• 제목/요약/키워드: gas production

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합성천연가스(SNG) 생산을 위한 석탄가스화기 기술성 검토 (Technical Review of Coal Gasifiers for Production of Synthetic Natural Gas)

  • 이근우;신용승
    • 대한기계학회논문집B
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    • 제36권8호
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    • pp.865-871
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    • 2012
  • 최근 고유가와 천연가스 수요 상승에 따른 가격 상승으로 인하여 상대적으로 낮은 가격의 석탄을 이용한 에너지 생산이 주목을 받고 있다. IGCC를 비롯한 석탄가스화 분야는 오래전부터 청정화석연료를 이용한 유망한 기술로 각광받아 왔었다. 본 연구에서는 이러한 석탄가스화 기술을 이용하여 합성천연가스를 생산하는 실제 프로젝트 개발단계에서 석탄가스화기 선정을 위한 기술적 검토를 수행하였다. 합성천연가스 생산에 적합하다고 판단되는 가스화기로써 고정층 슬래그 가스화기, 습식 분류층 가스화기, 건식 분류층 가스화기를 검토 대상으로 선정하여 연구를 진행하였다. 선정된 가스화기별 주요 공정 특징 및 성능에 대하여 검토하였으며, 종합검토내용을 토대로 합성천연가스 생산시 석탄가스화기 선정방향에 대하여 제시하였다.

소규모 수소 충전소용 천연가스 수증기 개질공정의 수치모사 및 공정 변수 값의 산정 (Simulation for the Evaluation of Reforming Parameter Values of the Natural Gas Steam Reforming Process for a Small Scale Hydrogen-Fueling Station)

  • 이득기;구기영;서동주;서유택;노현석;윤왕래
    • 한국수소및신에너지학회논문집
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    • 제18권1호
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    • pp.12-25
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    • 2007
  • Numerical simulation of the natural gas steam reforming process for on-site hydrogen production in a $H_2$ fueling station was conducted on the basis of process material and heat balances. The effects of reforming parameters on the process efficiency of hydrogen production were investigated, and set-point values of each of the parameters to minimize the sizes of unit process equipments and to secure a stable operability of the reforming process were suggested. S/C ratio of the reforming reactants was found to be a crucial parameter in the reforming process mostly governing both the hydrogen production efficiency and the stable operability of the process. The operation of the process was regarded to be stable if the feed water(WR) as a reforming reactant could evaporate completely to dry steam through HRSG. The optimum S/C ratio was 3.0 where the process efficiency of hydrogen production was maximized and the stable operability of the process was secured. The optimum feed rates of natural gas(NGR) and WR as reforming reactants and natural gas(NGB) as a burner fuel were also determined for the hydrogen production rate of $27\;Nm^3/h$.

액화천연가스 냉온열을 이용한 복합사이클의 설계 및 엑서지 해석 (Design and Exergy Analysis for a Combined Cycle using LNG Cold/Hot Energy)

  • 이근식
    • 설비공학논문집
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    • 제17권4호
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    • pp.285-296
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    • 2005
  • In order to reduce the compression power and to use the overall energy contained in LNG effectively, a combined cycle is devised and simulated. The combined cycle is composed of two cycles; one is an open cycle of liquid/solid carbon dioxide production cycle utilizing LNG cold energy in $CO_2$ condenser and the other is a closed cycle gas turbine which supplies power to the $CO_2$ cycle, utilizes LNG cold energy for lowering the compressor inlet temperature, and uses the heating value of LNG at the burner. The power consumed for the $CO_2$ cycle is investigated in terms of a production ratio of solid $CO_2$. The present study shows that much reduction in both $CO_2$ compression power (only $35\%$ of power used in conventional dry ice production cycle) and $CO_2$ condenser pressure could be achieved by utilizing LNG cold energy and that high cycle efficiency ($55.3\%$ at maximum power condition) in the gas turbine could be accomplished with the adoption of compressor inlet cooling and regenerator. Exergy analysis shows that irreversibility in the combined cycle increases linearly as a production ratio of solid $CO_2$ increases and most of the irreversibility occurs in the condenser and the heat exchanger for compressor inlet cooling. Hence, incoming LNG cold energy to the above components should be used more effectively.

