• Title/Summary/Keyword: gas reduction

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Corrosion Behavior of Stainless Steel 316 for Carbon Anode Oxide Reduction Application

  • Jeon, Min Ku;Kim, Sung-Wook;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.2
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    • pp.169-177
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    • 2020
  • Here, the stability of stainless steel 316 (SS-316) was investigated to identify its applicability in the oxide reduction process, as a component in related equipment, to produce a complicated gas mixture composed of O2 and Cl2 under an argon (Ar) atmosphere. The effects of the mixed gas composition were investigated at flow rates of 30 mL/min O2, 20 mL/min O2 + 10 mL/min Cl2, 10 mL/min O2 + 20 mL/min Cl2, and 30 mL/min Cl2, each at 600℃, during a constant argon flow rate of 170 mL/min. It was found that the corrosion of SS-316 by the chlorine gas was suppressed by the presence of oxygen, while the reaction proceeded linearly with the reaction time regardless of gas composition. Surface observation results revealed an uneven surface with circular pits in the samples that were fed mixed gases. Thermodynamic calculations proposed the combination of Fe and Ni chlorination reactions as an explanation for this pit formation phenomenon. An exponential increase in the corrosion rate was observed with an increase in the reaction temperature in a range of 300 ~ 600℃ under a flow of 30 mL/min Cl2 + 170 mL/min Ar.

A Study on Treatment Characteristics of the Phenol and Catechol using on Anaerobic Fluidized Bed Reactor (혐기성 유동층 반응기를 이용한 페놀과 카테콜의 처리특성에 관한 연구)

  • 김민수;박동일;홍종순;장인용
    • Journal of Environmental Health Sciences
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    • v.24 no.1
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    • pp.1-8
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    • 1998
  • This study was carried to investigate the treatment characteristics of the phenol and catechol with an anaerobic fluidized bed reactor(AFBR) having a dimension of 9 cm i.d. and 1.25 m height. The reactor was operated at $35\pm 1\circ$C. The COD concentration of the effluent, the gas production rate and the composition of gas were measured to determine the performance of the AFBR as the hydraulic retention time(HRT) was decreased from 2 days to i day at 600 mg/l of the phenol and catechol concentration. Stable treatment of the phenol wastewater could be achieved with the AFBR at 18 days but the catechol wastewater couldn't be. At HRT 2 days, the phenol wastewater showed the COD reduction efficiency of 93% and the gas production of 2.7 l/day and the catechol wastewater was obtained the COD reduction efficiency of 82% and the gas production of 0.72 l/day. Also at HRT 1 day the phenol and catechol wastewater showed the COD reduction efficiency of 95% and 73% and the gas production of 4.0 l/day and 1.25 l/day, respectively.

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Development of New GAIM Process for Faster Cooling and Material Reduction (빠른 냉각과 재료절감을 위한 새로운 가스성형 프로세스 개발)

  • 한성렬;박태원;곽진관;김철주;하만영;정영득
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.852-855
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    • 2003
  • Gas-Assisted Injection Molding(GAIM) process, that can be used to provide a hollow shape in a molding, is a variant of the conventional injection molding process. GAIM has many advantages such as reduction of material, sink mark. warpage. and lower injection pressure. Thus, GAIM has been widely applied in the industry to make moldings with a hollow channel such as handles, TV frames and so on. On the other hand, GAIM has some disadvantages such as slow cooling time and flow marks. In the disadvantages, hot gas core causes slow cooling of a molding and the overflow. which is to prevent flow mark. is waste of materials. To solve these problems, we developed a new GAIM system that we called RGIM(Reverse Gas Injection Molding). The RGIM has two special units; one is the overflow buffer, which is used for reduction of a material, and the other tile air unit, which is used for faster cooling of a molding. We conducted an experiment and simulation to verify the efficiency of the RGIM system. Through experiments and simulation, we confirmed the effectively operating of the RGIM system and extracted the optimum process conditions.

