• Title/Summary/Keyword: gas concentration

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Testing a Commercial Gas Engine using Synthetic Biogas (합성 바이오가스를 이용한 상용 가스엔진 발전기의 구동 특성)

  • Shim, Jae-Hoon;Hong, Seong-Gu;Kwun, Soon-Kuk
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.592-597
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    • 2005
  • Biogas is widely accepted as one of renewable energy. Raw biogas can be used in internal combustion engines either spark ignition or diesel engines. Since the gas has relatively low calorific values, engine power also is lower than rated power values. Modified engines or biogas-specific engines have been utilized in order to increase efficiency. Recently, gas engine/generators are provided for various purposes. They are mostly for LPG or natural gas. When biogas is fueled to the gas engines, de-rating is inevitable due to its lower calorific values. Meanwhile, massively produced commercial gas engines are more competitive in terms of initial investment for engines, compared to biogas-specific engines. Then, the characteristics of the commercial engine and power generation should be understood for better operation. A 5kW gas engine/generator(natural gas) was tested for determining an allowable maximum concentration of $CO_2$ in synthetic biogas, with respect to engine stating, power generation. Experimental results indicated that about 65% of methane concentration is required to start the gas engine. At this condition, the power generated was about 3 kW. It is about 60% of the nominal power, which is similar to the ratio of calorific values.

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Evaluation of 0ff-gas Characteristics in Vitrification Process of ion-Exchange Resin

  • Park, S. C.;Kim, H. S.;K. H. Yang;C. H. Yun;T. W. Hwang;S. W. Shin
    • Nuclear Engineering and Technology
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    • v.33 no.1
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    • pp.83-92
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    • 2001
  • The properties of off-gas generated from vitrification process of ion-exchange resin were characterized. Theoretical composition and flow rate of the off-gas were calculated based on chemical composition of resin and it's burning condition inside CCM. The calculated off-gas flow rate was 67.9Nm$^3$/h at the burning rate of 40kg/h. And the composition of off-gas was avaluated as $CO_2$(41.4%), steam(40.0%), $O_2$(13.3%), NO(3.6%), and SO$_2$(1.6%) in order. Then, actual flow rate and composition of off-gas were measured during pilot-scale demonstration tests and the results were compared with theoretical values. The actual flow rate of off-gas was about 1.6 times higher than theoretical one. The difference between theoretical and actual flow rates was caused by the in-leakage of air to the system, and the in-leakage rate was evaluated as 36.3Nm$^3$/h. Because of continuous change in the combustion parameters inside CCM, during demonstration tests, the concentration of toxic gases showed wide fluctuation. However, the concentration of CO, a barometer of incompleteness of combustion inside CCM, was stabilized soon. The result showed quasi-equilibrium state was achieved two hours after feeding of resin.

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Effects of Regeneration Parameters on Oxidation of Particulate in a Diesel Particulate Trap System (디젤 입자상물질 후처리 장치에서 입자상물질의 연소에 미치는 재생 인자의 영향)

  • Kim, J. U.;Cho, H.;Kim, H. U.;Park, D. S.;You, C.;Kim, E. S.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.2
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    • pp.168-177
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    • 1998
  • The effects of the regeneration parameters such as inlet gas temperature, space velocity, oxygen concentration of the exhaust gas, and initial particulate loading on the oxidation of the particulate inside ceramic cordierite filter have been investigated through an engine experiment. As the inlet gas temperature increases, the remarkable filter temperature occurs owing to the rapid combustion rate. Though the higher space velocity affirms the safe regeneration, it also requires much fuel consumption of the burner. For that reason, the space velocity should be compromised considering the fuel economy. The excessive accumulation of the particulate may cause undesirable regeneration temperatures inside filer even under the optimized regeneration condition. The inlet gas temperature should be selected to overcome the variation of the oxygen concentration which is inherent feature of the diesel engine. It is the most important factor in the regeneration control techniques.

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On Effluent Concentration and Time of Fading Out of Carbon Monoxide and Sulful Dioxide in Atmosphere (대기중(大氣中) 배출(排出)된 일산화탄소(一酸化炭素)와 아황산(亞黃酸)가스의 지속시간(持續時間))

  • Kim, Doo-Hie
    • Journal of Preventive Medicine and Public Health
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    • v.7 no.2
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    • pp.373-375
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    • 1974
  • The concentration of Carton momoxide(CO) and Sulful dioxide($SO_2$) by burning time of coal, and its time of fading out in atmosphere after effluence from stove were measured with Kitagawa gas detector, January, 1974. Gas for measurement was sampled by gas syringe at the point distanced 60cm. from first junction of garvanized pipe of stove. CO concentration was directly proportional to the burning temperature of coal but $SO_2$ was generally constant durning burning time or also in proportion to burning temperature. CO gas of effluent mixed with air(relative humidity, 40%) was maintained for long period relatively, but $SO_2$ gas was early faded out within short time. The period decreasing to allowable limit was about 4 days in former and about 30 minutes in later, respectiively.