유체 생산에 따른 유발지진 사례 분석 (Case Studies on Fluid Extraction Induced Seismicity)

  • 서은진;유화정;민기복;윤정석
    • 터널과지하공간
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    • 제31권6호
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    • pp.385-399
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    • 2021
  • 인간의 활동에 의해 발생하는 유발지진 중 유체의 주입뿐만 아니라 유체의 생산 또한 원인으로 알려져 있다. 본 기술보고에서는 유체를 생산할 때 저류층 내부의 공극압 감소로 인해 지진이 유발되는 메커니즘을 정리하였다. 유체 생산으로 인해 유발지진이 발생한 사례들 중 네덜란드 흐로닝언(Groningen) 가스전, 프랑스 라크(Lacq) 가스전 그리고 멕시코 세로 프리에토(Cerro Prieto) 지열 발전소를 소개하고 각 사례에 대한 기존 연구들을 정리하였다. 유체 생산 필드에서의 유체 생산량과 지반침하, 그리고 기존 단층의 유무가 유발지진과 큰 상관성을 보이는 것을 확인하였다. 따라서, 석유나 가스 생산 필드 그리고 지열 발전소 개발을 위해 저류층에서 유발지진의 발생 가능성을 내재하고 있는 단층 유무에 대한 정확한 탐사와 생산 중에 나타나는 지반침하를 실시간으로 모니터링하며 생산량을 조절하는 것이 중요하다.

침출수 무배출식 모형매립조를 이용한 도시폐기물 분해특성 (Decomposition Characteristics of Municipal Solid Wastes in Lysimeter Without Leachate Discharge)

  • 류돈식;이해승;이찬기
    • 환경위생공학
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    • 제15권2호
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    • pp.49-57
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    • 2000
  • The objective of this study is to find solid waste decomposition in landfill without leachate discharge. This study was observed variation of landfill gas production rate and leachate for stabilization assessment, and using four sets of lysimeter as experimental apparatus. Soild waste decomposition was accelerated in without leachate discharge system by sufficient moisture for methane bacteria. And gas production rate was between 54.2ℓ/kg VS∼335.9ℓ/kg VS in each lysimeter. Generation time of methane gas was showed different in each lysimeter, but it was much faster than literature research. The time of stabilization phase were began as follows : L-1 400 day, L-2 350 day, L-3 170 day and L-4 70 day respectively. Decreasing times of BOD/COD ratio and C/N ratio were necessary more than literature research because organic matter was not discharge such as wash out.

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Formation of Ti-B-N-C Ceramic Composite Materials via a Gas-Solid Phase Reaction

  • Yoon, Su-Jong
    • 한국재료학회지
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    • 제16권1호
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    • pp.50-57
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    • 2006
  • Phase mixtures of Titanium boride, nitride, and carbide powder were produced by the reduction of a mixture of titanium and boron oxides with carbon via a gas-solid phase reaction. Boron oxides produce a vapour phase or decompose to a metal sub-oxide gaseous species when reduced at elevated temperature. The mechanism of BO sub-oxide gas formation from $B_2O_3$ and its subsequent reduction to titanium diboride for the production of uniform size hexagonal platelets is explained. These gaseous phases are critical for the formation of boride, nitride and carbide ceramics. For the production of ceramic phase composite microstructures, the nitrogen partial pressure was the most critical factor. Some calculated equilibrium phase fields has been verified experimentally. The theoretical approach therefore identifies conditions for the formation of phase mixtures. The thermodynamic and kinetic factors that govern the phase constituents are also discussed.

Development of CO Laser-Arc Hybrid Welding Process

  • Lee, Se-Hwan
    • 한국레이저가공학회지
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    • 제5권3호
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    • pp.15-20
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    • 2002
  • The principal obstacle to selection of a laser processing method in production is its relatively high equipment cost and the natural unwillingness of production supervision to try something new until it is thoroughly proven. The major objective of this work is focused on the combined features of gas tungsten arc and a low-power cold laser beam. In this work, the laser beam from a 7 watts carbon monoxide laser was combined with electrical discharges from a short-pulsed capacitive discharge GTA welding power supply. When the low power CO laser beam passes through a special composition shielding gas, the CO molecules in the gas absorbs the radiation, and ionizes through a process blown as non-equilibrium, vibration-vibration pumping. The resulting laser-induced plasma(LIP) was positioned between various configurations of electrodes. The high-voltage impulse applied to the electrodes forced rapid electrical breakdown between the electrodes. Electrical discharges between tungsten electrodes and aluminum sheet specimens followed the ionized path provided by LIP. The result was well-focused melted spots.