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A techno-economic analysis of partial repowering of a 210 MW coal fired power plant

  • Samanta, Samiran;Ghosh, Sudip
    • Advances in Energy Research
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    • v.3 no.3
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    • pp.167-179
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    • 2015
  • This paper presents a techno-economic analysis of a partial repowering scheme for an existing 210 MW coal fired power plant by integrating a gas turbine and by employing waste heat recovery. In this repowering scheme, one of the four operating coal mills is taken out and a new natural gas fired gas turbine (GT) block is considered to be integrated, whose exhaust is fed to the furnace of the existing boiler. Feedwater heating is proposed through the utilization of waste heat of the boiler exhaust gas. From the thermodynamic analysis it is seen that the proposed repowering scheme helps to increase the plant capacity by about 28% and the overall efficiency by 27%. It also results in 21% reduction in the plant heat rate and 29% reduction in the specific $CO_2$ emissions. The economic analysis reveals that the partial repowering scheme is cost effective resulting in a reduction of the unit cost of electricity (UCOE) by 8.4%. The economic analysis further shows that the UCOE of the repowered plant is lower than that of a new green-field power plant of similar capacity.

Effects of Temperature, Pressure, Gas Velocity, and Capacity on Reduction Characteristics of Mass Produced Particle in a 0.5 MWth Chemical Looping Combustion System (0.5 MWth 급 케미컬루핑 연소시스템에서 대량생산 산소전달입자의 환원반응 특성에 미치는 온도, 압력, 유속 및 용량의 영향)

  • RYU, HO-JUNG;LEE, DOYEON;NAM, HYUNGSEOK;HWANG, BYUNG WOOK;KIM, HANA;WON, YOOSEOB;BAEK, JEOM-IN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.1
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    • pp.53-62
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    • 2021
  • Batch type reduction-oxidation tests were performed to check effects of temperature, pressure, gas velocity, and capacity on reduction characteristics of mass produced particle in a 0.5 MWth chemical looping combustion system. The fuel conversion and the CO2 selectivity increased as the temperature increased and as the gas velocity decreased. However the CO2 selectivity showed the maximum and decreased as the capacity increased because the CO emission increased. The results show that high temperature, low gas velocity and low inert gas concentration are preferable to ensure high reactivity of oxygen carrier in the fuel reactor.

A Study on the Greenhouse Gas Intensity of Building Groups and Regional in Korea (국내 에너지다소비건물의 용도별.지역별 온실가스 배출원단위분석 연구)

  • Lee, Chung-Kook;Suh, Seung-Jik
    • Journal of the Korean Solar Energy Society
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    • v.32 no.3
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    • pp.162-169
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    • 2012
  • Our country set the mid-term reduction goal of greenhouse gases up to 2020 in accordance with Bali roadmap agreed in 2007 through the negotiation with UNFCCC in 2009 and specified the proper goal as by the Basic Act on Green Growth that went into effect at April, 2010. First of all the enlargement of green building construction has been suggested as a worldwide strategy to achieve the green house gas reduction. Building area is one of most important sectors for the countermeasure of climate change agreement and the achievement of national green house gas reduction goal and the need to reduce its green house gases has been increased accordingly. The objective of the study is to examine the status and characterization of mass energy consumption local governmental buildings' green house gas emissions depending on usage (hotel, school, apartment, hospital) through the green house gas emission source unit analysis. The result indicated that the energy source unit was proportional to green house gas source unit and hotel showed the highest green house gas emission source unit per open area of construction unit, followed by hospital, apartment, and then school. In case of apartment, green house gas emission source unit per open area of construction unit decreased as year went on. Meanwhile school building showed a striking increase in the annual energy source unit.

