• Title/Summary/Keyword: gas measurement method

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Temperature Prediction Method for Superheater and Reheater Tubes of Fossil Power Plant Boiler During Operation (화력발전 보일러 과열기 및 재열기 운전 중 튜브 온도예측기법)

  • Kim, Bum-Shin;Song, Gee-Wook;Yoo, Seong-Yeon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.5
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    • pp.563-569
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    • 2012
  • The superheater and reheater tubes of a heavy-load fossil power plant boiler can be damaged by overheating, and therefore, the degree of overheating is assessed by measuring the oxide scale thickness inside the tube during outages. The tube temperature prediction from the oxide scale thickness measurement is necessarily accompanied by destructive tube sampling, and the result of tube temperature prediction cannot be expected to be accurate unless the selection of the overheated point is precise and the initial-operation tube temperature has been obtained. In contrast, if the tube temperature is to be predicted analytically, considerable effort (to carry out the analysis of combustion, radiation, convection heat transfer, and turbulence fluid dynamics of the gas outside the tube) is required. In addition, in the case of analytical tube temperature prediction, load changes, variations in the fuel composition, and operation mode changes are hardly considered, thus impeding the continuous monitoring of the tube temperature. This paper proposes a method for the short-term prediction of tube temperature; the method involves the use of boiler operation information and flow-network-analysis-based tube heat flux. This method can help in high-temperaturedamage monitoring when it is integrated with a practical tube-damage-assessment method such as the Larson-Miller Parameter.

Evaluation of CH4 Flux for Continuous Observation from Intertidal Flat Sediments in the Eoeun-ri, Taean-gun on the Mid-western Coast of Korea (서해안 태안 어은리 갯벌의 연속관측 메탄(CH4) 플럭스 특성 평가)

  • Lee, Jun-Ho;Rho, Kyoung Chan;Woo, Han Jun;Kang, Jeongwon;Jeong, Kap-Sik;Jang, Seok
    • Economic and Environmental Geology
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    • v.48 no.2
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    • pp.147-160
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    • 2015
  • In 2014, on 31 August and 1 September, the emissions of $CH_4$, $CO_2$, and $O_2$ gases were measured six times using the closed chamber method from exposed tidal flat sediments in the same position relative to the low point of the tidal cycle in the Eoeun-ri, Taean-gun, on the Mid-western Coast of Korea. The concentrations of $CH_4$ in the air sample collected in the chamber were measured using gas chromatography with an EG analyzer, model GS-23, within 6 hours of collection, and the other gases were measured in real time using a multi-gas monitor. The gas emission fluxes (source (+), and sink (-)) were calculated from a simple linear regression analysis of the changes in the concentrations over time. In order to see the surrounding parameters (water content, temperature, total organic carbon, average mean size of sediments, and the temperature of the inner chamber) were measured at the study site. On the first day, across three measurements during 5 hours 20 minutes, the observed $CO_2$ flux absorption was -137.00 to $-81.73mg/m^2/hr$, and the $O_2$ absorption, measured simultaneously, was -0.03 to $0.00mg/m^2/hr$. On the second day using an identical number of measurements, the $CO_2$ absorption was -20.43 to $-2.11mg/m^2/hr$, and the $O_2$ absorption -0.18 to $-0.14mg/m^2/hr$. The $CH_4$ absorption before low tide was $-0.02mg/m^2/hr$ (first day, Pearson correlation coefficient using the SPSS statistical analysis is -0.555(n=5, p=0.332, pronounced negative linear relationship)), and $-0.15mg/m^2/hr$ (second day, -0.915(n=5, p=0.030, strong negative linear relationship)) on both measurement days. The emitted flux after low tide on both measurement days reached a minimum of $+0.00mg/m^2/hr$ (+0.713(n=5, p=0.176, linear relationship which can be almost ignored)), and a maximum of $+0.03mg/m^2/hr$ (+0.194(n=5, p=0.754, weak positive linear relationship)) after low tide. However, the absolute values of the $CH_4$ fluxes were analyzed at different times. These results suggest that rate for $CH_4$ fluxes, even the same time and area, were influenced by changes in the tidal cycle characteristics of surface sediments for understanding their correlation with these gas emissions, and surrounding parameters such as physiochemical sediments conditions.

