• 한국안전학회지
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• 제35권5호
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• pp.15-21
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• 2020

Quantitative risk assessment (QRA) is used as a legal or voluntary safety management tool for the hazardous material industry and the utilization of the method is gradually increasing. Therefore, a leak frequency analysis based on reliable generic data is a critical element in the evolution of QRA and safety technologies. The aim of this paper is to derive the leak frequency function that can be applied more flexibly in QRA based on OGP report with high reliability and global utilization. For the purpose, we first reviewed the data on the 16 equipments included in the OGP report and selected the predictors. And then we found good equations to fit the OGP data using non-linear regression analysis. The various expectation functions were applied to search for suitable parameter to serve as a meaningful reference in the future. The results of this analysis show that the best fitting parameter is found in the form of DNV function and connection function in natural logarithm. In conclusion, the average percentage error between the fitted and the original value is very small as 3 %, so the derived prediction function can be applicable in the quantitative frequency analysis. This study is to contribute to expand the applicability of QRA and advance safety engineering as providing the generic equations for practical leak frequency analysis.

• Environmental Engineering Research
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• 제24권3호
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• pp.521-528
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• 2019

Electrochemical method was used for the fracturing flow-back fluid treatment in Guangyuan oilfield. After performing electrolysis, we found that the amount of $H_2$ gas produced by electrode was closely related to the combination mode of electrodes and electrode materials. Using an aluminium electrode resulted in a large $H_2$ production of each electrode combination, whereas inert anode and cathode materials resulted in low $H_2$ production. Then, the relationship between the gas production of $H_2$ and the treatment efficiency of fracturing flow-back fluid in Guangyuan oilfield was studied. Results showed that the turbidity removal and decolourisation rates of fracturing flow-back fluid were high when $H_2$ production was high. If the $H_2$ production of inert electrode was large, the energy consumption of this inert electrode was also high. However, energy consumption when an aluminium anode material was used was lower than that when the inert electrode was used, whereas the corresponding electrode combination production of $H_2$ was larger than that of the inert electrode combination. When the inert electrode was used as anode, the gas production type was mainly $O_2$, and $Cl_2$ was also produced and dissolved in water to form $ClO^-$. $H_2$ production at the cathode was reduced because $ClO^-$ obtained electrons.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 심포지엄 논문집 정보 및 제어부문
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• pp.207-209
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• 2007

In this paper, we introduce a genetic optimization of fuzzy set-fuzzy model using successive tuning method to carry out the model identification of complex and nonlinear systems. To identity we use genetic alrogithrt1 (GA) sand C-Means clustering. GA is used for determination the number of input, the seleced input variables, the number of membership function, and the conclusion inference type. Information Granules (IG) with the aid of C-Means clustering algorithm help determine the initial paramters of fuzzy model such as the initial apexes of the, membership functions in the premise part and the initial values of polyminial functions in the consequence part of the fuzzy rules. The overall design arises as a hybrid structural and parametric optimization. Genetic algorithms and C-Means clustering are used to generate the structurally as well as parametrically optimized fuzzy model. To identify the structure and estimate parameters of the fuzzy model we introduce the successive tuning method with variant generation-based evolution by means of GA. Numerical example is included to evaluate the performance of the proposed model.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2010년도 춘계학술발표대회
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• pp.3.1-3.1
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• 2010

Water splitting reaction using photocatalysts is of great interest in the utilization of solar energy [1]. In the present work, visible light-responsive $TiO_2$ thin films (Vis-$TiO_2$) were prepared by a radio frequency magnetron sputtering (RF-MS) deposition method and applied for the separate evolution of $H_2$ and $O_2$ from water as well as the photofuel cell. Special attentions will be focused on the effect of HF treatment of Vis-$TiO_2$ thin films on their photocatalytic activities. Vis-$TiO_2$ thin films were prepared by an RF-MS method using a calcined $TiO_2$ plate and Ar as the sputtering gas. The Vis-$TiO_2$ thin films were then deposited on the Ti foil substrate with the substrate temperature at 873 K (Vis-$TiO_2$/Ti). Vis-$TiO_2$/Ti thin films were immersed in a 0.045 vol% HF solution at room temperature. The effect of HF treatments on the activity of Vis-$TiO_2$/Ti thin films for the photocatalytic water splitting reaction have been investigated. Vis-$TiO_2$/Ti thin films treated with HF solution (HF-Vis-$TiO_2$/Ti) exhibited remarkable enhancement in the photocatalytic activity for $H_2$ evolution from a methanol aqueous solution as well as in the photoelectrochemical performance under visible light irradiation as compared with the untreated Vis-$TiO_2$/Ti thin films. Moreover, Pt-loaded HF-Vis-$TiO_2$/Ti thin films act as efficient and stable photocatalysts for the separate evolution of $H_2$ and $O_2$ from water under visible light irradiation in the presence of chemical bias. Thus, HF treatment was found to be an effective way to improve the photocatalytic activity of Vis-$TiO_2$/Ti thin films. Furthermore, unique separate type photofuel cell was fabricated using a Vis-$TiO_2$ thin film as an electrode, which can generate electrical power under solar light irradiation by using various kinds of biomass derivatives as fuel. It was found that the introduction of an iodine ($I^-/{I_3}^-$) redox solution at the cathode side enables the development of a highly efficient photofuel cell which can utilize a cost-efficient carbon electrode as an alternative to the Pt cathode.