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LNG-FPSO(Liquefied Natural Gas-Floating Production Storage and Offloading)용 질소 팽창 사이클의 효율 개선에 대한 연구 (Investigation on Efficiency Improvement of the Nitrogen Expander Cycle : Natural Gas Liquefaction Process for LNG-FPSO)

  • 백승환;정상권;김선영
    • 설비공학논문집
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    • 제22권7호
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    • pp.442-447
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    • 2010
  • FPSO (Floating Production Strorage and Offloading) method for LNG industry is efficient and facile compared to onshore NG (Natural Gas) treatment facility. Five simple natural gas liquefaction cycles for FPSO are presented and simulated in this paper. SMR (Single Mixed Refrigerant) cycle, SNE (Single Nitrogen Expander) cycle, DNE (Double Nitrogen Expander) cycle, PNE (Precooled Nitrogen Expander) cycle, and PDNE (Precooled Double Nitrogen Expander) cycle are compared. Simple analysis results in this paper show that precooling process and adding an expander in the liquefaction cycle is an effective way to increase liquefaction efficiency.

Anaerobic Fermentation of Woody Biomass Treated by Various Methods

  • Nakamura, Yoshitoshi;Mtui, Godliving
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제8권3호
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    • pp.179-182
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    • 2003
  • Anaerobic fermentation was attempted to produce methane from the wood chip (Eucalyptus globulus). By the pretreatment of the wood chip using hot water with high temperature, NaOH, and steam explosion, the production of methane gas was enhanced. The pretreatment using Steam explosion resulted in more amount of methane gas produced than the treatment using either hot water or 1% (w/w) NaOH with high temperature, and the steam explosion at a steam pressure of 25 atm and a steaming time of 3 min was the most effective for the methane production. The amount of methane gas produced depended on the ratio of weight of Klason lignin, a high molecular weight lignin, in the treated wood chip.

Determination of Nutritive Value of Wild Mustard, Sinapsis arvensis Harvested at Different Maturity Stages Using In situ and In vitro Measurements

  • Kamalak, Adem;Canbolat, Onder;Gurbuz, Yavuz;Ozkan, Cagri Ozgur;Kizilsimsek, Mustafa
    • Asian-Australasian Journal of Animal Sciences
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    • 제18권9호
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    • pp.1249-1254
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    • 2005
  • The aim of this study was to determine the effect of maturity stage on the nutritive value of wild mustard straw in terms of chemical composition, in situ, in vitro dry matter degradability and calculated ME. The nutritive values of wild mustard, Sinapsis arvensis hays harvested at three stages were evaluated by chemical composition, in vitro gas production and in situ dry matter degradation methods. Gas production or dry matter (DM) degradation were determined at 0, 3, 6, 12, 24, 48, 72 and 96 h and their kinetics were described using the equation p = a+b(1-e$^{-ct}$). Maturity had a significant effect on both the chemical composition and degradability of wild mustard. Neutral detergent fibre (NDF) and acid detergent fibre (ADF) (p<0.001) increased with increasing maturity whereas the crude protein (CP) (p<0.001) decreased. The gas produced after 96 h incubation ranged between 64.7 and 81.5 ml per 0.200 g of dry matter. The gas production (ml) at all incubation times and estimated parameters decreased with increasing maturity of wild mustard. The gas production at all incubation times and estimated parameters (a, b (a+b), metabolizable energy (ME) and organic matter digestibility (OMD)) were negatively correlated with NDF and ADF. The DM disappearance after 96 h incubation ranged between 50.8 and 76.1%. The in situ DM disappearance at all incubation times and estimated parameters decreased with increasing maturity of wild mustard. The in situ dry matter disappearance at all incubation times and some estimated parameters (c, a, b and effective dry matter degradability (EDMD)) were negatively correlated with NDF and ADF but positively correlated with CP. The nutritive value of wild mustard continually changed as it matured. Wild mustard, harvested at the proper stage of maturity offers considerable potential as a high quality forage for ruminants during the winter feeding period. The present study showed that if higher quality forage is an objective, wild mustard should be harvested at the early flowering stage.