Composition Ratio on the Superconducting Properties of SmBCO Coated Conductor Prepared by using a Composition Gradient Method)

  • 김호섭;오상수;장세훈;민창훈;하홍수;하동우;고락길;염도준;문승현;정국채
    • Progress in Superconductivity
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    • 제13권1호
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    • pp.7-11
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    • 2011
  • 조성경사법을 이용하여 LMO/IBAD-MgO template 상에 EDDC 증착법을 이용하여 $Sm_{1+x}Ba_{2-x}Cu_{3+y}O_{7-d}$ 초전도 박막을 증착하였다. 테이프 형상의 기판상에 길이방향으로 $Sm_{1+x}Ba_{2-x}Cu_{3+y}O_{7-d}$ 박막의 조성비가 연속적으로 변하는 샘플을 얻을 수 있었고, 비접촉 Hallprobe를 이용하여 임계전류를 측정한 결과 조성비에 대응하는 연속적인 임계전류분포를 측정할 수 있었다. 본 조성비 영역 중 Sm:Ba:Cu = 1.01:1.99 :4.87의 조성비에서 최대의 임계전류를 보였다. 이 조성비에서 SmBCO 박막표면에 전체적으로 roof tile 형상의 결정립들이 관찰되었으며 국소적으로 2차상들이 관찰되었다. 조성 경사법을 이용하면 광범위한 조성비영역에서 신뢰도 높은 초전도특성, 결정배향성, 박막표면 형상 등을 조사할 수 있을 것으로 예상된다.

소결법에 의한 $ZrO_2/Metal$계 경사기능재료에 관한 연구(1) (A Study on Zirconia/Metal.Functionally Gradient Materials by Sintering Method(1))

  • 정연길;최성철
    • 한국세라믹학회지
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    • 제31권3호
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    • pp.321-329
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    • 1994
  • Functionally gradient materials(FGM), which have the continuous or stepwise variation in a composition and microstructure, are being noticed as the material that solves problems caused by heterogeneous interface of coating or joining. And these materials also expect new functions occured by gradient composition itself. Therefore, to examine possibility of thermal barrier materials, TZP/Mo·FGM and TZP/Ni·FGM were fabricated by sintering method. As to the sintered specimens, sintering shrinkage, relative density and Vicker's hardness in each composition were examined. The phenomena due to the difference of sintering shrinkage velocity during sintering process and the thermal stress induced through differences of thermal expansion coefficient in FGM were discussed. And the structure changes at interface and microsturcture of FGM were investigated. As a results, the difference of shrinkage between ceramic and metal was about 14% in TZP/Mo and 7% in TZP/Ni. The relative density and hardness were considerably influenced by metal content changes. Owing to unbalance of sintering shrinkage velocity between ceramic and metal, various sintering defects were occured. To control these sintering defects and thermal stress, gradient composition of FGM should be narrow. The microstructure changes of FGM depended on the ceramic or metal volume percents and were analogous to the theoretical design.

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비예혼합 대향류 화염에서 연소 분위기 압력 영향 연구 (Effects of Combustion Atmosphere Pressure on Non-premixed Counterflow Flame)

  • 이기만
    • Journal of Advanced Marine Engineering and Technology
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    • 제30권8호
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    • pp.853-862
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    • 2006
  • The present study is numerically investigated the flame structure of non-premixed counterflow jet flames using the laminar flamelet model Detailed flame structures with the fuel composition of 40% CO, 30% $H_2$. 30% $N_2$ and an oxidizer composition of 79% $N_2$ and 21% $O_2$ in a non-premixed counterflow flame are studied numerically. This study is aimed to investigate the effects of axial velocity gradient and combustion atmosphere pressure on flame structure. The results show that the role of axial velocity gradient on combustion processes is globally opposite to that of combustion atmosphere pressure. That is, chemical nonequilibrium effects become dominant with increasing axial velocity gradient, but are suppressed with increasing ambient pressure. Also, the flame strength is globally weakened by the increase of axial velocity gradient but is augmented by the increase of ambient pressure. However, flame extinction is described better on the basis of only chemical reaction and in this study axial velocity gradient and ambient pressure play a similar role conceptually such that the increase of axial velocity gradient and ambient pressure cause flame not to be extinguished and extend the extinction limit, respectively. Consequently it is suggested that a combustion process like flame extinction is mainly influenced by the competition between the radical formation reaction and the third-body recombination reaction.

AlN/Al-Ti계 경사기능재료의 개발 (Development of AlN/Al-Ti Functionally Gradient Materials)

  • 이현규;박진성;공창덕
    • 한국추진공학회지
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    • 제5권1호
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    • pp.49-59
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    • 2001
  • 경사기능재료(FGM)는 일반적으로 세라믹스나 금속과 같은 서로 다른 재료로 이루어져 있다. FGM의 성질은 조성구배, 미세조직, 기공율에 의해 변화가 일어난다. 본 연구에서는 입방체 AlN/Al-$Al_3$Ti FGM은 분말야금공정으로 제조하였고 그 특성을 관찰하였다. Al에 서로 다른 Mg와 Ti 분말을 steel 몰드에 조성구배를 폭넓게 하여 적층, 혼합하였다. 소결온도와 Mg의 양을 점점 증가시킴으로써 형성된 AlN의 양도 더 증가하였다. AlN과 $Al_3$Ti는 조성구배를 XRD 분석, 광학현미경으로 조직을 관찰하였으며 미소경도시험을 행하였다.