A Study on the Characteristics of Condensable Fine Particles in Flue Gas (배출가스 중 응축성미세먼지 특성 연구)

  • Gong, Buju;Kim, Jonghyeon;Kim, Hyeri;Lee, Sangbo;Kim, Hyungchun;Jo, Jeonghwa;Kim, Jeonghun;Gang, Daeil;Park, Jeong Min;Hong, Jihyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.5
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    • pp.501-512
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    • 2016
  • The study evaluated methods to measure condensable fine particles in flue gases and measured particulate matter by fuel and material to get precise concentrations and quantities. As a result of the method evaluation, it is required to improve test methods for measuring Condensable Particulate Matter (CPM) emitted after the conventional Filterable Particulate Matter (FPM) measurement process. Relative Standard Deviation (RSD) based on the evaluated analysis process showed that RSD percentages of FPM and CPM were around 27.0~139.5%. As errors in the process of CPM measurement and analysis can be caused while separating and dehydrating organic and inorganic materials from condensed liquid samples, transporting samples, and titrating ammonium hydroxide in the sample, it is required to comply with the exact test procedures. As for characteristics of FPM and CPM concentrations, CPM had about 1.6~63 times higher concentrations than FPM, and CPM caused huge increase in PM mass concentrations. Also, emission concentrations and quantities varied according to the characteristics of each fuel, the size of emitting facilities, operational conditions of emitters, etc. PM in the flue gases mostly consisted of CPM (61~99%), and the result of organic/inorganic component analysis revealed that organic dusts accounted for 30~88%. High-efficiency prevention facilities also had high concentrations of CPM due to large amounts of $NO_x$, and the more fuels, the more inorganic dusts. As a result of comparison between emission coefficients by fuel and the EPA AP-42, FPM had lower result values compared to that in the US materials, and CPM had higher values than FPM. For the emission coefficients of the total PM (FPM+CPM) by industry, that of thermal power stations (bituminous coal) was 71.64 g/ton, and cement manufacturing facility (blended fuels) 18.90 g/ton. In order to estimate emission quantities and coefficients proper to the circumstances of air pollutant-emitting facilities in Korea, measurement data need to be calculated in stages by facility condition according to the CPM measurement method in the study. About 80% of PM in flue gases are CPM, and a half of which are organic dusts that are mostly unknown yet. For effective management and control of PM in flue gases, it is necessary to identify the current conditions through quantitative and qualitative analysis of harmful organic substances, and have more interest in and conduct studies on unknown materials' measurements and behaviors.

A Study on VOCS Adsorption at Low Pressure (낮은 분압의 VOCs의 흡착에 관한 연구)

  • Song, Hun-Taek;Kan, Sung-Won;Min, Byong-Hun;Suh, Sung-Sup
    • Clean Technology
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    • v.9 no.4
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    • pp.153-161
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    • 2003
  • This study was carried out as a basic experiment for development of adsorption process in which benzene and toluene was adsorbed on activated carbon. In the static adsorption experiment, Adsorption character of benzene and toluene was studied by change of temperature and pressure. Activated carbon 12~20mesh and activated carbon 20~40mesh was used as adsorbents, Benzene, toluene and nitrogen as adsorbates. Experimental data were obtained to fitted to Langmuir isotherm and dependence was acquired. Parameters of adsorption heat and adsorption constant was obtained. Static adsorption experiment for binary mixtures confirmed that Langmuir isotherm parameters could be applicable to Extended Langmuir isotherm. Experimental technique used in this study only requires pressure measurement and this technique is different from the conventional method which measures gas mole compositions before adsorption and after adsorption. The dynamic adsorption experiment was carried out and the experimental results was compared with the computer simulation results. In this study, basic data was acquired to decide adsorption conditions in the process.