Effects of Non-Absorbable Gases on the Absorption Process of Aqueous LiBr Solution Film in a Vertical Tube (II) (수직관내 리튬브로마이드 수용액막의 흡수과정에 대한 비흡수가스의 영향)

  • Kim, Byeong-Ju;Lee, Chan-U
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.4
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    • pp.499-509
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    • 1998
  • In the absorption process of water vapor in a liquid film, the composition of the gas phase, in which a non-absorbable gas is combined with the absorbate influences the transport characteristics remarkably. In the present study, the absorption processes of water vapor into aqueous solution of lithium bromide in the presence of non-absorbable gases were investigated analytically. The continuity, momentum, energy and diffusion equations for the solution film and gas phase were formulated in integral forms and solved numerically. It was found that the mass transfer resistance in gas phase increased with the concentration of non-absorbable gas. However the primary resistance to mass transfer was in the liquid phase. As the concentration of non-absorbable gas in the absorbate increased, the liquid-vapor interfacial temperature and concentration of absorbate in solution decreased, which resulted in the reduction of absorption rate. The reduction of mass transfer rate was found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of an absorber where non-absorbable gases accumulated. At higher non-absorbable gas concentration, the decrease of absorption flux was almost linear to the volumetric concentration of non-absorbable gas.

Effects of Gas Recycle on Plant Cell Growth and Secondary Metabolites Production in Airlift Fermentor (Airlift 배양기에서 Gas Recycle이 식물세포 성장 및 이차대사산물 생성에 미치는 영향)

  • 유병삼;변상요
    • KSBB Journal
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    • v.9 no.2
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    • pp.180-185
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    • 1994
  • The productivity of alkaloid in the airlift fermentor operation was less than that of suspension coltures of Eschscholtzia californica cells in the shake flask. To overcome the productivity reduction, a gas recycle airlift fermentor was developed because the gas-stripping in normal airlift fermentor was believed to play a significant role for productivity reduction. The alkaloid content in the gas recycle system with Eschscholtzia californica suspension cells was 2.7 times higher than that of normal airlift fermentor. The productivity of alkaloids and $CO_2$ concentration were affected by the volume of gas reservoir in the gas recycle airlift fermentor.

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Optimal firing method of the Celadon using gas kiln (가스가마를 사용한 최적의 청자 소성방법 연구)

  • Kim, Sanggon
    • Journal of Energy Engineering
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    • v.28 no.2
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    • pp.55-62
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    • 2019
  • The purpose of this research is to find the optimum combustion conditions for the celadon using a gas kiln. It is clearly defined by the amount of CO gas in the kiln that it is fired in the commonly used oxidation and reduction atmosphere. As a result, while celadon was fired at $1250^{\circ}C$, oxidation happened when the amount of CO was 0~4,500 PPM, a neutral condition happened when the of CO was 4,500~25,000PPM and a reducing process was happened when the of CO was more that 25,000PPM. To reduce gas and firing time while keeping uniformly the firing temperature and firing condition of the gas kiln, you can partially block the gas corridor and adjust it as a damper. This adjustment reduces gas consumption by 40% and shortens the firing time by 1 hour.

Two-stage concession game approach for analyzing greenhouse gases emission reduction schemes

  • Yuan, Liang;He, Weijun;Degefu, Dagmawi Mulugeta;Kim, Soonja;Shen, Juqin;An, Min
    • Environmental Engineering Research
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    • v.21 no.4
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    • pp.420-426
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    • 2016
  • Climate change imposes a huge treat on the sustainability of our environment. One of the major reasons for the increasing impacts of climate change is the emission of greenhouse gases. Therefore, cooperative greenhouse gas emission reduction schemes with a general consensus are needed in order to reduce the impacts of climate change. Due to the strong link between greenhouse gas emission and economic development there is disagreement among countries on the designing and implementation of emission reduction plans. In this paper the authors proposed a two-stage concession game to analyze emission reduction plans and determine a balanced emission range that improves the utilities of the bargaining parties. Furthermore the game was applied to a hypothetical example. Our results from the case study indicated that even though the utilities of the bargaining parties is highly affected by emission reductions, after making concessions their utilities can be improved given their emission reductions are within in a certain desirable range. The authors hope that this article provides insights which could be useful for understanding emission reduction plans and their consequences on the negotiating parties.