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Steep plasma density gradient at middle latitudes observed by DMSP and TOPEX during the magnetic storm of 11-12 April 2001

  • Park, Sa-Rah;Kim, Khan-Hyuk;Kil, Hyo-Sub;Jee, Geon-Hwa;Lee, Dong-Hun;Goldstein, J.
    • 한국우주과학회:학술대회논문집(한국우주과학회보)
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    • 한국우주과학회 2011년도 한국우주과학회보 제20권1호
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    • pp.26.3-27
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    • 2011
  • Formation of a steep plasma density gradient in the middle-latitude ionosphere during geomagnetic storms and the latitudinal migration of its location depending on the storm phase are suggested to be associated with the ionospheric signature of the plasmapause. We test this idea by using the satellite and ground observation data during the 11 April 2001 storm. The locations of the steep plasma density gradient identified by TOPEX/Poseidon (2001 LT) and DMSP (1800 and 2130 LT) satellites coincide with the ionospheric footprints of the plasmapause identified by the IMAGE satellite. This observation may support the dependence of the middle-latitude plasma density gradient location on the plasmapause motion, but does not explain why the steep density gradient whose morphology is largely different from the morphology of the middle-latitude ionization trough during quiet period is formed in association with the plasmapause. The ionospheric disturbances in the total electron content (TEC) maps shows that the steep TEC gradient is formed at the boundary of the positive ionospheric storm in low-middle latitudes and the negative ionospheric storm in middle-high latitudes. We interpret that the thermospheric neutral composition disturbance in the dayside is confined within the middle-high latitude ionospheric convection zone. The neutral composition latitudes and, therefore, the locations of the steep plasma density gradient coincide with the footprints of the plasmapause. The TEC maps show that the appearance of the steep plasma density gradient in the pre-midnight sector during the recovery phase is related to the co-rotation of the gradient that is created during the main phase.

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Vertical and longitudinal variations in plant communities of drawdown zone of a monsoonal riverine reservoir in South Korea

  • Cho, Hyunsuk;Marrs, Rob H.;Alday, Josu G.;Cho, Kang-Hyun
    • Journal of Ecology and Environment
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    • 제43권2호
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    • pp.271-281
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    • 2019
  • Background: The plant communities within reservoir drawdown zones are ecologically important as they provide a range of ecosystem services such as stabilizing the shoreline, improving water quality, enhancing biodiversity, and mitigating climate change. The aim of the study was therefore to identify the major environmental factors affecting these plant communities within the drawdown zone of the Soyangho Reservoir in South Korea, which experiences a monsoonal climate, and thereafter to (1) elucidate the plant species responses and (2) compare the soil seedbank composition along main environmental gradients. Results: Two main environmental gradients affecting the plant community structure were identified within the drawdown zone; these were a vertical and longitudinal gradient. On the vertical dimension, a hydrological gradient of flood/exposure, the annual-dominated plant community near the water edge changed to a perennial-dominated community at the highest elevation. On the longitudinal dimension from the dam to the upstream, plant species composition changed from an upland forest-edge community to a lowland riverine community, and this was correlated with slope degree, soil particle size, and soil moisture content. Simultaneously, the composition of the soil seedbank was separated along the vertical gradient of the drawdown zone, with mainly annuals near the water edge and some perennials at higher elevations. The species composition similarity between the seedbank and extant vegetation was greater in the annual communities at low elevation than in the perennial communities at higher elevation. Conclusions: The structures of plant community and soil seedbank in the drawdown zone of a monsoonal riverine reservoir were changed first along the vertical and secondly along the longitudinal gradients. The soil seedbank could play an important role on the vegetation regeneration after the disturbances of flood/exposure in the drawdown zone. These results indicate that it is important to understand the vertical and longitudinal environmental gradients affecting shoreline plant community structure and the role of soil seedbanks on the rapid vegetation regeneration for conserving and restoring the drawdown zone of a monsoonal reservoir.