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A Experiment Study on Selection the Optimal Condition for GMA Root-pass Welding in Overhead and Vertical Position (GMA 위보기 및 수직자세 초층용접 최적조건 선정에 관한 실험적 연구)

  • Kim, Ji-Sun;Kim, In-Ju;Kim, Ill-Soo
    • Journal of Welding and Joining
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    • v.30 no.6
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    • pp.42-48
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    • 2012
  • Due to increase in demand of stable and long pipelines in natural gas industry, wide range of researches are being performed on automation welding to improved welding quality with respect to weld process parameters in real time measurement. In particular, the coupling between the pipe manufacturing process and location of the weld seam, the measured size of the gap that exists in the weld position and the weld angle depending on whether the movement of molten weld. This is due to absence of controlling welding penetration position, depending on the required size of the angle of the setting. In addition, the optimum welding conditions must be considered while selecting, the correlation between these variables and the systematic correlation has not yet been identified. Therefore, in most welded pipe root-pass weld solely depends on the experience of workers in relation to secure a stable weld quality. In this study, automation welding system is implemented to select a suitable root-pass STT (Surface Tension Transfer) welding method using the optimal welding conditions. To successfully accomplish this objective, there were various welding conditions used for welding experiment to confirm that the assessment required for construction through the pipe and automatic welding process is proposed to optimize this plan.

Simulation and Model Validation of Combustion in a Wood Pellet Boiler Using Computational Fluid Dynamics (전산유체역학을 이용한 목재펠릿보일러 연소모델 정립 및 검증)

  • Oh, Kwang Cheol;Euh, Seung Hee;Oh, Jae Heun;Kim, Dae Hyun
    • Journal of Energy Engineering
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    • v.23 no.3
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    • pp.203-210
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    • 2014
  • In this study, combustion behaviour were to analyze by comparing experimental data against predicted values. In developing pellet boiler performance, various factors such as combustion chamber shape, input air velocity, the amount of fuel, temperature, and fuel characteristics need to be analyzed. Analytical model using a numerical method is useful to overcome time and cost consuming by practical experiment. By controlling feeding rate of fuel, flue gas composition and temperature distribution obtained form experiment were compared with predicted values using FLUENT(ANSYS, Inc., Southpointe). Measurement were in good agreement with model predictions : with 0.60 % for $CO_2$ 0.73% for $O_2$ when compared with independent data sets.

Characteristics of Substrate Degradation and Bacterial Population in the Membrane Separation Anaerobic Digestion Process (막분리혐기성소화공정에 있어서 기질분해와 세균군의 분포특성)

  • Cha, Gi-Cheol;Chung, Hyung-Keun;Kim, Dong-Jin;Kim, Young-Chur
    • Journal of Korean Society on Water Environment
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    • v.16 no.4
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    • pp.541-554
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    • 2000
  • Experimental study of anaerobic digestion process combined with and without the submerged separation membrane was investigated by using laboratory-scale reactor at the hydraulic retention time of 0.5 day and 1.0 day. The removal efficiencies of carbohydrate at the digester without and with membrane were 84.4 to 86.8 % and 99.6 to 99.7 %, respectively, and the methane gas recovery efficiencies were 0.4 to 1.2 % and 12.3 to 28.7 %. According to the measurement by the most probable numbers method. the numbers of various groups of bacteria in the digesters with membrane were enumerated in the following ranges ; acidogens : $1.7{\times}10^9$ to $5.0{\times}10^9MPN/m{\ell}$, homoacetogens : $5.0{\times}10^7$ to $2.4{\times}10^8MPN/m{\ell}$, $H_2$-utilizing methanogens : $1.3{\times}10^7$ to $9.2{\times}10^8MPN/m{\ell}$, and acetate-utilizing methanogens : $2.3{\times}10^6$ to $2.0{\times}10^8MPN/m{\ell}$. The number of methanogens at the digester with membrane increased by approximately $10^2$ to $10^4$ times in comparison with that of the digester without membrane.

