• Title/Summary/Keyword: gas measurement method

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Crystal Growth of 3C-SiC Using HMDS Gas Source (HMDS 가스원을 이용한 3C-SiC의 결정성장)

  • Sun, Ju-Hun;Chung, Yun-Sik;Chung, Gwiy-Sang;Nishino, Shigehiro
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.735-738
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    • 2002
  • Single crystal 3C-SiC(cubic silicon carbide) thin-films were deposited on Si(100) substrate up to a thickness of $4.3{\mu}m$ by APCVD method using HMDS(hexamethyildisilane) at $1350^{\circ}C$. The HMDS flow rate was 0.5 sccm and the carrier gas flow rate was 2.5 slm. The HMDS flow rate was important to get a mirror-like crystal surface. The growth rate of the 3C-SiC films was $4.3{\mu}m/hr$. The 3C-SiC epitaxical films grown on Si(100) were characterized by XRD, AFM, RHEED, XPS and raman scattering, respectively. The 3C-SiC distinct phonons of TO(transverse optical) near $796cm^{-1}$ and LO(longitudinal optical) near $974{\pm}1cm^{-1}$ were recorded by raman scattering measurement. The heteroepitaxially grown films were identified as the single crystal 3C-SiC phase by XRD spectra$(2{\theta}=41.5^{\circ})$.

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Electron Density Measurement of Inductively Coupled Plasma Using Langmuir Probe (Langmuir Probe를 이용한 유도결합형 플라즈마의 전자 밀도 측정)

  • Lee, Young-Hwan;Jo, Ju-Ung;Kim, Kwang-Soo;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1111-1114
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    • 2003
  • In this paper, electrical characteristics of inductively coupled plasma in an electrodeless fluorescent lamp were investigated using a Langmuir probe with a variation of argon gas pressure. The RF output was applied in the range of $5{\sim}50W$ at 13.56MHz. The internal plasma voltage of the chamber and the probe current were measured while varying the supply voltage to the Langmuir probe in the range of $-100V{\sim}+100V$. When the pressure of argon gas was increased, electric current was decreased. There was a significant electric current increase from l0W to 30W. Also, when the RF power was increased, electron density was increase. This implies that this method can be used to find an optimal RF power for efficient light illumination in an electrodeless fluorescent lamp.

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Equivalence Ratio Measurements in Gas Spray Using Laser Raman Scattering (Laser Raman Scattering을 이용한 가스 분무내 당량비 계측에 관한 연구)

  • Jin, S.H.;Park, K.S.;Song, J.I.;Kim, G.S.
    • Journal of ILASS-Korea
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    • v.2 no.4
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    • pp.7-14
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    • 1997
  • Laser Raman scattering method has been applied to measure equivalence ratio of methane/air mixture in injected spray. We used high power KrF excimer laser$(\lambda=248nm)$ and a high gain ICCD camera to capture low intensity signal. Raman shifts and Raman scattering cross -sections of $H_2,\;O_2,\;N_2,\;CO_2,\;CH_4\;and\;C_3H_8$ are measured precisely. Our results show an excellent agreement with those of other groups. Mole fraction measurement of $O_2\;and\;N_2$ from air shows that $O_2:N_2=0.206:0.794$. We used gas injector which was operated at 1 bar. Methane is used as a fuel. Spray region is $10mm\times37mm$ and this region is divided into 80 points. In Raman signals are obtained and ensemble averaged for each point. 3-d and contour plot of distribution of equuivalence ratio is presented. Our measured results show that the equivalence ratio of methane/air mixture in methane-rich region is reasonable. However, more study is necessary for methane-lean region because background noise level is almost same as Raman intensity of methane.

