• Journal of the Korean Chemical Society
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• v.54 no.4
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• pp.387-394
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• 2010

The theoretical calculations for $B_nH_n$, $B_nH_{n+1}$, $B_nH_{n+2}$ (n = 3-6) have been considered at the B3LYP level of theory with the 6-311G$^*$ basis set. The optimized geometries, harmonic vibrational frequencies, and binding energies are evaluated to elucidate the thermodynamic stability and spectroscopic properties. The harmonic vibrational frequencies for the molecules considered in this study show all real numbers implying true minima and the binding energies are corrected using zero-point vibrational energies (ZPVE). The binding energies and average energies due to increasing of BH monomer are predicted.

• Bulletin of the Korean Chemical Society
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• v.32 no.3
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• pp.793-799
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• 2011

We report the complexation behavior of calix[4]arenemonoquinone-triacid (CTAQ), which is an electroactive and water-soluble receptor for calcium ion. UV-visible and NMR spectroscopic studies revealed that CTAQ in aqueous media forms 1:2 as well as 1:1 (metal ion:CTAQ) stoichiometric complexes with $Ca^{2+}$, $Sr^{2+}$, and $Ba^{2+}$ ions. The nonlinear fitting of titration curves based on UV-visible absorption spectra showed that the binding constants of CTAQ for $Ca^{2+}$ ion are 4 $({\pm}2){\times}10^6\;M^{-1}$ for 1:1 and 1.4 $({\pm}0.5){\times}10^{11}\;M^{-2}$ for 1:2 complex. NMR conformational studies and the titration curves corroborate that the $Ca^{2+}$:CTAQ complex in aqueous solution is not present in the form of merely 1:1 one, being consistent with UV-visible spectrophotometric results. The Monte Carlo simulation supports the presence of a stable conformer of 1:2 complexes in which a $Ca^{2+}$ ion is interposed between two CTAQs at the global minimum. This is the first model of 1:2 stoichiometric complex of calix[4]arene and alkaline earth ions in aqueous media.

• Journal of the Korean Geotechnical Society
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• v.15 no.3
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• pp.27-40
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• 1999

In limit equilibrium methods(LEM), all methods employ the same definition of the safety factor as a ratio of the shear strength of the soil to the shear stress required for equilibrium, employing certain assumptions with regard to equilibrium. In addition, in the conventional finite element method of analysis, the minimum safety factor is obtained assuming certain slip surfaces after the state of stress are found. Although the stress states are obtained from the finite element method(FEM), the slope stability analysis follows the conventional method that assumes a potential slip surface. In this study, a slope stability analysis based on FEM is developed to locate the slip surface by tracking the weakest points in the slope based on the local safety factor considering the magnitude and direction of the shear stresses. It has also been applied to be compared with the slip surfaces predicted by LEM. A computer program has been developed to draw contour lines of the local safety factors automatically. This method is illustrated through a simple hypothetical slope, a natural soil slope, and a dam slope. The developed method matches very well with the conventional LEM methods, with slightly lower global safety factors.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.65 no.3
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• pp.411-418
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• 2016

In accordance with global energy conservation policies such as MEPS(Minimum Energy Performance Standard), electric motor industry is moving to super-high-efficiency machines and research to develop IE4 (International Energy Efficiency Class4) motors has been launched. In this situation, SynRM (Synchronous Reluctance Motor) has been attracting attention in place of induction motor which hardly provides super premium efficiency. As a result, much research on SynRM is being performed at home and abroad. Also, some products have already been appearing in the market. Compared to induction motor, SynRM has better efficiency per unit area and wider operating range. Although the utilization of control system in synchronous motor results in higher prices, we still need to concentrate on developments of SynRM so as to comply with the new policies. This study demonstrated the electromagnetic design methods of super-premium SynRM while maintaining the frame of existing IE3 induction motor for blower. We documented the design procedures for generating high saliency which is the most essential and mechanical stress analysis is also treated. In conclusion, we proved the validity of our design by manufacturing and testing our SynRM models.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.30 no.6
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• pp.559-566
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• 2017

This paper proposes a new composite deckplate system reinforced with inverted triangular truss girders(called 'D Deck'), which does not require the use of temporary supports at construction stage. The proposed system retains increased stiffness and strength while keeping the absolute floor height change to a minimum level and can be utilized as floor systems of various types beam members such as the conventional wide-flange and U-shaped composite beams. In order to evaluate the performance of the proposed system, five specimens with a span of 5.5 m were fabricated and tested under field loading conditions consisting of several intermediate steps. The load-deflection curves of each specimen were plotted and compared with the nonlinear three-dimensional finite element analysis results. The comparison showed that the effective load sharing between the truss girders and floor deck occurs and the maximum deflection under construction stage loading is well below the limit estimated by the provisions in Korea Building Code.

• Journal of Digital Contents Society
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• v.11 no.4
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• pp.607-614
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• 2010

History centered knowledge based story-telling project planning tool supports the process of story creation in narrative genre about history of families or individuals. Narrative fields not only include drama, mythology, legend, history but also non-verbal epics such as movie, play, ballet and opera. But as verbal epic, this research paper focuses on the family history and individual history of each household. This story-telling planning tool redevelops each genre of story-telling about family history through sampleDB and informationDB, and it is widely applicable in concreting high quality stories in both its content and value. Reduces the time of planning story-telling, and impose minimum expenses in human resources. Content about family history is one of the most the fundamental and renowned contents in Story-telling but planning tool that is easily applicable in creating such content does not exist in statue quo. In this current system lacking creative infra, this research paper seeks to provide a planning tool that public can easily utilize, and by systemizing the tool. it aims to create a creative contents tool model applicable in variety of genres.

