• 제목/요약/키워드: general forms

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Adsorption Mechanisms of NH3 on Chlorinated Si(100)-2×1 Surface

  • Lee, Hee-Soon;Choi, Cheol-Ho
    • Bulletin of the Korean Chemical Society
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    • 제33권3호
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    • pp.775-778
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    • 2012
  • The potential energy surfaces of ammonia molecule adsorptions on the symmetrically chlorinated Si(100)-$2{\times}1$ surface were explored with SIMOMM:MP2/6-31G(d). It was found that the initial nucleophilic attack by ammonia nitrogen to the surface Si forms a $S_N2$ type transition state, which eventually leads to an HCl molecular desorption. The second ammonia molecule adsorption requires much less reaction barrier, which can be rationalized by the surface cooperative effect. In general, it was shown that the surface Si-Cl bonds can be easily subjected to the substitution reactions by ammonia molecules yielding symmetric surface Si-$NH_2$ bonds, which can be a good initial template for subsequent surface chemical modifications. The ammonia adsorptions are in general more facile than the corresponding water adsorption, since ammonia is better nucleophile.

A Goneral Procedure for Testing Equivalence

  • Sung Nae Kyung
    • Communications for Statistical Applications and Methods
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    • 제5권2호
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    • pp.491-501
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    • 1998
  • Motivated by bioequivalence studies which involve comparisons of pharmaceutically equivalent dosage forms, we propose a more general decision rule for showing equivalence simultaneously between multiple means and a control mean. Namely, this testing procedure is concerned with the situation in that one must make decisions as to the bioequivalence of an original drug product and several generic formulations of that drug. This general test is developed by considering a spherical confidence region, which is a direct extension of the usual t-based confidence interval rule formally approved by the U.S. Food and Drug Administration. We characterize the test by the probability of rejection curves and assess its performance via Monte-Carlo simulation. Since the manufacturer's main concern is the proper choice of sample sizes, we provide optimal sample sizes from the Monte-Carlo simulation results. We also consider an application of the generalized equivalence test to a repeated measures design.

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석면과 건강에 대한 이슈 (Critical Issues on Health Risk of Asbestos)

  • 윤충식
    • 한국환경보건학회지
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    • 제35권5호
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    • pp.426-432
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    • 2009
  • Asbestos is a commercial term of natural occurring silicated minerals and forms long, thin fibers. Chrysotile, the serpentine asbestos, accounts for most use in commercial use. Asbestos is well known health hazard material and it is proved that inhalation of asbestos fibers leads to increased risk of developing several diseases such as lung cancer, mesothelioma, asbestosis. In these days, people most at risk for exposure are maintenance and construction workers and general citizens who are working on and close to the work area at which asbestos containing material is disturbing. Non asbestiform, though its chemical composition is same with regulated asbestos, is known to be less hazardous than asbestiform. Exposure guideline, 0.01 f/ml, is not safe level in terms of health risk. It is reasonable to take preventable action when asbestos is suspicious. In Korea, it is necessary to clarify the concept between hazard and risk, to differentiate asbestiform from non asbestiform, to make regulations for compensation for asbestos related patients, to manage future exposure for general citizens.

REMARKS ON FIXED POINT THEOREMS OF DOWNING AND KIRK FOR SET-VALUED MAPPINGS IN METRIC AND BANACH SPACES

  • Park, Sehie
    • 대한수학회보
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    • 제21권2호
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    • pp.55-60
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    • 1984
  • In [2], D. Downing and W.A. Kirk obtained a number of fixed point theorems for set-valued maps in matric and Banach spaces. The authors considered maps which are more general than the contractions with nonempty and closed mapping values, and obtain results for maps satisfying certain "inwardness" conditions. A key aspect of their approach is the application of a general fixed point theorem due to Caristi [1]. On the other hand, in [6], the present author obtained a number of equivalent formulations of the well-known result of I. Ekeland [3, 4] on the variational principle for approximate solutions of minimization problems. Some of such formulations include sharpened forms of the Caristi theorem. In this paper, using one of such formulations, we show that Theorems 1-3 and Corollaries 1-5 of [2] are substantially improved by giving geometric estimations of fixed points.ed points.

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선 기하를 이용한 가속도 해석과 동역학에의 적용 (Acceleration analysis by using line geometry and its application to dynamics)

  • 홍만복;최용제
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2002년도 추계학술대회 논문집
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    • pp.912-915
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    • 2002
  • It has been known that general velocity and force of a rigid body in space can be described in forms of a twist and a wrench by use of screws. However, the geometrical meaning of acceleration has not been clearly disclosed. It has been a normal practice to analyze or synthesize the acceleration effect of manipulator using some complex mathematical equations, which do not represent any geometrical meanings. In other words, such a technique doesn't clearly provide information about the overall acceleration state of manipulator at that instant. In this study, the geometrical meaning of acceleration of a rigid body has been investigated and thereby a geometrical procedure which can be applied to inverse acceleration analysis of a general non-redundant manipulator is presented as an application.