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Measurement of Radon-222 Exhalation Rate from Building Materials by Using CR-39 Radon Cup (CR-39 라돈컵을 이용한 국산 전축자재의 라돈-222 방출율 측정)

  • Chang, Si-Young;Ha, Chung-Woo;Lee, Byoung-Hun
    • Journal of Radiation Protection and Research
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    • v.16 no.1
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    • pp.15-24
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    • 1991
  • Radon-222 exhalation rate from several domestic building materials were experimentally measured by using radon cup method, in which a CR-39 plastic is used as a passive radon detector. The radon detection factor of CR-39 detector determined in a series of calibration experiments was $0.164{\pm}0.005(tracks\;cm^{-2}/Bq\;d\;m^{-3})$, which is consistent with those reported by other investigators. The radon exhalation rates of several building materials (brick, red brick, concrete block, granite plate, concrete floor and wall) ranges from $6.8{\times}10^{-6}\;(granite plate)\;to\;75.0{\times}10^{-6}Bq/m^2-sec(brick)$ with the increasing order of granite plate, red brick, concrete wall, concrete block, concrete floor and brick. It showed that the CR39 radon cup can be efficiently utilized in measuring the radon-222 gas exhalation rate from building materials.

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Measurement of hydrogen content in a-C:H films prepared by ECR-PECVD (ECR-PECVD 방법으로 증착된 a-C:H 박막의 수소함량 측정)

  • 손영호;정우철;정재인;김인수;배인호
    • Journal of the Korean Vacuum Society
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    • v.10 no.1
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    • pp.119-126
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    • 2001
  • Hydrogenated amorphous carbon (a-C:H) films were deposited by ECR-PECVD (electron cyclotron resonance-plasma enhanced chemical vapor deposition) method with deposition conditions such as ECR plasma source power, gas composition of methane and hydrogen, deposition time and substrate bias voltage. The hydrogen content in the films has been measured by ERDA (elastic recoil detection analysis) using 2.5 MeV $He^{++}$ ion beam. From the results of AES (Auger electron spectroscopy), RBS (Rutherford backscattering spectrometry) and ERDA, the composition elements of deposited film were confirmed the carbon atom and the hydrogen atom. It was observed by FTIR (Fourier transform infrared) that the hydrogen contents in the film varied according to the deposition conditions. In deposition condition of substrate bias voltage, the hydrogen contents were decreased remarkably because the amount of dehydrogenation in films was increased as the substrate bias voltage increased. In the rest deposition conditions, the hydrogen contents in the film were measured in the range 45~55%.

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Filter- and Denuder-Based Organic Carbon Correction for Positive Sampling Artifacts

  • Hwang, InJo;Na, Kwangsam
    • Asian Journal of Atmospheric Environment
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    • v.11 no.2
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    • pp.107-113
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    • 2017
  • This study describes (1) the impact of positive sampling artifacts caused by not only a filter-based sampling, but also a denuder-based sampling in the determination of particle-phase organic carbon (POC), (2) the effect of sample flow rate on positive artifacts, and (3) an optimum flow rate that provides a minimized negative sampling artifact for the denuder-based sampling method. To achieve the goals of this study, four different sampling media combinations were employed: (1) Quartz filter-alone (Q-alone), (2) quartz filter behind quartz-fiber filter (QBQ), (3) quartz filter and quartz filter behind Teflon filter (Q-QBT), and (4) quartz filter behind carbon-based denuder (Denuder-Q). The measurement of ambient POC was carried out in an urban area. In addition, to determine gas-phase OC (GOC) removal efficiency of the denuder, a Teflon filter and a quartz filter were deployed upstream and downstream of the denuder, respectively with varying sample flow rates: 5, 10, 20, and 30 LPM. It was found that Q-alone sampling configuration showed a higher POC than QBQ, Q-QBT, and Denuder-Q by 12%, 28%, and 23%, respectively at a sample flow rate of 20 LPM due to no correction for positive artifact caused by adsorption of GOC onto the filter. A lower quantity of GOC was collected from the backup quartz filter on QBQ than that from Q-QBT. This was because GOC was not in equilibrium with that adsorbed on the front quartz filter of QBQ during the sampling period. It is observed that the loss of particle number and mass across the denuder increases with decreasing sample flow rate. The contribution o f positive arti facts to POC decreased with increasing sample flow rate, showing 29%, 25%, and 22% for 10, 20, and 30 LPM, respectively. The 20 LPM turns out to be the optimum sample flow rate for both filter and denuder-based POC sampling.