• Journal of the Microelectronics and Packaging Society
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• v.11 no.2 s.31
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• pp.17-22
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• 2004

In this study, BNT($BaO-Nd_{2}O_3-TiO_2$) and $70P_{2}O_5-5B_{2}O_3-(25-x)BaO-xNa_{2}O$ glass-ceramic composites were fabricated and investigated in order to apply for low temperature cofired ceramic. The prepared BNT based glass-ceramic composites were sintered at $800{\sim}950^{\circ}C$ with the glass fit contents ranging from 10 to $15\;wt\%$. The properties such as sintering and dielectric property were investigated in the ceramic compositions according to the phosphate glass frit. The dielectric constant was varied between 10 to 40 and shrinkage rate was increased according to increasing glass frit.

• Journal of the Korean Ceramic Society
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• v.26 no.5
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• pp.677-681
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• 1989

On the preparation of silica glass by sol-gel process, we used fine powder of silica gel to prevent cracking. In this case, the best condition of silica glass preparation is the contents of 10~40wt% seed and the gelation time of solution in contract. The dried gels conversed to silica glass by heat treatment up to 125$0^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.28 no.4
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• pp.324-328
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• 1991

Monolithic silica gel and glass were prepared from TMOS solution with high concentration of HCl. Appearance of the dried gels and gelation time varied with content of HCl and H2O were observed in the TMOS-CH3OH-HCl-H2O system. The conversion from gel to glass during heat treatment stage was investigated using TG-DTA, XRD, IR and SEM and characteristics of the gel were examined by measuring bulk density, linear shrinkage and Vicker's hardness. A transparent silica glass was prepared from the gel after heat treatment at 1050℃.

• Journal of the Korean Ceramic Society
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• v.29 no.6
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• pp.451-458
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• 1992

Dense glass-ceramics for low firing temperature substrate were prepared by addition of CeO2 flux to the glass of MgO-Al2O3-SiO2 system. Glass powders were fabricated by melting at 150$0^{\circ}C$ and ball milling. Glass powder compacts were sintered at 800~100$0^{\circ}C$ for 3h. The crystallization and the shrinkage behaviors of glass powder compacts were analyzed by XRD, DTA and TMA. The shrinkage of glass powder compact increased with increasing the amount of CeO2. Because the softening temperature decreased and the crystallization temperature increased with increasing the amount of CeO2. Apparently, addition of CeO2 prevented formation of $\mu$-cordierite phase from the glass-ceramics and improved formation of $\alpha$-cordierite phase. Therefore crystallization properties were enhanced.

• Journal of the Korean Ceramic Society
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• v.37 no.6
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• pp.545-551
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• 2000

Sintering behaviors of the glass-alumina composites for low firing temperature were investigated as a function of the particle size of glass frit. The system of glass frit was Pb-B-Si-Al-O. The median particle sizes of the glass frits were 2.72$\mu\textrm{m}$, 2.67$\mu\textrm{m}$ and 1.33$\mu\textrm{m}$, which were prepared with changing ball-milling times as 24 h, 48 h and 96 h. The glass-alumina composites showed maximum density at certain temperature, and further heating led to dedensification behaviors, so called over-firing. The sintering temperature, which showed maximum density, raised from 425$^{\circ}C$ to 475$^{\circ}C$ with increase of particle size of glass frit from 1.33$\mu\textrm{m}$ to 2.72$\mu\textrm{m}$. Especially, the over firing behaviors, which were occurred at high sintering temperatures, were greatly increased with decrease of particle size of glass frit.

• Journal of the Korean Ceramic Society
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• v.19 no.1
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• pp.24-34
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• 1982

The effect of the several variables on wetting of AISIB1113 steel by molten glass was studied by Sessible-drop method. Experimental variables were temperature, firing atmospheres, Fe2O3 addition to the sealing glass and steel surface conditions. The degree of wetting in terms of contact angles between molten glass and metal tested at different test conditions was analyzed by using Young's equation. The results showed that contact angles in H2 atmosphere in the glass metal systems were high but in N2 atmosphere, were small for studied glass metal systems. Especially, when the glass drop was in contact with oxidized steel in N2 atmosphere, The best adherence with contact angle of approximately 9°was obtained. In the case of Fe2O3 addition in glass contact angles subtantially increased due to the increase of surface tension of glass. Wetting phenomena were also discussed under the basis of these experimental results.

