• Geomechanics and Engineering
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• 제13권2호
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• pp.285-300
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• 2017

Shallow coal resources are increasingly depleted, the mining has entered the deep stage. Due to "High stress, high gas, strong adsorption and low permeability" of coal seam, the gas drainage has become more difficult and the probability of coal and gas outburst accident increases. Based on the flow solid coupling theory of coal seam gas, the coupling model about stress and gas seepage of coal seam was set up by solid module and Darcy module in Comsol Multiphysics. The gas extraction effects were researched after applying hydraulic technology to increase permeability. The results showed that the effective influence radius increases with the expanded borehole radius and drainage time, decreases with initial gas pressure. The relationship between the effective influence radius and various factors presents in the form: $y=a+{\frac{b}{\left(1+{(\frac{x}{x_0})^p}\right)}}$. The effective influence radius with multiple boreholes is obviously larger than that of the single hole. According to the actual coal seam and gas geological conditions, appropriate layout way was selected to achieve the best effect. The field application results are consistent with the simulation results. It is found that the horizontal stress plays a very important role in coal seam drainage effect. The stress distribution change around the drilling hole will lead to the changes in porosity of coal seam, further resulting in permeability evolution and finally gas pressure distribution varies.

• Archives of Pharmacal Research
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• 제27권1호
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• pp.25-30
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• 2004

Combinatorial homoserine lactone mixtures and individual products were obtained from the methionine-functionalized resin in solid-phase synthesis. The four-step process consisting of a coupling step of an N-Fmoc-L-methionine, deprotection of N-Fmoc group, N-coupling with a carboxylic acid, and cleavage reaction through a polymer supported strategy is described. Gas chromatography-mass selective detector (GC-MSD) techniques provide the most powerful methods for identifying both the combinatorial mixtures and individual products.

• Geomechanics and Engineering
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• 제22권3호
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• pp.255-264
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• 2020

With the ongoing development of deep mining of coal resources, some coal mine dynamic disasters have exhibited characteristics of both coal-gas outbursts and rockbursts. Therefore, research is required on the mechanism of rockburst-outburst coupling disaster. In this study, the failure characteristics of coal-rock combination structures were investigated using lab-scale physical simulation experiments. The energy criterion of the rockburst-outburst coupling disaster was obtained, and the mechanism of the disaster induced by the gas-solid coupling instability of the coal-rock combination structure was determined. The experimental results indicate that the damage of the coal-rock structure is significantly different from that of a coal body. The influence of the coal-rock structure should be considered in the study of rockburst-outburst coupling disaster. The deformation degree of the roof is controlled by the more significant main role of the gas pressure and the difference in the strength between the rock body and the coal body. The outburst holes and spall characteristics of the coal body after the failure of the coal-rock structure are strongly affected by the difference in strength between the roof and the coal body. The research results provide an in-depth understanding of the mechanism of rockburst-outburst coupling disasters in deep mining.

• Geomechanics and Engineering
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• 제15권1호
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• pp.677-686
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• 2018

Aimed at serious casing damage problem during the process of oilfield development by injecting water, based on seepage mechanics, fluid mechanics and the theory of rock mechanics, the multi-physics coupling theory was also taken into account, the mathematical model for production of petroleum with water flooding was established, and the method to solve the coupling model was presented by combination of Abaqus and Eclipse software. The Q9G3 block in Jibei oilfield was taken for instance, the well log data and geological survey data were employed to build the numerical model of Q9G3 block, the method established above was applied to simulate the evolution of seepage and stress. The production data was imported into the model to conduct the history match work of the model, and the fitting accuracy of the model was quite good. The main mechanism of casing damage of the block was analyzed, and some wells with probable casing damage problem were pointed out, the displacement of the well wall matched very well with testing data of the filed. Finally, according to the simulation results, some useful measures for preventing casing damage in Jibei oilfield was proposed.

• 한국안전학회지
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• 제9권1호
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• pp.146-154
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• 1994

A series of numerical calculations are performed in order to investigate the dispersion mechanism of toxic gaseous and solid pollutants in extremely short-term and short range. The calculations are carried out in an open space characterized by turbulent boundary layer. The simulation is made by the use of numerical model, in which a control-volume based finite difference method is used together with the SIMPLEC algorithm for the resolution of the pressure-velocity coupling problem. The Reynolds stresses are solved by two-equation, k-$\varepsilon$ model modified for buoyancy. The major parameters consider-ed in this study are temperature, velocity and Injection height of toxic gases, environmental conditions such as temperature and velocity of free stream air, and topographic factor. The results are presented and discussed in detail. The flow field is commonly characterized by the formation of a strong recirculation zone due to the upward motion of the hot toxic gas and ground shear stress. The driving force of the upward motion is explained by the effect of thermal buoyancy of hot gas and the difference of inlet velocity between toxic gas and free stream.