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A Study on the Calculation Process of Carbon Dioxide Emission for Buildings with Life Cycle Assessment (건축물 생애과정에서의 이산화탄소 배출량 계산 프로세스에 관한 연구)

  • Jeong, Young-Sun;Huh, Jung-Ho
    • Journal of the Korean Solar Energy Society
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    • v.31 no.1
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    • pp.23-30
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    • 2011
  • International cooperation to reduce greenhouse gas emissions is expected to provide a big crisis and a great opportunity at the same time for our industry that heavily consumes energy. To cope actively with the international environmental regulation, such as the Framework Convention on Climate Change, quantitative measurement of the volume of greenhouse gases emitted by various industries and quantitative prediction of the greenhouse gas emissions of the future are becoming more important than anything else at the national level. This study aims to propose the calculation process of carbon dioxide($CO_2$) emission for building in life cycle. This paper describes and compares 9 different tool for environmental load estimation with LCA. This study proposed the calculation process for quantitatively predicting and assessing $CO_2$ emissions during the life cycle of buildings based on the life cycle assessment(LCA). The life cycle steps of buildings were divided into the design/supervision, new construction, repair, renovation, use of operating energy in buildings, maintenance, and reconstruction stage in the life cycle inventory analysis and the method of assessing the environmental load in each stage was proposed.

Mechanical and Antibacterial Properties of Copper-added Austenitic Stainless Steel (304L) by MIM

  • Nishiyabu, Kazuaki;Masai, Yoshikaze;Ishida, Masashi;Tanaka, Shigeo
    • Journal of Powder Materials
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    • v.9 no.4
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    • pp.227-234
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    • 2002
  • For the austenitic stainless steel (304L) manufactured by metal injection molding(MIM), the effects of copper content and sintering temperature on the mechanical properties, antibacterial activities, corrosion resistance, and electric resistances were investigated. The specimens were prepared by injection molding of the premixed powders of water-atomized 304 L and Cu with poly-acetyl binders. The green compacts were prepared with various copper contents from 0 to 10 wt.% Cu, which were debound thermally at 873 K for 7.2 ks in $N_2$gas atmosphere and subsequently sintered at various temperatures from 1323 K to 1623 K for 7.2 ks in Ar gas atmosphere. The relative density and tensile strength of the sintered compacts showed the minimum values at 5 and 8 wt.% Cu, respectively. Both the relative density and the tensile strength of the specimen with 10 wt.% Cu sintered at 1373 K showed the highest values, higher than those of copper-free specimen. Antibacterial activities investigated by the plastic film contact printing method for bacilli and the quantitative analysis of copper ion dissolved in water increased as the increase of the copper content to stainless steels. It was also verified by the measurement of pitting potential that the copper addition in 304 L could improve the corrosion resistance. Furthermore the electric conductivity increased with the increase of copper content.

Wound-State Monitoring for Burn Patients Using E-Nose/SPME System

  • Byun, Hyung-Gi;Persaud, Krishna C.;Pisanelli, Anna Maria
    • ETRI Journal
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    • v.32 no.3
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    • pp.440-446
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    • 2010
  • Array-based gas sensors now offer the potential of a robust analytical approach to odor measurement for medical use. We are developing a fast reliable method for detection of microbial infection by monitoring the headspace from the infected wound. In this paper, we present initial results obtained from wound-state monitoring for burn patients using an electronic nose incorporating an automated solid-phase microextraction (SPME) desorption system to enable the system to be used for clinical validation. SPME preconcentration is used for sampling of the headspace air and the response of the sensor module to variable concentrations of volatiles emitted from SPME fiber is evaluated. Gas chromatography-mass spectrometry studies prove that living bacteria, the typical infectious agents in clinical practice, can be distinguished from each other by means of a limited set of key volatile products. Principal component analysis results give the first indication that infected patients may be distinguished from uninfected patients. Microbial laboratory analysis using clinical samples verifies the performance of the system.

Laminar Burning Velocity Measurement of SNG/Air Flames - A Comparison of Bunsen and Spherical Flame Method - (SNG/공기 화염의 층류 연소속도 측정 - 분젠과 구형 화염법 비교 -)

