• Membrane Journal
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• v.24 no.5
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• pp.341-349
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• 2014

Molecular dynamics (MD) computer simulation is a very useful tool to calculate the trajectory and velocity of particles (generally, atoms), and thus to analyze the various structures and kinetic properties of atoms and molecules. For gas separation membranes, MD has been widely used for structure analysis of polymers such as free volume analysis and conformation search, and for the study of gas transport behavior such as permeability and diffusivity. In this paper, general methodology how to apply MD on gas separation membranes will be described and various related researches will be introduced.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.731-734
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• 2009

KIER has been developed a compact and highly efficient fuel processor which is one of the key component of the residential PEM fuel cells system. The fuel processor uses methane steam reforming to convert natural gas to a mixture of water, hydrogen, carbon dioxide, carbon monoxide and unreacted methane. Then carbon monoxide is converted to carbon dioxide in water-gas-shift reactor and preferential oxidation reactor. A start-up time of the fuel processor is about 1h and CO concentration among the final product is maintained less than 5 vol. ppm. To achieve high thermal efficiency of 80% on a LHV basis, an optimal thermal network was designed. Internal heat exchange of the fuel processor is so efficient that the temperature of the reformed gas and the flue gas at the exit of the fuel processor remains less than $100^{\circ}C$. A compact design considering a mixing and distribution of the feed was applied to reduce the reactor volume. The current volume of the fuel processor is 17L with insulation.

• Journal of Hydrogen and New Energy
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• v.23 no.5
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• pp.545-550
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• 2012

This work is for the design study of natural gas reformer (40 $m^3/hr$ over). We used experimental kinetic data from literature. After that, we set up theoretical model based on experimental reaction kinetic data. The shape of reactor is 1.7 m long and 200 mm dia. with cylinder geometry. Volume of reactor is 53.4 liter. Average flow velocity of gases in the reactor has been determined 0.272 m/sec and residence time is 9.26 sec. Reaction temperature is $850^{\circ}C$, with pressure 9.3 Bar. Used natural gas volume is about 9.21 $m^3/hr$. Produced hydrogen is 43.7 $m^3/hr$ with no change of pressure. Unreacted natural gas is 0.09 $m^3/hr$ and the amount of steam is 26.9 $m^3/hr$. Steam to $CH_4$ (s/c ratio) is 2.91. Reforming reaction take place from the reactor entrance to 120 cm region of cylinder type reactor. After the entrance of reacting gases to 120 cm region, the reaction reaches equilibrium which is close to products. This study can be applicable to design various reactors. Output data is in good agreements with the data in literatures1).

• Journal of Mechanical Science and Technology
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• v.18 no.4
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• pp.699-708
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• 2004

Natural gas hydrate typically contains 85 wt.% water and 15 wt.% natural gas, and commonly belongs to cubic structure I and II. When referred to standard conditions, 1 ㎤ solid hydrate contains up to 200㎥ of natural gas depending on pressure and temperature. Such the large volume of natural gas hydrate can be utilized to store and transport a large quantity of natural gas in a stable condition. In the present investigation, experiments were carried out for the formation of natural gas hydrate governed by pressure, temperature, gas compositions, etc. The results show that the equilibrium pressure of structure II is approximately 65% lower and the solubility is approximately 3 times higher than structure I. It is also found that for the sub-cooling of structure I and II of more than 9 and 11 K respectively, the hydrates are rapidly being formed. It is noted that utilizing nozzles for spraying water in the form of droplets into the natural gas dramatically reduces the hydrate formation time and increases its solubility at the same time.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.3
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• pp.10-18
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• 2004

It is well known that the stratified charge combustion has many kind of advantages to combustion characteristics, such as higher thermal efficiency and less CO, NOx levels than conventional homogeneous mixture combustion. Although this combustion can be caused low fuel consumption, it is produced the high unburned hydrocarbon and soot levels because of different equivalence ratio in the combustion chamber. Moreover it has a lot of possibility of low output and misfire if the mixture gas would not be in existence around the spark plug. In this paper, fundamental studies for stratified combustion were carried out using a constant volume combustion chamber. The effect of locally mixture gas distribution according to control the direct injection and premixed injection in the chamber were examined experimentally. In addition, the effects of turbulence on stratified charge combustion process were observed by schlieren photography.