PLZT 경사 기능 재료를 이용한 세라믹 엑튜에이터 (Ceramic Actuators with PLZT Functionally Gradient Material)

  • 최승철;김한수;손정호;김현재;정형진
    • 한국재료학회지
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    • 제1권2호
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    • pp.105-112
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    • 1991
  • 압전 actuator를 위한 새로운 형태의 재료를 개발하여, 그 특성들을 조사하였다. 이 압전 actuator는 세 층으로 구성되어 있다: 압전 세라믹 층, 조성이 점차로 변하는 중간층, 그리고 또 다른 압전 세라믹 층, 이러한 형태이 재료는 경사 기능 재료(Functionally Gradient Material, FGM)라 불리운다. 경사 기능 재료를 제작하기 위한 재료설계의 개념을 도입하여, FGM화에 있어서 열팽창에 의한 시편의 박리를 막기 위해 $(Pb,\;La)(Zr,\;Ti)O_3$계에서 서로 다른 세라믹스의 조성을 선택하였다. $1300^{\circ}C$, 2시간의 소성에 의해 경사 기능화된 PLZT는 약 $20\mu\textrm{m}$정도의 중간층을 형성하는 미세구조를 가지고 있었다. 경사 기능 재료에서의 유전 및 압전 등의 여러 특성은 두 접합 조성층 특성의 사이의 값을 나타내었다. 인가 전압에 따른 strain특성은 전반적으로 단일 시편의 특성보다 증가하였으며, 특히 접합 조성층에서 고압전-저유전성 조성과 저압전-고유전성 조성을 경사 기능화하였을 경우에 변위의 증가 정도가 더욱 향상되었다.

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Composition and interface quality control of AlGaN/GaN heterostructure and their 2DEG transport properties

  • Kee, Bong;Kim, H.J.;Na, H.S.;Kwon, S.Y.;Lim, S.K.;Yoon, Eui-Joon
    • Journal of Korean Vacuum Science & Technology
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    • 제4권3호
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    • pp.81-85
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    • 2000
  • The effects of $NH_3$ flow rate and reactor pressure on Al composition and the interface of AlGaN/GaN heterostructure were studied. Equilibrium partial pressure of Ga and Al over AiGaN alloy was calculated as a function of growth pressure, $NH_3$flow rate and temperature. It was found equilbrium vapor pressure of Al is significantly lower than that of Ga, thus, the alloy composition mainly controlled by Ga partial pressure. We believe that more decomposition of Ga occur at lower $NH_3$ flow rate and higher growth pressure leads to preferred Al incorporation into AlGaN. The alloy composition gradient became larger at AlGaN/GaN heterointerface at higher reactor pressures, higher Al composition and low $NH_3$ flow rate. This composition gradient lowered sheet carrier concentration and electron mobility as well. We obtained an AlGaN/GaN heterostructure with sheet carrier density of ${\sim}2{\times}10^{13}cm^{-2}$ and mobility of 1250 and 5000 $cm^2$/Vs at 300 K and 100 K, respectively.

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Phycobilisome composition in Chondrus crispus (Gigartinales, Rhodophyta) from a wild type strain and its vegetatively derived green mutant

  • Cornish, M. Lynn;O' Leary, Stephen J.B.;Garbary, David J.
    • ALGAE
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    • 제28권1호
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    • pp.121-129
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    • 2013
  • Intact phycobilisomes from a wild-type red Chondrus crispus and its vegetatively derived green mutant were isolated by centrifugation through a discontinuous sucrose density gradient. Pigment composition was subsequently characterized by spectrophotometry. Vegetative thalli of the two strains grown together for six months in the laboratory resulted in different pigment profiles. Two pigmented phycobilisome bands appeared in the sucrose gradient of the wild-type alga, a purple coloured one, and a pink one, whereas only a single blue band appeared in the gradient of the green mutant. Spectrophotometric and fluorescence analyses identified the phycobiliprotein composition of the purple band as the typical phycoerythrin-phycocyanin-allophycocyanin complement in the wild-type, but there was no detectable phycoerythrin present in the blue band of the green mutant. Sodium dodecyl sulphate, preparative polyacrylamide gel electrophoresis analysis confirmed the presence of allophycocyanin subunits in all extracts, but firm evidence of an R-phycoerythrin linker polypeptide in the blue band was missing. These results highlight the ability of C. crispus to adapt to a phycoerythrin deficiency by adjusting light harvesting pigment ratios.

Carbon and Cobalt Diffusion in Liquid Phase Sintering of WC-Co with Gradient Composition

  • Park, Dong-Kyu;Kim, Ki-Won;Jung, Woo-Hyun
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.635-636
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    • 2006
  • In this study, the diffusion behaviors of C and Co in liquid phase sintering of WC-Co system were investigated whether these two components diffused in the same direction in case of having opposite gradient each other with not being $\eta$ phase. The green compacts with controlled compositions in not being of $\eta$ phase and gradient composition which one is WC-5Co-1.2%C, the other is WC-XCo-0.2%C (where X = 5, 10, 15, 20, 25) were sintered at $1350^{\circ}C$ and $1400^{\circ}C$ and then the diffusion behaviors of C and Co were investigated by analyses of compositional change, also determined for microstructure and microhardness. Also, same testing was carried out on the specimens with dual layers sintered in upright and reverse positions to evaluate the effect of gravity on the diffusion in liquid Co. From the results of this study, we can find the fact that the direction of diffusion for C and Co in WC-Co system during liquid phase sintering was different and the effect of gravity for the liquid was insignificant. Also other physical properties were changed on the diffusion of elements.

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