• 한국진공학회지
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• 제10권4호
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• pp.387-395
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• 2001

증착 조건에 따라 나타나는 폴리머상, 경질, 흑연상의 다이아몬드상 카본(DLC) 박막에서 두께 감소에 따른 탄성률의 변화거동을 구조적인 관점에서 살펴보았다. 실험에 사용된 박막은 r.f.-PACVD 장비를 이용하여 증착하였으며, 반응 가스로는 벤젠과 메탄을 사용하였다. 기판을 식각 과정을 통해 완전히 제거시켜 주기 때문에 다른 방법들과는 달리 기판의 영향 없이 박막만의 탄성률을 정확히 측정할 수 있는 free overhang 방법을 이용하여 DLC 박막의 biaxial elastic modulus를 측정하였다. 또한 Raman 분석을 이용하여 박막의 구조를 조사하였다. 박막이 폴리머상 혹은 흑연상인 경우 두께가 감소함에 따라 탄성률이 감소하는 것을 확인하였고, Ramanm spectrum의 G-peak 위치를 분석한 결과 그 원인은 폴리머상인 경우 증착 초기에 낮은 물성을 가지는 폴리머상의 박막이 형성되기 때문이며, 흑연상인 경우 증착 초기에 낮은 물성을 가지는 흑연상의 박막이 증착되기 때문이다. 반면에 경질의 박막에서는 두께에 상관없이 일정한 탄성률을 가지고 있었으며, 두께에 따른 박막의 구조적인 변화도 관찰되지 않았다.

• 천문학회지
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• 제38권2호
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• pp.121-124
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• 2005

High resolution images of the nuclear regions of nearby galaxies show that nuclear spirals are preponderant in normal galaxies as well as in active galaxies. These nuclear spirals, especially the grand-design nuclear spirals are found to be formed by the gas flow driven by the bar. Hydrodynamical simulations exploring a wide range of parameter space show that the morphology of nuclear spirals depends not only on the inner dynamics but on the global dynamics resulting from the global mass distribution of galaxies. Thus, the nuclear morphology can be a diagnostic tool for the inner dynamics of galaxies when the global mass distribution is taken into account.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.18.2-18.2
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• 2011

We study and analyze here a novel and simple approach to produce copper oxide nanowires in a methanol as an alternative to chemical synthesis routs and VLS-growth method. First, copper oxide nanowires are grown from copper nanoparticles in methanol at $60^{\circ}C$. Nanoparticles are synthesized via inert gas condensation, one of the dry processes. Synthesized nanowires were confirmed via XRD, FESEM and TEM. As a result, all particles have grown to Cu2O nanowires (20~30 nm in diameter, 5~10 um in length; aspect ratio >160~500). Next, these synthesized oxide nanowires are reduced copper nanowires in the furnace under hydrogen flow at $200{\sim}450^{\circ}C$. The evolution of oxide nanowires and their transformation to copper nanowires is studied as a function of time.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.978-979
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• 2006

In this study, bottom-up type powder processing and top-down type SPD (severe plastic deformation) approaches were combined in order to achieve both full density and grain refinement of metallic powders with least grain growth. ECAP (Equal channel angular pressing) was used for the powder consolidation. We investigated the consolidation, plastic deformation and microstructure evolution behavior of the metallic powders during ECAP using an experimental method. It was found that high mechanical strength could be achieved effectively as a result of the well bonded powder contact surface during ECAP process of gas atomized Al-Si powders.

• 한국분말재료학회지
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• 제7권4호
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• pp.218-227
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• 2000

It is well known that the Cu-Cr alloys are very difficult to be made by conventional sintering methods. This difficulty originates both from limited solubility of Cr in the Cu matrix and from limited sintering temperature due to high vapor pressures of Cr and Cu components at the high temperature. Densification of Cu-50%Cr Powder compacts by conventional Powder metallurgy Process has been studied. Three kinds of sintering methods were tested in order to obtain high-density sintered compacts. Completely densified Cu-Cr compacts could be obtained neither by solid state sintering method nor by liquid phase sintering method. Both low degree of shrinkage and evolution of large pores in the Cu matrix during the solid state sintering are attributed to the anchoring effect of large Cr particles, which inhibits homogeneous densification of Cu matrix and induces pore generation in the Cu matrix. In addition, the effect of undiffusible gas coming from the reduction of Cu-oxide and Cr-oxide was observed during liquid phase sintering. A two-step sintering method, solid state sintering followed by liquid phase sintering, was proved to have beneficial effect on the fabrication of high-dendsity Cu-Cr sintered compacts. The sintered compacts have properties similar to those of commercial products.

• Steel and Composite Structures
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• 제28권6호
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• pp.759-766
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• 2018

Friction Stir Welding (FSW) is a solid-state process, where the objects are joined together without reaching their melting point. It has been shown that this method is a suitable way to join dissimilar aluminium alloys. The current article employed hole drilling technique to measure the residual stress distribution experimentally in different zones of dissimilar aluminium alloys AA6061-T6 and AA7075-T6 Butt welded using FSW. Results are compared with those of similar AA6061-T6 plates joined using a conventional fusion welding method called tungsten inert gas (TIG). Also, the evolution of the residual stresses in the thickness direction was investigated, and it was found that the maximum residual stresses are below the yield strength of the material in the shoulder region. It was also revealed that the longitudinal residual stresses in the joint were much larger than the transverse residual stresses. Meanwhile, Vickers micro hardness measurements were performed in the cross-section of the samples. The largest hardness values were observed in the stir zone (SZ) adjacent to the advancing side whereas low hardness values were measured at the HAZ of both alloys and the SZ adjacent to the retreating side.