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A LONGITUDINAL STUDY ON THE INTERRELATIONSHIP BETWEEN THE GROWTH CHANGE OF THE MANDIBLE AND DEVELOPMENTAL AGE OF GROWING GIRLS (성장기 소녀에서 하악골 성장 변화와 발육 연령의 상호 관계에 대한 누년적 연구)

  • Kim, Young-Joon;Sohn, Byung-Wha
    • The korean journal of orthodontics
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    • v.22 no.3 s.38
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    • pp.603-615
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    • 1992
  • This study was undertaken to investigate the interrelationship between the growth change of mandible and the developmental age of growing girls in the longitudinal data from 7 years to 15 years. The data were obtained from maturation stage of cervical vertebrae through the serial lateral cephalogram, height increment records which was taken at one year interval, menarche date through interview. On the basis of findings of this study, the following conclusions were obtained. 1. In general the growth of mandible (Ar-Pog, Ar-Go, Go-Pog) showed two peaks of growth velocity. 2. The maximum growth of mandible (Ar-Pog, Ar-Go, Go-Pog) almost appeared between stage 3 and stage 4 in maturation of cervical vertebrae. 3. It showed the tendency that the maximum increment of height appeared faster than that of mandible (Ar-Pog, Ar-Go, Pog-Go). 4. The maximum growth of height almost appeared between stage 2 and stage 3 in maturation of cervical vertebrae. 5. It showed the tendency that the menarche appeared later than the maximum growth of mandible (Ar-Pog, Ar-Go, Pog-Go). 6. The menarche almost appeared at stage 4, stage 5 in maturation of cervical vertebrae.

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Layer-by-layer assembled graphene oxide films and barrier properties of thermally reduced graphene oxide membranes

  • Kim, Seon-Guk;Park, Ok-Kyung;Lee, Joong Hee;Ku, Bon-Cheol
    • Carbon letters
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    • v.14 no.4
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    • pp.247-250
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    • 2013
  • In this study, we present a facile method of fabricating graphene oxide (GO) films on the surface of polyimide (PI) via layer-by-layer (LBL) assembly of charged GO. The positively charged amino-phenyl functionalized GO (APGO) is alternatively complexed with the negatively charged GO through an electrostatic LBL assembly process. Furthermore, we investigated the water vapor transmission rate and oxygen transmission rate of the prepared (reduced GO $[rGO]/rAPGO)_{10}$ deposited PI film (rGO/rAPGO/PI) and pure PI film. The water vapor transmission rate of the GO and APGO-coated PI composite film was increased due to the intrinsically hydrophilic property of the charged composite films. However, the oxygen transmission rate was decreased from 220 to 78 $cm^3/m^2{\cdot}day{\cdot}atm$, due to the barrier effect of the graphene films on the PI surface. Since the proposed method allows for large-scale production of graphene films, it is considered to have potential for utilization in various applications.

Synthesis and Properties of Polyimide Composites Containing Graphene Oxide Via In-Situ Polymerization

  • Zhu, Jiadeng;Lee, Cheol-Ho;Joh, Han-Ik;Kim, Hwan Chul;Lee, Sungho
    • Carbon letters
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    • v.13 no.4
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    • pp.230-235
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    • 2012
  • In this study, reduced graphene oxide/polyimide (r-GO/PI) composite films, which showed significant enhancement in their electrical conductivity, were successfully fabricated. GO was prepared from graphite using a modified Hummers method. The GO was used as a nanofiller material for the preparation of r-GO/PI composites by in-situ polymerization. An addition of 20 wt% of GO led to a significant decrease in the volume resistivity of composite films by less than nine orders of magnitude compared to that of pure PI films due to the electrical percolation networks of reduced GO created during imidization within the films. A tensile test indicated that the Young's modulus of the r-GO/PI composite film containing 20 wt% GO increased drastically from 2.3 GPa to 4.4 GPa, which was an improvement of approximately 84% compared to that of pure PI film. In addition, the corresponding tensile strength was found to have decreased only by 12%, from 113 MPa to 99 MPa.

