• Title/Summary/Keyword: gas volume

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Nanostructural Features of nc-Si : H Thin Films Prepared by PECVD (PECVD 기법에 의해 제조된 nc-Si : H 박막의 나노 구조적 특성)

  • 심재현;정수진;조남희
    • Korean Journal of Crystallography
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    • v.14 no.2
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    • pp.56-61
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    • 2003
  • Nanocrystalline hydrogenated silicon (nc-Si : H) thin films were deposited at room temperature by plasma enhanced chemical vapor deposition (PECVD): a mixture of SiH₄ and H₂ gas was introduced into the evacuated reaction chamber. When the H₂ gas flow rate was low, the density of Si-H₃ bonds was high in the films. On the other hand, when the H₂ gas flow rate was high, e.g., 100 sccm, a large number of Si-H bonds contributed to the passivation of the surface of the large volume of Si nanocrystallites. The relative fraction of the Si-H₃ and Si-H₂ bonds in the amorphous matrix varied sensitively with the H₂ gas flow rate. The variation was associated with the change in the intensity as well as the wavelength of the main PL peaks, indicating the change in the total volume as well as the size of the Si nanocrystallites in the films.

The pressure drop characteristics in LNG heat exchanger of cryogenic cascade refrigeration cycle (초저온 캐스케이드 냉동사이클의 LNG 열교환기 압력강하 특성)

  • Yoon, J.I.;Choi, K.H.;Kwag, J.W.;Son, C.H.;Baek, S.M.
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.376-381
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    • 2012
  • Natural gas is converted in to LNG by chilling and liquefying the gas to the temperature of $-162^{\circ}C$, when liquefied, the volume of natural gas is reduced to 1/600th of its standard volume. This gives LNG the advantage in transportation. The pressure dorp of the cascade liquefaction cycle was investigated and simulated using HYSYS software. The simulation results showed that the pressure drop in the LNG heat exchanger is set to 50 kPa considering the increase in the compressor work of cryogenic cascade liquefaction cycle.

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A study on the electrical characteristics of the fluorocarbon (Fluorocarbon의 전기적 특성연구)

  • 허창수;조한구
    • Electrical & Electronic Materials
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    • v.8 no.2
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    • pp.217-223
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    • 1995
  • In this paper, we investigated physical properties and electrical characteristics of the fluorocarbon that used as coolants for large power gas-insulated transformer. Volume resistivity of the fluorocarbon was .rho.=1.87*10$^{15}$ [.ohm.cm] at 1 atm, 27.deg. C. Dielectric constant was 1.86 and decreases as temperature increase. The breakdown voltage at 1 atm was higher than that of transformer oil. The breakdown voltage of fluorocarbon vapor was about 18kV when pressure in a test chamber increases over lkg/cm$^{2}$. When fluorocarbon was mixed with SF$_{6}$ gas, breakdown voltage of the mixed was higher than that of fluorocarbon. Then fluorocarbon leads to increase over 4kg/cm$^{2}$ in pressure as temperature increase. Therefore, when a gas-insulated transformer is manufactured, the design must be taken into consideration a high-pressure.

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A Study on Bubbles Flow in the Gas-injected Cylindrical Bath (기체가 주입된 원통형 용기내에서 기포유동에 관한 연구)

  • Seo Dong-Pyo;Park Keun-Uk;Oh Yool-Kwon
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.393-396
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    • 2002
  • Submerged gas-injected system can be applied to various industrial field such as metallurgical and chemical processes, So this study aims at presenting the relevant relationship between gas phase and liquid phase in a gas-injected bath. In a cylinderical bath, local gas volume fraction and bubble frequency were measured by electroconductivity probe and oscilloscope. The temperature of each phase was measured using thermocouple and data acquisition system. In vertical gas injection system, gas-liquid two phase plume was formed, being symmetry to the axial direction of injection nozzle and in a shape of con. Lacal gas-liquid flow becomes irregular around the injection nozzle due to kinetic energy of gas and the flow variables show radical change at the vicinity of gas(air) injection nozzle As most of the kinetic energy of gas was transferred to liquid in this region, liquid started to circulate. In this reason, this region was defined as 'developing flow region' The Bubble was taking a form of churn flow at the vicinity of nozzle. Sometimes smaller bubbles formed by the collapse of bubbles were observed. The gas injected into liquid bath lost its kinetic energy and then was governed by the effect of buoyancy. In this region the bubbles which lost their kinetic energy move upward with relatively uniform velocity and separate. Near the gas nozzle, gas concentration was the highest. But it started to decrease as the axial distance increased, showing a Gaussian distribution.

