• 제목/요약/키워드: glass structure

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A Solid-state 27Al MAS and 3QMAS NMR Study of Basaltic and Phonolitic Silicate Glasses (현무암과 포놀라이트 비정질 규산염의 원자구조 차이에 대한 고상핵자기 공명 분광분석 연구)

  • Park, Sun Young;Lee, Sung Keun
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.1
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    • pp.61-69
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    • 2015
  • While the macroscopic properties and eruption style of basaltic and phonolitic melts are different, the microscopic origins including atomic structures are not well understood. Here we report the atomic structure differences of glass in diopside-anorthite eutectic composition (basaltic glass) and phonolitic glass using high-resolution 1D and 2D solid-state Nuclear Magnetic Resonance (NMR). The $^{27}Al$ MAS NMR spectra for basaltic glass and phonolitic glass show that the full width at half maximum (FWHM) of Al for basaltic glass is about twice than phonolitic glass, suggesting the topological disorder of basaltic magma is larger than that of phonolitic magma. The $^{27}Al$ 3QMAS NMR spectra for basaltic glass and phonolite glass show much improved resolution than the 1D MAS NMR, resolving Al and Al. Approximately 3.3% of Al is observed for basaltic glass, demonstrating the configurational disorder of basaltic magma is larger than phonolitic magma. This result confirms that the topological disorder of Al in basaltic glass is larger than that of phonolitic glass. The observed structural differences between basaltic glass and phonolitic glass can provide an atomistic origin for change of the macroscopic properties with composition including viscosity.

Optimum Design of Glass Net in 2[MVA] Mold Transformer (2[MVA] 배전용 몰드변압기의 글라스넷 형상 최적설계)

  • Jeon, Mun-Ho;Kim, Chang-Eob
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.1
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    • pp.107-112
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    • 2011
  • In this paper, the optimum design of the glass net shape was studied to minimize the electric field of mold transformer. The glass net is used for reinforcement in structure between coils and epoxy, but it can cause to increase the electric field and the partial discharge. Therefore, the optimum design of glass net is required to minimize the electric field. In this paper, the objective function was approximated by using response surface method and then Zoom-in method was used for optimal design to minimize the electric field. The electric field was analysed using finite element method for each shape of glass nets.

Development of the Activity Type Smart Concrete using the Glass Pipe

  • Kim, Ie-Sung;Kim, Wha-Jung
    • Corrosion Science and Technology
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    • v.4 no.1
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    • pp.29-32
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    • 2005
  • A various structural materials are used in construction projects such as a stone, concrete, steel materials. Between of them, concrete are used widely. The compressive strength of concrete is high, and its maintenance and management is comparatively easy. The R.C Building will be superannuated as time passes. This program is generated by propagation of cracks. In order to manage such cracks, time and efforts, expense, etc. are required. In this study, glass sensors were embedding in a model beam and column and leakage of fluorescence and adhesive material was investigated. Further, currents in glass pipe were observed to find the leakage of liquid in glass pipes. Progressive cracks generated by cause the fracture of glass pipes. Therefore, the liquid become to flow and electric current stops, and the cracked part of the member can be found easily. Moreover, the adhesive delays progressive cracking system that responds in air, and the life of a structure can be made to extend. The purpose of this research is to develop of low price sensors that can perform of self-diagnosis in addition to ability of concrete repair concrete to damage.

Shrinkage Free Sintering of Low Temperature Cofired Ceramics by Glass Infilteration

  • Yeo, Dong-Hun;You, Jung-Hun;Shin, Hyo-Soon;Kim, Jong-Hee
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1218-1219
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    • 2006
  • The shrinkage variation of Low Temperature Cofired Ceramics(LTCC) limits the size of the substrates that impose limitations on embedded passive components. This paper focuses on the method of minimizing or controlling planar shrinkage and reducing distortion during firing. The laminated sheets of alumina and glass were sintered at varying temperature, and depending on the amount of the glass ceramics. When the sintered of multi-layer structure with $Al_2O_3/Glass/Al_2O_3$, the glass infiltrated entirely into $Al_2O_3$ layer at the temperature of about $950^{\circ}C$ or higher.

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Transformer-based glass area detection method (트랜스포머기 반 유리 영역 검출방법)

  • Hu, Xiaohang;Gao, Rui;Yang, Seung-Jun;Cho, Kyungeun
    • Proceedings of the Korea Information Processing Society Conference
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    • 2022.11a
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    • pp.648-649
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    • 2022
  • Glass is a common object in living environments, but even humans are sometimes unable to identify it. This study proposes a method for detecting glass area by learning edge information from images. The network structure of Transformer is used to accept the base features extracted by backbone and extract the boundary information of RGB images, and both features are used to learn the features of glass area and determine the glass area based on these boundary features. The experimental results show that our proposed method can detect glass area in images.

Status of Quartz Glass Crucible (석영유리 도가니 국내외 현황)

  • Noh, Sunghun;Kang, NamHun;Yun, Heuikeun;Kim, Hyeong-Jun
    • Ceramist
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    • v.22 no.4
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    • pp.452-463
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    • 2019
  • A quartz glass crucible is the essential material for manufacturing silicon ingots such as semiconductors and solar cells. Quartz glass crucibles for semiconductors and solar cells are made similar, but differ in surface purity, structure and durability. Recently, ultra high purity synthetic glass crucibles for semiconductors have become more important due to foreign problems. In Korea, it has succeeded in producing 28-inch quartz glass crucibles through the past 10 years. However, 32-inch synthetic quartz glass for the production of silicon ingots for semiconductors is not up to the level of advanced technology, and the technology gap is expected to be 2 to 3 years. In order to overcome these technological gaps and localize synthetic quartz glass ware, close cooperation between production companies and demand companies and localization of synthetic quartz glass powder must also be made. In addition, if government support can be added, faster results can be expected.