• Journal of the Korean Ceramic Society
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• v.35 no.12
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• pp.1274-1279
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• 1998

The glass forming ability of the PbO-B2O3-TiO3-BaO system was investigated in relation to transitieon tem-peratures and the atomic ratio between constituents. Glass forming tendency was improved as the tem-peratures and the atomic ratio between constituents. Glass forming tendency was improved as the tem-perature differences between liquidus temperature and crystallization(or glass transition) temperature de-creased and the temperature difference between crystallization and glass transition temperature increases. The atomic ratio could be used as a criterion to deign glass systems. The interposition of B and Ba atoms between Pb and Ti atoms was one of important factors in glass formation.

• Journal of the Korean Ceramic Society
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• v.52 no.2
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• pp.92-102
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• 2015

Current plans for legacy nuclear wastes stored in underground tanks at the U.S. Department of Energy's Hanford Site in Washington are that they will be separated into high-level waste and low-activity waste fractions that will be vitrified separately. Formulating optimized glass compositions that maximize the waste loading in glass is critical for successful and economical treatment and immobilization of these nuclear wastes. Glass property-composition models have been developed and applied to formulate glass compositions for various objectives for the past several decades. Property models with associated uncertainties combined with composition and property constraints have been used to develop preliminary glass formulation algorithms designed for vitrification process control and waste-form qualification at the planned waste vitrification plant. This paper provides an overview of the current status of glass property-composition models, constraints applicable to Hanford waste vitrification, and glass formulation approaches that have been developed for vitrification of hazardous and highly radioactive wastes stored at the Hanford Site.

• Korean Journal of Materials Research
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• v.19 no.11
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• pp.613-618
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• 2009

We designed new compositions for lead free and low temperature sealing glass frit of $ZnO-V_2O_5-P_2O_5$ system, which can be used for PDP (Plasma Display Panel) or other electronic devices. The $ZnO-V_2O_5-P_2O_5$ system can be used as a sealing material at temperatures even lower than 430$^{\circ}C$. This system, however, showed lower bonding strength with glass substrate compared to commercialized Pb based sealing materials. So, we added $TiO_2$ as a promoter for bonding strength. We examined the effect of $TiO_2$ addition on sealing behaviors of $ZnO-V_2O_5-P_2O_5$ glasses with the data for flow button, wetting angle, temporary & permanent residual stress of glass substrate, EPMA analysis of interface between sealing materials and glass substrate, and bonding strength. As a result, sealing characteristics of $ZnO-V_2O_5-P_2O_5$ system glasses were improved with $TiO_2$ addition, but showed a maximum value at 5 mol% $TiO_2$ addition. The reason for improved bonding characteristics was considered to be the chemical interaction between glass substrate and sealing glass, and structural densification of sealing glass itself.

• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.394-399
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• 1999

As the prosthetic application of natural mineral substituted for chemical reagent, composites and a glass-ceramics containing hydro-xyapatite isolated from tuna bone were prepared by solid state reaction. On x-ray examinations, the major phases of composites were identified as pseudowollastonite(${\alpha}-CaSiO_3$) and ${\beta}$-tricalcium phosphate($\beta$-TCP) and the phase of a glass-ceramics was observed as $\beta$-TCP and fluoroapatite caused by $CaF_2$ respectively. SEM images depict that the microstructures of grain at the composites were a function of temperature. The measured strength of a glass-ceramics prepared at $900^{\circ}C$ for 4 hr in air was 90 MPa as a 4-point bending method and this value was similar to the cortical bone, as 50~150 MPa but it was lower than its maximum strength.