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Combustion Characteristics of Landfill Gas in Constant Volume Combustion Chamber for Large Displacement Volume Engine (III) - Torch Ignition (1) - (대형기관 모사 정적연소실에서 매립지 가스의 연소특성에 대한 연구 (III) - 토치 점화 (1) -)

  • Kim, Inok;Ohm, Inyong;Kwon, Soon Tae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.2
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    • pp.125-134
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    • 2015
  • This is the third paper on the combustion characteristics of the landfill gas in a constant volume combustion chamber for a large displacement volume commercial engine. It is the first in this series to discuss the effects of the torch device on combustion. The results show that an optimum orifice ratio exists regardless of the torch volume, and a few adverse effects on the combustion are observed for an excessively small orifice ratio. In addition, the torch ignition decreases the initial burn duration, and the decrease in the heat transfer caused by this decreased duration contributes to an increase in the peak combustion pressure. Finally, the torch mostly plays a positive role in shortening the main burn duration when the combustion condition is worsened by a lower methane fraction. Yet, the torch decreases the initial burn duration rather than the main burn as the methane fraction increases.

Prediction of Explosion Risk for Natural Gas Facilities using Computational Fluid Dynamics (CFD) (전산유체역학시뮬레이션을 이용한 도시가스 설비의 폭발위험성 예측)

  • Han, Sangil;Lee, Dongwook;Hwang, Kyu-Suk
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.606-611
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    • 2018
  • City natural gas is classified flammable hazardous gas and should be secured according to explosion risk assessment determined by Industrial Standard KS C IEC. In this study, leak size, ventilation grade and effectiveness were adopted to the KS C IEC for risk assessment in natural gas supply system. To evaluate the applicability of the computational fluid dynamics (CFD), the risk assessment was studied for four different conditions using hypothetical volume($V_z$) valuesfrom gas leak experiments, KS C IEC calculation, and CFD simulation.

A Study on the Auto-ignition Combustion Characteristics of CH4-Air Pre-mixtures in Constant Volume Combustion Chamber (정적연소기를 이용한 메탄-공기 예혼합기의 자발화 연소특성에 관한 연구)

  • Lee, Jin-Soo;Lee, Hae-Chul;Cha, Kyung-Ok;Jung, Dong-Soo
    • Journal of ILASS-Korea
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    • v.10 no.2
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    • pp.41-47
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    • 2005
  • Exhaust gas emissions from internal combustion engines are one of the major sources of air pollution. And. it is extremely difficult to increase gasoline engine efficiency and to reduce NOx and PM(particulate matter) simultaneously in diesel combustion. This paper offers some basic concepts to overcome the above problems. To solve the problems, a recommended technique is CAI(controlled auto-ignition) combustion. In this paper. internal EGR(exhaust gas recirculation) effect is suggested to realize CAI combustion. An experimental study was carried out to achieve CAI combustion using homogeneous premixed gas mixture in the constant volume combustion chamber(CVCC). A flame trap was used to simulate internal EGR effect and to increase flame propagation speed in the CVCC. Flame propagation photos and pressure signals were acquired to verify internal EGR effect. Flame trap creates high speed burned gas jet. It achieves higher flame propagation speed due to the effect of geometry and burned gas jet.

