• Title/Summary/Keyword: gel materials

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Partial Purification of Mussel Adhesive Protein for Mytilus Edulis and Preparation of Mussel Protein Hydrolysates

  • Sun, Nam-Kyu;Song, Kyung-Bin
    • Preventive Nutrition and Food Science
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    • v.5 no.3
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    • pp.148-152
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    • 2000
  • Mussel adhesive protein (MAP) was extracted from Korean Mytilus edulis and then partially purified using Sephacryl S-300 gel permeation chromatography and reversed-phase high performance liquid chromatography. As an indicator of adhesiveness, is 3,4-dihydroxyphenylalanine (DOPA) content was determined. Its DOPA/protein ratio of 0.19 was higher than those of other reports, indicating a good adhesive. The partially purified MAP was confirmed by acid-urea polyacrylamide gel electrophoresis using cetylpiridinium bromide as a cationic detergent. Sea mussel hydrolysates were prepared using three commercial proteases to provide value-added functional materials and their angiotensin converting enzyme (ACE) inhibitory activities were determined. Among hydrolysates of sea mussel, Protamex was the best and further purification would improved ACE inhibitory activity.

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A Study of Transparent Liquid Crystal Gel with High Oil Content from Fatty Acid Soap (지방산 솝을 이용한 고오일 함유 투명젤 생성에 관한 연구)

  • Lee, Jung-No;Kim, Hyuk-Hwa;Yu, Kang-Yeol
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.4
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    • pp.431-437
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    • 2011
  • Transparent liquid crystal gels with high oil content by fatty acid soap were investigated. The solubilization efficiency of the mineral oil was dependent on the process. The process of dropping water part into the solution of oil and surfactant was more efficient than the process of dropping water part into the surfactant solution and after that dropping oil. The fatty acid soap could not solubilize the high oil content, but under the certain range, addition of CDE (Coconut Diethanolamide), Arlacel 165 (Glyceryl Stearate/PEG-100 Stearate) and cetostearyl alcohol helped solubilize the high content oil. Also, the glycerin and water content had influence on the solubilization. Especially, higher oil content gel showed elastic feature.

Solution-Derived Amorphous Yttrium Gallium Oxide Thin Films for Liquid Crystal Alignment Layers

  • Oh, Byeong-Yun
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.2
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    • pp.109-112
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    • 2016
  • We demonstrated an alternative electrically controlled birefringence liquid crystal (ECB-LC) system with ion beam (IB)-irradiated yttrium gallium oxide (YGaO) alignment films using a sol-gel process. The surface roughness of the films was dependent on the annealing temperature; aggregated particles on surface were observed at lower annealing temperatures, whereas a smooth surface could be obtained with higher annealing temperatures. Higher transmittance in the visible region was observed at higher annealing temperatures. The film had an amorphous crystallographic state irrespective of the annealing temperature. Furthermore, ECB-LC cell with our IB-irradiated YGaO film yielded faster response time when compared to ECB-LC cell with rubbed polyimide. Considering the fast response time and high transmittance, the IB-irradiated YGaO-base LC system is a powerful alternative application for the liquid crystal display industry.

Compound waterproofing method of green roof using copper barrier sheet and recycled tire melting liquid waterproofing material that reinforced treatments are valve and glass fiber mesh. (알루미늄 판막과 유리섬유를 합지한 구리방근시트와 폐타이어 용융액상 도막방수재를 이용한 옥상녹화 복합방수공법)

  • Kim, Young chan;Cho, Il Kyu;choi, sung min;Oh, Sang Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.173-178
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    • 2008
  • This is green roof bottom system which composed by aluminum valve and glass fiber together as major reinforcement, so the cooper sheet can have root proof, and using recycled tire gel-type membrane waterproofing system which dost not contains VOCs. The copper sheet reduce the plants' root growing, so it helpes to maintain the waterproofing layer and stability of root proofing. Gel type membrane waterproofing system can do waterproofing, stress dispersion, and reducing leakage expansion. So those two materials can help each other to make green roof bottom layer would have the stability and durability.

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Fabrication of Discontinuous Al2O3-Dispersed TZP Fibers by a Sol-Gel Method (졸-겔법을 이용한 Al2O3가 분산된 TZP 단섬유의 제조)

  • Sim, Soo-Man
    • Journal of the Korean Ceramic Society
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    • v.52 no.1
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    • pp.56-60
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    • 2015
  • Discontinuous, polycrystalline $Al_2O_3$-dispersed TZP fibers were prepared by the centrifugal spinning of a colloidal $ZrO_2$ sol containing Y and Al nitrates and poly(vinyl alcohol). Factors affecting the rheological properties of the sols, such as sol concentrations, aging, and the amounts and types of additives, were investigated by measuring the shear viscosities. The flow characteristics of the sols were studied in relation to the spinnability by measuring the viscosity with respect to the shear rate. The spinnability was obtained through the addition of a polymer which increases the viscosity to a range of optimum viscosity values for spinning. Aging the sols containing the additives did not noticeably change the sol viscosities at room temperature up to 30 days. The flow behavior of the spinnable sols progressively changed from nearly Newtonian to pseudoplastic with an increase in the sol concentration.