• Journal of Positioning, Navigation, and Timing
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• v.7 no.2
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• pp.53-59
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• 2018

This paper proposes a pseudo-random beamforming technique for time-synchronized mobile base stations (BSs) for multi-cell downlink networks which have mobility. The base stations equipped with multi-antennas and mobile stations (MSs) are time-synchronized based on global positioning system (GPS) signals and generate a number of transmit beamforming matrix candidates according to the predetermined pseudo-random pattern. In addition, MSs generate receive beamforming vectors that correspond to the beam index number based on the minimum mean square error (MMSE) using transmit beamforming vectors that make up a number of transmit beamforming matrices and wireless channel matrices from BSs estimated via the reference signals (RS). Afterward, values of received signal-to-interference-plus-noise ratio (SINR) with regard to all transmit beamforming vectors are calculated, and the resulting values are then feedbacked to the BS of the same cells along with the beam index number. Each of the BSs calculates each of the sum-rates of the transmit beamforming matrix candidates based on the feedback information and then transmits the calculated results to the BS coordinator. After this, optimum transmit beamforming matrices, which can maximize a sum-rate of the entire cells, are selected at the BS coordinator and informed to the BSs. Finally, data signals are transmitted using them. The simulation results verified that a sum-rate of the entire cells was improved as the number of transmit beamforming matrix candidates increased. It was also found that if the received SINR values and beam index numbers are feedbacked opportunistically from each of the MSs to the BSs, not only nearly the same performance in sum-rate with that of applying existing feedback techniques could be achieved but also an amount of feedback was significantly reduced.

• Advances in Energy Research
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• v.5 no.3
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• pp.227-237
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• 2017

The continuous increase of emission rates of green house gases and the effects on global warming added a new dimension to the problem of substituting the petroleum and its derivatives by environment friendly and sustainable energy sources for the world. Solar and wind energy appear at the top of the list of renewable of high potential, widely available, of dominated technology and well accepted. Brazil is one of the few countries in the world that receives number hours of sunshine exceeding 3,000 hours per year with a daily average of 4.5 to 6 kWh. However, this potential is largely unexplored and poorly tapped. The number of renewable systems implanted in Brazil has grown in recent years, but still insignificant when compared, for example, with Germany and Spain among others. This paper presents the results of an optical study on small concentration solar collector with evacuated tube enveloping the absorber and internal reflective surface fixed on the bottom part of the evacuated tube. The designed collector has a 2D geometrical concentration ratio between 2.455 and 4.91. The orientation of the solar collector, the ratio of the radius of the receiver to the radius of the absorber, the incidence angle for each period of the year, the collector inclination angle, the aperture angle of the reflective surface, concentration and optical efficiency were determined. The ray traces and flux distribution on the absorber of the evacuated tube solar collector were determined by using the program Ray Optics Simulation. The optical efficiency varies during the year according to the solar declination. For the periods were the solar declination is close to zero the efficiencies are maximum, and the variation during the day is around 25.88% and 99.9%. For the periods were the solar declination is maximum the efficiencies are minimum, and the variation during the day is around 23.78% and 91.79%.

• Journal of the Society of Naval Architects of Korea
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• v.46 no.2
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• pp.97-104
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• 2009

Ever increasing fuel prices, almost doubled in the last three years, and global pressure to reduce their environmental impact have been enforcing commercial vessel operators and designers to re-assess current vessel designs with emphasis on their propulsion systems and operational practices. In this paper the "Inclined Keel Hull (IKH)" concept, which facilitates to use larger propeller diameter in combination with lower shaft speed rates and hence better transport efficiency, is explored for a modern 3600 TEU container vessel with the aim of fitting an 13 % larger diameter propeller (and hence resulting 20% lower rpm) to gain further power saving over the similar size basis container ship with conventional "level keel" configuration. It appears that successful application of the "inclined keel Hull" concept is a fine balance amongst the maximum gain in propulsive efficiency, minimum increase in hull resistance and satisfaction of other naval architectural and operational requirements. In order to make the concept economically more viable, this paper concentrates on the fore body design with the possible combination of increase of volume in its fore body to recover the expected volume loss in the aft body due to the space for larger propeller and its low wave-making resistance to minimize the efficiency loss using a well-established optimization software.

• Journal of the Korean Solar Energy Society
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• v.39 no.6
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• pp.1-13
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• 2019

With the adoption of the Paris Agreement, a new climate regime is intensifying the global interest in reducing greenhouse gas emissions. In the meantime, Korea is preparing to introduce a new renewable energy carbon certification system in order to activate the use of renewable energy and to reduce carbon emissions in the entire life cycle of manufacturing and disposal of renewable energy facilities. Therefore, this study aims to identify the implications for the introduction of the carbon certification system and to establish a theoretical basis for the system design by examining the status of overseas carbon certification, international trade norms and trade disputes. As a result, carbon emissions certification is being implemented in developed countries such as EU, UK, France, USA and Japan, but only France, Germany and EU have adopted carbon certification for renewable energy sector. The analysis of the WTO TBT Agreement and GATT also confirmed the possibility of a violation of the international trade rules of the carbon certification system and derived nine international technical standards related to carbon certification. Finally, by examining the case of trade disputes related to environmental labeling, the minimum requirements to be considered at the institutional design stage were drawn to eliminate the possibility of trade disputes.