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Study of Counter Diffusion in Isostatic Permeameters

  • Bianchi, F.;Pegoraro, M.;Zanderighi, L.
    • Korean Membrane Journal
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    • v.3 no.1
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    • pp.39-50
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    • 2001
  • The counter-diffusion of two gaseous substances permeating a polymeric membrane has been investigated both experimentally and theoretically. The aim of the study was to find mutual effects, if any, that could influence the permeability and diffusivity data. The experimental data were obtained with an isostatic permeameter operating at ambient pressure and 303 K: helium, nitrogen, carbon dioxide methane were used as permeating gas at different partial pressure; helium or nitrogen as equilibrating or carrier gas. No evident mutual effect of the counter-diffusing gas was observed. The theoretical analysis gave some insight into the phenomena and it was concluded that at near-atmospheric pressures, and in the absence of swelling phenomena no mutual interaction exists. On a theoretical basis any mutual interaction between diffusing and counter-diffusing gases could only occur: i) at high pressures , when the free movement of permeating gas molecules within the polymer is hindered by the counter-diffusing gas; ii) when a large part of the free volume fraction is occupied by the counter--diffusing gas; iii) swelling phenomena modify the structure and free volume fraction of the polymer.

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A Study on Stratification Phenomena of Still Hydrogen-Methane Gas Mixture in a Vertical Urban Gas Pipe (도시가스 수직 배관 내 정지된 수소-메탄 혼합가스의 성층화 현상 연구)

  • Tae Kyun Kim;Jung Min Cho;Jaeyong Sung
    • Journal of the Korean Society of Visualization
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    • v.22 no.1
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    • pp.68-78
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    • 2024
  • The stratification phenomena of still hydrogen (20%) and methane (80%) gas mixture in a vertical urban gas pipe have been investigated by simulating the flows based on a mixture model. The stratification is accompanied with the natural convection by the buoyancy force. The hydrogen volume fraction in the upper sections of the pipe increases with time but the increasing rate gets smaller due to the weaker buoyancy force. The pipe with a smaller diameter exhibits a higher peak of hydrogen concentration. The size of vortices is proportional to the pipe diameter. The slip velocity between hydrogen and methane oscillates with a large amplitude at the earlier stage of stratification and then the amplitude decreases sharply. The slip velocity decreases with the diameter, making the stratification become slower. The length of pipe does not affect the stratification since the pipe is sufficiently long relative to the size of vortices.

An Experimental Study of Silica Particle Growth in a Coflow Diffusion Flame Utilizing Light Scattering and Local Sampling Technique (II) - Effects of Diffusion - (광산란과 입자포집을 이용한 동축류 확산화염 내의 실리카 입자의 성장 측정(II) - 확산의 영향 -)

  • Cho, Jaegeol;Lee, Jeonghoon;Kim, Hyun Woo;Choi, Mansoo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.9
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    • pp.1151-1162
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    • 1999
  • The effects of radial heat and $H_2O$ diffusion on the evolution of silica particles in coflow diffusion flames have been studied experimentally. The evolution of silica aggregate particles in coflow diffusion flames has been measured experimentally using light scattering and thermophoretic sampling techniques. The measurements of scattering cross section from $90^{\circ}$ light scattering have been utilized to calculate the aggregate number density and volume fraction using with combination of measuring the particle size and morphology through the localized sampling and a TEM image analysis. Aggregate or particle number densities and volume fractions were calculated using Rayleigh-Debye-Gans and Mie theory for fractal aggregates and spherical particles, respectively. Flame temperatures and volumetric differential scattering cross sections have been measured for different flame conditions such as inert gas species, $H_2$ flow rates, and burner injection configurations to examine the relation between the formation of particles and radial $H_2O$ diffusion. The comparisons of oxidation and flame hydrolysis have also been made for various $H_2$ flow rates using $N_2$ or $O_2$ as a carrier gas. Results indicate that the role of oxidation becomes dominant as both carrier gas($O_2$) and $H_2$ flow rates increases since the radial heat diffusion precedes $H_2O$ diffusion in coflow flames used in this study. The effect of carrier gas flow rates on the evolution of silica particles have also been studied. When using $N_2$ as a carrier gas, the particle volume fraction has a maximum at a certain carrier gas flow rate and as the flow rate is further increased, the hydrolysis reaction Is delayed and the spherical particles finally evolves into fractal aggregates due to decreased flame temperature and residence time.