Ion Beam Assisted Crystallization Behavior of Sol-Gel Derived $PbTiO_3$ Thin Films

  • Oh, Young-Jei;Oh, Tae-Sung;Jung, Hyung-Jin
    • The Korean Journal of Ceramics
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    • v.2 no.1
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    • pp.48-53
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    • 1996
  • Ion beam assisted crystallization behavior of sol-gel derived $PbTiO_3$ thin films, deposited on bare silicon(100) substrates by spin-casting method, has been investigated. Ar ion bombardment was directly conducted on the spincoated film surface with or without heating the film from room temperature to $300^{\circ}C$. Ion dose was changed from $5{\times}10^{15}$ to $7.5{\times}10^{16}$ $Ar^-/cm^2$. Formation of (110) oriented perovskite phase was obseerved with ion dose above $5{\times}10^{16}\; Ar^+/cm^2$. Crystallization of $PbTiO_3$ thin film could be enhanced with increasing the Air ion dose, or heating the substrate during ion bombardment. Crystallization of the $PbTiO_3$ films by ion bombardment was related to the local heating effect during ion bombardment.

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A study on the Synthesis and Characterization of Polyimide/TiO2 Nanocomposite (폴리이미드/TiO2 나노복합재의 합성과 물성 연구)

  • Lee, Bong-Shin;Lee, Joong-Hee;Kim, In-Taek;Lee, Myong-Hoon;Nah, Chang-Woon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.12
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    • pp.2624-2630
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    • 2002
  • Organic/inorganic hybrid materials have rapidly become a fascinating research field. In this study, $polyimide/TiO_2$ composites were synthesized from nano-sized anatase $TiO_2$ and two types of polyimide, that is, BPDA-PPD and PMDA-ODA. Nano-sized $TiO_2$ particles were prepared from $TiOEt_4$ solution by the sol-gel method. The synthesized PI/$TiO_2$ composites were characterized by using XRD, TGA, FT-IR, TEM, and Atomic Force Microscope(AFM). $TiO_2$ particles were dispersed well in polyimides and the mechanical and thermal stability of polyimide was improved with $TiO_2$ nano particles.

Synthesis and Electrochemical Characteristics of Li0.7[Ni0.05Mn0.95]O2 as a Positive Material for Rechargeable Lithium Batteries

  • Shin, Sun-Sik;Kim, Dong-Won;Sun, Yang-Kook
    • Bulletin of the Korean Chemical Society
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    • v.23 no.5
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    • pp.679-682
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    • 2002
  • Layered Na0.7[Ni0.05Mn0.95]O2 compounds have been synthesized by a sol-gel method, using glycolic acid as a chelating agent. Na0.7[Ni0.05Mn0.95]O2 precursors w ere used to prepare layered lithium manganese oxides by ion exchange for Na by Li, using LiBr in hexanol. Powder X-ray diffraction shows the layered Na0.7[Ni0.05Mn0.95]O2 has an O3 type structure, which exhibits a large reversible capacity of approximately 190 mA h g-1 in the 2.4-4.5 V range. Na0.7[Ni0.05Mn0.95]O2 powders undergo transformation to spinel during cycling.

Magnetic Abrasive Polishing and Its Application (초정밀 자기연마 가공 기술과 최근 연구)

  • Kwak, Tae-Soo;Kwak, Jae-Seob
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.3
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    • pp.266-272
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    • 2012
  • This paper has aims to share fundamental knowledge for magnetic abrasive polishing and to mainly introduce recent research results. In order to enhance a magnetic flux density for nonferrous materials, advanced magnetic abrasive polishing system which is called 2nd generation system was established by electro-magnet array table, and the effectiveness of the electromagnet array table was evaluated in real polishing experiments. To increase adhesiveness of the abrasives in high speed polishing, a silicone gel agent was proposed and carbon nanotube particles as new magnetic abrasives were applied in the magnetic abrasive polishing. In addition, a strategy for optimal step-over determination by heuristic algorithm was introduced for applying large size workpiece. Curved surfaces having a uniform radius were simulated and tested with installed electro-magnet array table.

Development and Characteristics of a New Insulator between Turns of Superconducting Coil (초전도 Coil의 새로운 turn간 절연재료의 개발 및 특성)

  • 박영욱;이동성;이정원;곽동순;김상현
    • Progress in Superconductivity and Cryogenics
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    • v.4 no.1
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    • pp.26-29
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    • 2002
  • Polyimide-epoxysilane (coupling agent) composites were reacted with oligomeric PDMS, a condensation product of difunctional silane, by a sol-gel process and were then dried into films. And then, the surface, mechanical, and electric properties were measured. The study showed that PDMS existed in the polymide matrix by the use of FT-IR. In the mechanical properties, the maximum elongation and toughness was increased in the polyimide with silane-groups. But the maximum tensile strength was slightly decreased. And the intensive dispersion of the silane-groups on the surface of polyimide was ascertained through XPS measurement. In the electric properties. AC break down voltage was increased by increasing the amount of difunctional silane. This experiment showed that PDMS added polyimide had better mechanical and electric properties than classical materials.