• 대한기계학회논문집
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• 제16권11호
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• pp.2169-2180
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• 1992

본 연구에서는 비정상적인 효과가 매우 클 경우에 추진제가 고체-용융층-기체 의 상변화를 거쳐 변환된 기체가 화학반응을 할 때, Vieille의 관계식이 얼마나 수정 되어야 하는가를 검토한다. 그러나, 연소실내의 파의 전파까지 고려하면 문제가 너 무 커지므로, 시간의 함수로 주어진 압력에 대하여 기체의 생성등이 어떻게 응답하는 가 만이 연구되었다.

• 한국안전학회지
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• 제10권3호
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• pp.68-80
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• 1995

A series of parametric calculations have been performed in order to investigate the short-term and short-range plume and puff behavior of toxic gaseous and solid pollutant dispersion in an open atmosphere. The simulation is made by the use of the computer program developed by this laboratory, in which a control-volume based finite-difference method is used together with the SIMPLEC algorithm for the resolution of the pressure-velocity coupling appeared In Wavier-Stokes equation. The Reynolds stresses are solved by the standard two-equation k-$\varepsilon$ model modified for buoyancy together with the RNG(Renormalization Group) k-$\varepsilon$ model. The major parameters considered in this calculation are pollutant gas density and temperature, the relative velocity of pollutants to that of the surrounding atmospheric air, and particulate size and density together with the height released. The flow field is typically characterized by the formation of a strong recirculation region for the case of the low density gases such as $CH_4$ and air due to the strong buoyancy, while the flow is simply declining pattern toward the downstream ground for the case of heavy molecule like the $CH_2C1_2$and $CCl_4$, even for the high temperature, $200^{\circ}C$. The effect of gas temperature and velocity on the flow field together with the particle trajectory are presented and discussed in detail. In general, the results are physically acceptable and consistent.

• Geomechanics and Engineering
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• 제10권3호
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• pp.297-314
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• 2016

With the mining depth continuously increasing, gas emission behaviors become more and more complex. Gas emission is an important basis for choosing the method of gas drainage, gas controlling. Thus, the accurate prediction of gas emission is of great significance for coal mine. In this work, based on the sources of gas emission from the heading faces and the fluid-solid coupling process, we established a gas continuous dynamic emission model, numerically simulated and applied it to the engineering. The result was roughly consistent with the actual situation and shows the model is correct. We proposed the measures of reducing the excavation distance and borehole gas drainage based on the model. The measures were applied and the result shows the overproof problem of gas emission disappears. The model considered the influence factors of gas emission wholly, and has a wide applicability, promotional value. The research is of great significance for the controlling of gas disaster, gas drainage and pre-warning coal and gas outbursts based on gas emission anomaly at the heading face.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2010년 춘계학술대회논문집
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• pp.548-550
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• 2010

The droplet motion on a flat substrate with contact angle hysteresis is studied by solving the equations governing the conservation of mass and momentum. The liquid- gas interface is determined by an level-set method which is based on a sharp-interface representation for accurately imposing the matching or coupling conditions at the interface. The method is modified to treat the dynamic contact angle at the liquid-gas-solid interface. The computations are performed to investigate a droplet impact and merging pattern on a flat substrate to find a optimal condition in a micro-line patterning process. The effects of dynamic contact angles on droplet motion are quantified.

• 멤브레인
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• 제23권2호
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• pp.136-143
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• 2013

최근 큰 각광을 받고 있는 표면개질소재 중 하나인 도파민은 알칼리 수용액상에서 자발적으로 반응이 진행되어 금속, 고분자 등 거의 모든 소재에 강하게 흡착되는 물질로 흡착 메커니즘 및 반응 후 최종구조에 관해 많은 논란이 있다. 기존의 도파민의 최종구조는 aryl-aryl 결합에 의한 고분자 구조가 제안되었지만, 본 연구에서는 구조분석을 통해 기존에 제안된 aryl-aryl 결합이 형성되지 않는 결과와 열적거동을 통해 고분자의 특징이 나타나지 않는 것을 확인하였으며, 기체투과거동을 통해 고분자와 같이 비다공성 코팅층을 형성하지 못하는 결과를 토대로, 도파민의 최종구조는 2차 결합에 의한 초분자 구조로 서로 응집되어 있는 것으로 판단된다.