Effect of SiO2/B2O3 ratio on Li ion conductivity of a Li2O-B2O3-SiO2 glass electrolyte

  • Kim, Young Han;Yoon, Mi Young;Lee, Eun Jung;Hwang, Hae Jin
    • Journal of Ceramic Processing Research
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    • v.13 no.spc1
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    • pp.37-41
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    • 2012
  • A lithium ion conducting borosilicate glass was fabricated by a conventional melt quenching technique from a mixture of Li2CO3, B2O3 and SiO2 powders. The Li ion conductivity of the lithium borosilicate glasses was evaluated in terms of the SiO2/B2O3 ratio. In the Li2O-B2O3-SiO2 ternary glass, the glass forming region decreases with an increasing Li2O content. At the same Li2O, the crystallization tendency of the glass samples increases with the SiO2/B2O3 ratio, resulting in a reduced glass forming region in the Li2O-B2O3-SiO2 ternary glass. The electrical conductivity moderately depends on the SiO2/B2O3 ratio in the Li2O-B2O3-SiO2 ternary glass. The conductivity of the glasses slightly increases with the SiO2/B2O3 ratio. The observed phenomenon can be explained by the modification of the glass structure as a function of the SiO2 content.

Micro-deformation behavior of Brittle Hf-based Metallic Glass during Mechanical Milling (기계적 합금화 공정에 의한 Hf계 비정질 분말의 미세변형거동 관찰)

  • Kim, Song-Yi;Lee, A-Young;Cha, Eun-Ji;Kwon, Do-Hun;Hong, Sung-Uk;Lee, Min-Woo;Kim, Hwi-Jun;Lee, Min-Ha
    • Journal of Powder Materials
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    • v.25 no.3
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    • pp.246-250
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    • 2018
  • In this study, we investigate the deformation behavior of $Hf_{44.5}Cu_{27}Ni_{13.5}Nb_5Al_{10}$ metallic glass powder under repeated compressive strain during mechanical milling. High-density (11.0 g/cc) Hf-based metallic glass powders are prepared using a gas atomization process. The relationship between the mechanical alloying time and microstructural change under phase transformation is evaluated for crystallization of the amorphous phase. Planetary mechanical milling is performed for 0, 40, or 90 h at 100 rpm. The amorphous structure of the Hf-based metallic glass powders during mechanical milling is analyzed using differential scanning calorimetry (DSC) and X-ray diffraction (XRD). Microstructural analysis of the Hf-based metallic glass powder deformed using mechanical milling reveals a layered structure with vein patterns at the fracture surface, which is observed in the fracture of bulk metallic glasses. We also study the crystallization behavior and the phase and microstructure transformations under isothermal heat treatment of the Hf-based metallic glass.

Surface Control of Planarization Layer on Embossed Glass for Light Extraction in OLEDs

  • Cho, Doo-Hee;Shin, Jin-Wook;Moon, Jaehyun;Park, Seung Koo;Joo, Chul Woong;Cho, Nam Sung;Huh, Jin Woo;Han, Jun-Han;Lee, Jonghee;Chu, Hye Yong;Lee, Jeong-Ik
    • ETRI Journal
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    • v.36 no.5
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    • pp.847-855
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    • 2014
  • We developed a highly refractive index planarization layer showing a very smooth surface for organic light-emitting diode (OLED) light extraction, and we successfully prepared a highly efficient white OLED device with an embossed nano-structure and highly refractive index planarization layers. White OLEDs act as an internal out-coupling layer. We used a spin-coating method and two types of $TiO_2$ solutions for a planarization of the embossed nano-structure on a glass substrate. The first $TiO_2$ solution was $TiO_2$ sol, which consists of $TiO_2$ colloidal particles in an acidic aqueous solution and several organic additives. The second solution was an organic and inorganic hybrid solution of $TiO_2$. The surface roughness ($R_a$) and refractive index of the $TiO_2$ planarization films on a flat glass were 0.4 nm and 2.0 at 550 nm, respectively. The J-V characteristics of the OLED including the embossed nano-structure and the $TiO_2$ planarization film were almost the same as those of an OLED with a flat glass, and the luminous efficacy of the aforementioned OLED was enhanced by 34% compared to that of an OLED with a flat glass.

Structure and Thermal Properties of SnO2-(1-x)P2O5-xB2O3 Glasses (SnO2-(1-x)P2O5-xB2O3 유리의 열적, 구조적 특성)

  • An, Yong-Tae;Choi, Byung-Hyun;Ji, Mi-Jung;Chang, Woo-Suk;Bae, Hyun;Hwang, Hae-Jin
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.117-121
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    • 2010
  • $SnO_2-(1-x)P_2O_5-xB_2O_3$ glass system were prepared by melt-quenching technique in the compositional series containing 50, 55 and 60 mol% of $SnO_2$. Local structure of the glasses was investigated by Raman and FT-IR measurements. A large glass-forming region was found at the phosphate side of the ternary system with homogeneous glasses containing up to 5~25 mol% of $B_2O_3$. According as content of $B_2O_3$ increases, theraml expansion coefficient of glass decreased but transition temperature and softening temperature increased. Because these phenomenon changed local structure of glass. According as content of $B_2O_3$ increases, quantity of bridging oxygen increased. Also, according as content of $SnO_2$ increases, confirmed that quantity of non-bridging oxygen increases.