• Journal of the Korean Society of Combustion
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• v.13 no.3
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• pp.9-16
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• 2008

In this study, a cylindrical constant volume combustion chamber is used to investigate the flow and combustion characteristics of methane-air homogeneous mixture under various initial charge pressure, excess air ratios and ignition times. The flame and burning speed, mean gas speed are calculated by numerical analysis to analyze the combustion characteristics. It is found that the mean gas velocity during combustion has the maximum value around 300 ms and then decreased gradually on the condition of 10000 ms, and that the combustion duration is shorten and flame speed and burning velocity have the highest value under the conditions of an excess air ratio 1.1, an initial charge pressure of 0.2 MPa and an ignition time of 300 ms in the present study. And, the initial pressure and burning speed are in inverse proportion, so that it is in agreement with Strehlow who presented that the initial pressure and burning speed are in inverse proportion when the burning speed is under 50cm/s.

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.3
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• pp.156-167
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• 1996

The present work is a continuation of our previous study to investigate the effects of parameters such as equivalence ratio, hydrogen supplement rate and initial pressure on combustion characteristics in a disk-shaped constant volume combustion chamber. The main results obtained from the study can be summarized as follows. The flames in near stoichiometric mixture of methane-air are propagated with a spherical shape, but in excess rich or lean mixtures are propagated with a elliptical shape. And, they are changed to an unstable elliptical shape flame with very regular cells by increasing the hydrogen supplement rate. Also, flame is sluggishly propagated at increased initial pressure in combustion chamber. Volume fraction of burned gas and flame radius as the combustion characteristics are increased by increasing the hydrogen supplement rate, especially at the combustion middle period, but then are slowly increased by increasing the initial pressure.

• Proceedings of the SAREK Conference
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• 2006.06a
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• pp.417-422
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• 2006

On trends of 'well-being', heat recovery ventilators(HRV) are recently installed in high rise buildings. HRV is not energy saving instrument but ventilating one. But many people have not been aware of the accurate fact. In this study, performances of HRV are tested under foreign and domestic standards. Especially air-tightness is measured three times by using gas concentration method and pressing equipment. Wet effective ventilating air volume is acquired by solving gas concentration equations. After research air-tightness and effective ventilating air volume must be more focused on than heat transfer efficiency to select the optimal HRV. Heat transfer efficiency must be adjusted by air-tightness results.

• The Research Journal of the Costume Culture
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• v.8 no.5
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• pp.660-667
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• 2000

Clothing ventilation was investigated using a manikin wearing an impermeable overall under an isothermal condition, in which the ventilation occurred only through the openings. The ventilation volume was estimated by both microenvironment volume and ventilation rate, where, the microenvironment volume was measured by an air subsitution method and the ventilation rate by a trace gas method. Microenvironment volume of the experimental garment was about 21.0 liters. Even though it was certainly affected by the distance from the opening, the ventilation rate was more significantly influenced by the opening area and the shape of air layer in the clothing. The volume of air exchange in the clothing microenvironment was affected greatly by the microenvironment volume and the opening area, and it was different for each part of the body with bigger air exchange volume in the microenvironment of the leg as compared to that of the arm.

• Journal of Hydrogen and New Energy
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• v.34 no.3
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• pp.283-291
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• 2023

The physical properties were analyzed for four gas diffusion layers, and gas diffusion electrodes (GDEs) for the cathode of high-temperature polymer electrolyte membrane fuel cell were fabricated through bar coating with three binder to carbon (B/C) ratios. Among them, The GDE from JNT30-A6P showed a significant change in secondary pore volume at a B/C ratio of 0.31, which had the largest pore volume among all GDEs. In the polarization curve, JNT30-A6P GDE showed the best membrane electrode assembly (MEA) performance with a peak power density of 384 mW/cm² at a a B/C ratio of 0.31. From the distribution of relaxation time analysis, the peak 1 corresponding to mass transfer resistance of oxygen reduction reaction (ORR) was significantly reduced in the JNT30-A6P GDE. This is the result that when the binder content decreased, the volume of the secondary pore increased, and the mass transfer resistance of ORR decreased, which played an essential role in the MEA performance.