Impaired Response Inhibition in Patients with Obsessive-Compulsive Disorder (강박장애 환자의 반응억제 결함)

  • Boo, Young Jun;Kim, Se Joo;Kang, Jee In
    • Anxiety and mood
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    • v.11 no.1
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    • pp.33-37
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    • 2015
  • Objective : Impaired response inhibition has been suggested to play an important role in the pathophysiology of obsessive-compulsive disorder (OCD). The aim of this study was to evaluate the response inhibition in patients with OCD, by using the Go/NoGo paradigm, and to better understand its associations with clinical symptoms. Methods : The participants included 63 OCD patients and 80 healthy volunteers matched in age and sex. response inhibition was evaluated using computerized Go/NoGo task, in which their commission error rates, omission error rates, and mean response times were measured. The severity of clinical symptoms in the OCD patients was assessed using Montgomery-Asberg Depression Scale and Yale-Brown Obsessive Compulsive Scale. Result : OCD patients showed significantly impaired inhibition and higher omission errors rates despite their slower response time, compared to normal controls. Clinical symptoms were not correlated with commission errors and omission errors. Conclusion : The present results indicate that impairment in response inhibition may play a critical role in the pathophysiology of OCD as a trait. These findings suggest that deficit of response inhibition may contribute to developing and maintaining clinical symptoms such as compelling need to repeat certain actions in patients with OCD.

Effects of Jingansikpung-tang Water Extract on LDH Activity of Cultured Spinal Sensory Neurons Damaged by GO (진간식풍탕 전탕액이 GO에 의해 손상된 배양 척수감각신경세포의 LDH 활성도에 미치는 영향)

  • Park Kwang Su;Kwon Kang Beam;Seong Eun Kyung;Song Yong Sun;Ryu Do Gon
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.16 no.3
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    • pp.563-566
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    • 2002
  • To evaluate the effect of Jingansikpung-tang(JST) water extract on cultured mouse spinal sensory neuron which was inhibited by glucose oxidase(GO)-induced cytotoxicity, MTT and LDH activity assay were carried out after the cultured mouse spinal sensory neuron were pre-incubated with various concentrations of JST extract for 3 hours prior to exposure of GO. The results obtained were as follows: GO, a oxygen radical, decreased the survival rate of the cultured mouse spinal sensory neuron cells on MTT assay. JST water extract have efficacy of decreasing LDH activity increasing by GO in cultured mouse spinal sensory neuron. From above the results, it is concluded that JST water extract has marked efficacy as a treatment for the damages caused in the GO-mediated oxidative process.

Graphene Oxide as a Novel Nanoplatform for Direct Hybridization of Graphene-SnO2

  • Park, Hun;Han, Tae Hee
    • Bulletin of the Korean Chemical Society
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    • v.34 no.11
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    • pp.3269-3273
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    • 2013
  • Graphene oxide (GO) has been of particular interest because it provides unique properties due to its high surface area, chemical functionality and ease of mass production. GO is produced by chemical exfoliation of graphite and is decorated with oxygen-containing groups such as phenol hydroxyl, epoxide groups and ionizable carboxylic acid groups. Due to the presence of those functional groups, GO can be utilized as a novel platform for hybrid nanocomposites in chemical synthetic approaches. In this work, GO-$SnO_2$ nanocomposites have been prepared through the spontaneous formation of molecular hybrids. When $SnO_2$ precursor solution and GO suspension were simply mixed, $Sn^{2+}$ was spontaneously formed into $SnO_2$ nanoparticles upon the deoxygenation of GO. Through further chemical reduction by adding hydrazine, reduced GO-$SnO_2$ hybrid was finally created. Our investigation for the electrocapacitive properties of hybrid electrode showed the enhanced performance (389 F/g), compared with rGO-only electrode (241 F/g). Our approach offers a scalable, robust synthetic route to prepare graphene-based nanocomposites for supercapacitor electrode via spontaneous hybridization.

Mechanical properties of epoxy composites reinforced with ammonia-treated graphene oxides

  • Park, Mi-Seon;Lee, Sangmin;Lee, Young-Seak
    • Carbon letters
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    • v.21
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    • pp.1-7
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    • 2017
  • The effects of ammonia-treated graphene oxide (GO) on composites based on epoxy resin were investigated. Ammonia solutions of different concentrations (14-28%) were used to modify GO. Nitrogen functional groups were introduced on the GO surfaces without significant structural changes. The ammonia-treated GO-based epoxy composites exhibited interesting changes in their mechanical properties related to the presence of nitrogen functional groups, particularly amine ($C-NH_2$) groups on the GO surfaces. The highest tensile and impact strength values were 42.1 MPa and 12.3 J/m, respectively, which were observed in an epoxy composite prepared with GO treated with a 28% ammonia solution. This improved tensile strength was 2.2 and 1.3 times higher than those of the neat epoxy and the non-treated GO-based epoxy composite, respectively. The amine groups on the GO ensure its participation in the cross-linking reaction of the epoxy resin under amine curing agent condition and enhance its interfacial bonding with the epoxy resin.