  • KIM, DONGCHAN;LEE, KEEMAN
    • Journal of Hydrogen and New Energy
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    • v.27 no.6
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    • pp.737-746
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    • 2016
  • This article describes a comparison on laminar burning velocity measured by Bunsen and spherical flame methods of synthetic natural gas (SNG) with various composition of hydrogen. In this study, the laminar burning velocity measurements were employed by Bunsen burner and cylindrical constant combustor at which flame images were captured by Schlieren system. These results were also compared with numerical based on CHEMKIN package with GRI 3.0, USC-II and UC Sandiego mechanism. In case of spherical flames, the suitable flame radius range and theoretical models were verified using the well-known previous results in methane/air flames. As an experimental condition, hydrogen content of SNG was adjusted 0% to 11%. Equivalence ratios of Bunsen flames were adjusted from 0.8 to 1.6. On the other hand, those of spherical flames were adjusted from 0.6 to 1.4, relatively. From results of this study, the both laminar burning velocities measured in Bunsen and spherical flame methods were resulted in similar tendency. As the hydrogen content increased, the laminar burning velocity also increased collectively. Laminar burning velocity of measured SNG-air flames was best coincided with GRI 3.0 mechanism by comparison of reaction mechanisms.

Preparation of ITO Thin Films by FTS{Facing Targets Sputtering) Method (FTS법을 이용한 ITO박막의 제작)

  • Kim, Geon-Hi;Keum, Min-Jong;Kim, Han-Ki;Son, In-Hwan;Jang, Kyung-Wook;Lee, Won-Jae;Choi, Hyung-Wook;Park, Yong-Seo;Kim, Kyung-Hwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.11
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    • pp.1230-1233
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    • 2004
  • The ITO thin films were prepared by the FTS(Facing Targets Sputtering) system. The ITO thin films are deposited by changing the input current and working gas pressure. Then, electric characteristics, transmittance and surface roughness of ITO thin films were measured by Hall effect measurement, UV-VIS spectrometer and AFM. As a result, the ITO thin film was fabricated with resistivity 6xl0$^{-4}$ Ωㆍcm, carrier mobility 52.11 $\textrm{cm}^2$/Vㆍsec, carrier concentration 1.72 x $10^{20}$ $cm^{-3}$ transmittance over 85 % of ITO film at working gas pressure 1 mTorr and input current 0.6 A.

Measurement of Inductively Coupled Plasma Using Langmuir Probe (Langmuir Probe를 이용한 유도결합형 플라즈마의 측정)

  • Lee, Y.H.;Jo, J.U.;Kim, K.S.;Choi, Y.S.;Park, D.H.
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1719-1721
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    • 2003
  • In this paper, electrical characteristics of inductively coupled plasma in an electrodeless fluorescent lamp were investigated using a Langmuir probe with a variation of Ar gas pressure. The RF output was applied in the range of 5-50W at 13.56MHz. The internal plasma voltage of the chamber and the probe current were measured while varying the supply voltage to the Langmuir probe in the range of -100V ${\sim}$ +100V. When the pressure of Ar gas was increased, electric current was decreased. There was a significant electric current increase when the applied RF power was increased from 10 W to 30 W. This implies that this method can be used to find an optimal RF power for efficient light illumination in an electrodeless fluorescent lamp.

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Microstructural Investigation of CoCrFeMnNi High Entropy Alloy Oxynitride Films Prepared by Sputtering Using an Air Gas

  • Le, Duc Duy;Hong, Soon-Ku;Ngo, Trong Si;Lee, Jeongkuk;Park, Yun Chang;Hong, Sun Ig;Na, Young-Sang
    • Metals and materials international
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    • v.24 no.6
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    • pp.1285-1292
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    • 2018
  • Microstructural properties of as-grown and annealed CoCrFeMnNi high entropy alloy (HEA) oxynitride thin films were investigated. The CoCrFeMnNi HEA oxynitride thin film was grown by magnetron sputtering method using an air gas, and annealed under the argon plus air flow for 5 h at $800^{\circ}C$. The as-grown film was homogeneous and uniform composed of nanometer-sized crystalline regions mixed with amorphous-like phase. The crystalline phase in the as-grown film was face centered cubic structure with the lattice constant of 0.4242 nm. Significant microstructural changes were observed after the annealing process. First, it was fully recrystallized and grain growth happened. Second, Ni-rich region was observed in nanometer-scale range. Third, phase change happened and it was determined to be $Fe_3O_4$ spinel structure with the lattice constant of 0.8326 nm. Hardness and Young's modulus of the as-grown film were 4.1 and 150.5 GPa, while those were 9.4 and 156.4 GPa for the annealed film, respectively.