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An Integrated Database and Web Service for Microbial Resources at KACC

  • Kim, Chang-Kug;Jeon, Young-Ah;Cho, Gyu-Taek;Kwon, Soon-Wo;Kim, Yong-Hwan;Hong, Seung-Beom
    • Genomics & Informatics
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    • 제7권1호
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    • pp.41-45
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    • 2009
  • The Korean Agricultural Culture Collection (KACC) has developed a web-based system to provide an integrated database with information updates about microbial resources. This integrated database consists of 5 major functions and contains general information, which includes identification numbers, culture media composition, image information, DNA sequences, patent information, and general forms for ordering and depositing microorganisms. In 2008, KACC started providing characterization information. KACC maintains 9,801 cultures of microorganisms, including 3,296 strains of bacteria, 4,734 fungi, 784 actinomycetes, 64 yeasts, and 923 others.

Time-dependent analysis of reinforced concrete structures using the layered finite element method

  • Bradford, M.A.;Gilbert, R.I.;Sun, S.C.H.
    • Structural Engineering and Mechanics
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    • 제8권6호
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    • pp.561-578
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    • 1999
  • The response of a reinforced concrete structure to loading is both immediate and time-dependent. Under a sustained load, the deflections caused by creep and shrinkage may be several times their instantaneous values. The paper describes a general finite element procedure, based on the so-called layered model, to analyse reinforced concrete members, and shows in particular how the simple Step by Step Method may be incorporated into this procedure. By invoking the Modified Newton Raphson Method as a solution procedure, the accuracy of the finite element method is verified against independent test results, and then applied to a variety of problems in order to demonstrate its efficacy. The method forms a general method for analysing highly indeterminate concrete structures in the time domain.

Hyperfine Interaction Integrals for NMR Chemical Shifts in 5f Paramagnetic Systems

  • 이기학;이지영;김동희
    • Bulletin of the Korean Chemical Society
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    • 제18권4호
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    • pp.424-427
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    • 1997
  • To study the NMR chemical shift arising from the 5f-electron orbital angular momentum and the 5f-electron spin dipolar-nuclear spin angular momentum interactions, the evaluation of the hyperfine integrals has been extended to any pairs of SCF type 5f orbitals adopting a general method which is applicable to a general vector R, pointing in any direction in space. From the electronic wavefunctions for 5f orbitals expressed in common coordinate system, the radial part of the hyperfine interaction integrals are derived by translating the exponential part, r2 exp(-2βr), in terms of R, rN and the modified Bessel functions. The radial integals for 5f orbitals are tabulated in analytical forms. When two of the hyperfine integrals along the (100), (010), (001), (110), and (111) axes are calculated using the derived radial integrals, the calculated values for the 5f system change sign for R-values larger than R 0.35 nm. But the calculated values for the 4f systems change sign for R-values larger than R 0.20 nm.

Guided wave formation in coal mines and associated effects to buildings

  • Uyar, Guzin G.;Babayigit, Ezel
    • Structural Engineering and Mechanics
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    • 제60권6호
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    • pp.923-937
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    • 2016
  • The common prospect in diminishing mine-blast vibration is decreasing vibration with increasing distance. This paper indicates that, contrary to the general expectancy, vibration waves change their forms when they are travelling through the low velocity layer like coal and so-called guided waves moving the vibration waves to longer distances without decreasing their amplitudes. The reason for this unexpected vibration increase is the formation of guided waves in the coal bed which has low density and low seismic velocity with respect to the neighboring layers. The amplitudes of these guided waves, that are capable of traveling long distances depending on the seam thickness, are several times higher than that of the usual vibration waves. This phenomenon can many complaints from the residential areas very far away from the blasting sites. Thus, this unexpected behavior of the coal beds in the surface coal mines should also be considered in vibration minimization studies. This study developed a model to predict the effects of guided waves on the propagation ways of blast-induced vibrations. Therefore, vibration mitigation studies considering the nearby buildings can be focused on these target places.

버강 시기 불탑의 형식적 특성과 분류 (Formal Characteristics and Classifications of Pagodas in the Period of Bagan)

  • 염승훈;천득염;김소영
    • 건축역사연구
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    • 제25권5호
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    • pp.75-86
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    • 2016
  • This paper examines the pagodas during the Bagan period, which are thought to be most valuable among those in Myanmar. They have not been sufficiently studied, in spite of their high Buddhist status. It considers the contemplation of Pato, their formal characteristics in the Bagan period and the formal categorizations of pagodas in the same period. Thus, following seven kinds of conclusions are derived: first, researchers provide opinions to the Pato which should be regarded as the Buddhist shrine-type of pagoda with a unique Bagan form, symbolically indicating that Theravada Buddhism incorporated Hinduism; second, the terraces were characteristic components in pagodas, during the Bagan period, which were built after the enthronement of King Anawratha and are thought to symbolically express the wish to widely spread Theravada Buddhism; third, Shwesandaw Zedi seems to affect not only Shwezigon Zedi, a representative standard form of pagoda in Myanmar, but also Ananda Pato; fourth, it is thought to be proper to examine the terraces by classifying them into lower, central(from pedestals to Angryeon and Bokryeon) and upper part, if it intends to divide a pagoda with bell-shaped body on the terraces during the Bagan period, into three parts; fifth, the Pato may be identified as a form of pagoda during the Bagan period, and such a form can be classified as that of Sikhara on the rectangular terrace; sixth, forms of Myanmar's pagodas can be classified into fourteen kinds of them, and they may be also grouped into transmitted, general and special type; and seventh, on the basis of the findings, it is thought that the pagodas during the Bagan period may be classified into six forms, and they can be largely categorized into transmitted, general and special type.