Fabrication and Characterization of Highly Reactive Al/CuO Nano-composite using Graphene Oxide (산화그래핀을 적용한 고반응성 Al/CuO 나노복합재 제조 및 분석)

  • Lim, YeSeul
    • Journal of Powder Materials
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    • v.26 no.3
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    • pp.220-224
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    • 2019
  • The aluminum (Al)/copper oxide (CuO) complex is known as the most promising material for thermite reactions, releasing a high heat and pressure through ignition or thermal heating. To improve the reaction rate and wettability for handling safety, nanosized primary particles are applied on Al/CuO composite for energetic materials in explosives or propellants. Herein, graphene oxide (GO) is adopted for the Al/CuO composites as the functional supporting materials, preventing a phase-separation between solvent and composites, leading to a significantly enhanced reactivity. The characterizations of Al/CuO decorated on GO(Al/CuO/GO) are performed through scanning electron microscopy, transmission electron microscopy, and energy dispersive X-ray spectroscopy mapping analysis. Moreover, the functional bridging between Al/CuO and GO is suggested by identifying the chemical bonding with GO in X-ray photoelectron spectroscopy analysis. The reactivity of Al/CuO/GO composites is evaluated by comparing the maximum pressure and rate of the pressure increase of Al/CuO and Al/CuO/GO. The composites with a specific concentration of GO (10 wt%) demonstrate a well-dispersed mixture in hexane solution without phase separation.

Synthesis of Au@TiO2 Core-shell Nanoparticle-decorated rGO Nanocomposite and its NO2 Sensing Properties

  • Kumar Naik, Gautam;Yu, Yeon Tae
    • Journal of Sensor Science and Technology
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    • v.28 no.4
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    • pp.225-230
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    • 2019
  • $Au@TiO_2$ core-shell decorated rGO nanocomposite (NC) was prepared using a simple solvothermal method followed by heat treatment for gas sensor application. The crystal structure and morphology of the composites were characterized by X-ray powder diffraction and transmission electron microscopy, respectively. The $NO_2$ sensing response of the $Au@TiO_2/rGO$ NC was tested at operating temperatures from $250^{\circ}C$ to $500^{\circ}C$, and was compared with those of the bare rGO and $Au@TiO_2$ core-shell NPs. The $Au@TiO_2/rGO$ NC-based sensor showed a far higher response than the rGO or $Au@TiO_2$ core-shell based sensors, with the maximum response detected when the operating temperature was $400^{\circ}C$. This improved response was due to the high rGO gas absorption capability for $NO_2$ gas and the catalytic effect of $Au@TiO_2$ core-shell NPs in oxidizing $NO_2$ to $NO_3$.

Activated Carbon-Embedded Reduced Graphene Oxide Electrodes for Capacitive Desalination

  • Tarif Ahmed;Jin Sun Cha;Chan-gyu Park;Ho Kyong Shon;Dong Suk Han;Hyunwoong Park
    • Journal of Electrochemical Science and Technology
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    • v.14 no.3
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    • pp.222-230
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    • 2023
  • Capacitive deionization of saline water is one of the most promising water purification technologies due to its high energy efficiency and cost-effectiveness. This study synthesizes porous carbon composites composed of reduced graphene oxide (rGO) and activated carbon (AC) with various rGO/AC ratios using a facile chemical method. Surface characterization of the rGO/AC composites shows a successful chemical reduction of GO to rGO and incorporation of AC into rGO. The optimized rGO/AC composite electrode exhibits a specific capacitance of ~243 F g-1 in a 1 M NaCl solution. The galvanostatic charging-discharging test shows excellent reversible cycles, with a slight shortening in the cycle time from the ~260th to the 530th cycle. Various monovalent sodium salts (NaF, NaCl, NaBr, and NaI) and chloride salts (LiCl, NaCl, KCl, and CsCl) are deionized with the rGO/AC electrode pairs at a cell voltage of 1.3 V. Among them, NaI shows the highest specific adsorption capacity of ~22.2 mg g-1. Detailed surface characterization and electrochemical analyses are conducted.