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Photodegradation of Volatile Organic Compound (VOC) Through V-Doped or CuOx-grafted $TiO_2$ nanoparticles

  • Kim, Beum Woo;Kim, Seonmin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.271.1-271.1
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    • 2013
  • Titania is usually used in sun-screens, tooth paste, and other daily used objects as a pigment. However, scientists have focused on titania as photocatalyst due to its excellent activities. By fabricating vanadium doped TiO2 and CuOx co-catalyzed TiO2 nano-size filter, the degradation level of the volatile organic compound (VOC) concentration was tested using 365nm UV LED as light source in a closed chamber. Main purpose for this test is to evaluate the activities of various catalysts for degrading the VOCs which are detrimental to human body and toluene and p-xylene were chosen in the VOC removal test. Target gas materials were injected into the test chamber with dry air as carrier gas which was flowed into the gas washer bottle filled with liquid form of VOC substance. When the VOC gas flows into the chamber, it is circulated by 200 mm fan in order to contact with the set-up filter on the aluminum holder. Target gas concentration in the chamber was monitored using VOC detector (miniRae3000, Raesystems) which was also placed inside the chamber. With the measured concentration, the VOC degradation efficiency and the degradation rate were evaluated and used to compare the catalytic activities.

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Analysis of dew point and corrosion resistance for power plant economizer tube with exhaust gas temperature and sulfuric acid concentration (발전소 절탄기 튜브의 배기가스 온도와 황산 농도에 따른 노점 및 내식성 분석)

  • Choi, Jae-Hoon;Lee, Seung-Jun
    • Journal of the Korean institute of surface engineering
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    • v.55 no.6
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    • pp.433-440
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    • 2022
  • Environmental pollution caused by power plant exhaust gas is highlighted and eco-friendly regulations are being strengthened. However, due to the abundant reserves and low prices of coal, still the most used for power generation in the world. Therefore, flexible operation of coal-fired power plants to reduce emissions has become an inevitable option. However, lowering the output increases the possibility of acid dew point corrosion as the exhaust gas temperature decreases. The dew point corrosion occurs when condensable gases such as SO3, HCl, NO2 and H2O cools below the saturation temperature. SO3 is already well known to cause severe low- temperature corrosion in coal-fired power plants. Therefore, this study aims to prevent damage that may occur during operation by analyzing the dew point and corrosion resistance with exhaust gas temperature and sulfuric acid concentration of the power plant economizer tube.

A Space Charge Model for Semiconductor Gas Sensors (반도체 가스감지소자를 위한 공간전하 모델)

  • 이성필;이덕동;손병기
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.11
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    • pp.1631-1636
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    • 1989
  • A space charge model for semiconductor reduced gas sensors has been roposed and applied to gas sensing mechanism. SnO2-x and SnO2-x/Pt thin film were deposited by vacuum evaporating method. And Hall effect and gas sensitivity characteristics of these sensors were measured. From the space charge model and carrier concentration, the number of the adsorbed gas atom on the solid surface was calculated quantitatively. The gas sensing model was compared with CO gas sensitivities of the fabricated thin film gas sensors.

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A Study to Increase Methane Ratio of Landfill Gas by Capturing Carbon Dioxide (매립지가스의 메탄 비율 증가를 위한 이산화탄소 포집 연구)

  • Bada Kim;Junghyun Park;Sungwoon Choi;Youngchul An;Daeyup Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.2
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    • pp.25-31
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    • 2023
  • The purpose of this study is to increase the thermal efficiency of a landfill gas (LFG) power generation engine by capturing carbon dioxide (CO2) from landfill gas (LFG) using monoethanolamine (MEA), which is widely used in the chemical CO2 absorption process. Since the use of LFG as an energy source can be a means of reducing greenhouse gas emissions, MEA can be used to reduce CO2 in LFG and increase the concentration of CH4 to improve the efficiency of power generation. In this study, experiments were conducted to measure the solubility of CO2 and CH4 in MEA solution, increase the solubility under different conditions, and analyse the dissolution characteristics. It was found that the CO2 absorption rate increased as the ratio of MEA to reaction gas increased. There is an optimum MEA concentration to maximise CO2 solubility, and even if the concentration is increased above this concentration, the solubility does not improve significantly. This study provided fundamental work to develop a more practical fuel by capturing CO2 from LFG and increasing the concentration of CH4 while reducing greenhouse gas emissions.

A Study on Concentration of Indoor Nitrogen Dioxide in Relation to House Characteristics (주택특성에 관련된 실내 이산화질소 농도에 관한 연구)

  • 양원호;배현주;김현용;정문식;정문호
    • Journal of environmental and Sanitary engineering
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    • v.14 no.4
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    • pp.85-92
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    • 1999
  • Indoor air quality tends to be the dominant contributor to personal exposure because most people spend over 90% of their time indoors. For some contaminants, exposure to indoor air poses a potentially greater health threat than outdoor air exposures. Indoor nitrogen dioxide ($NO_2$) levels are mainly affected gas range, flue gas spillage, kerosene heaters, wood-burning appliances and cigarette smoke. In addition, indoor $NO_2$ levels are influenced by such house characterization as surface reaction and air exchange rate. In this study, the measurements of indoor and outdoor $NO_2$ concentrations were taken using identical protocols, and information was collected on housing characteristics using identical questionnaires in 14 houses out of 15 houses for daily 30 daily 30 days in Brisbane, Australia.The usage of gas range was the most contributing factor in indoor $NO_2$ concentration in relation to house characteristics. Average indoor and outdoor ratios of NO2 concentration in electronic and gas cooking houses were $0.6{\pm}0.1$ and $0.9{\pm}0.2$, respectively. The frequency distributions of $NO_2$ concentration in each house were approximately log-normal Geometric mean of indoor $NO_2$ concentrations of electronic and gas cooking houses for daily 30 days ranged from 2.5 ppm to 11.5 ppm with a mean 6.8 and from 4.7 ppm to 28.6 ppm with a mean 15.6 ppm, respectively. The $NO_2$ concentrations between electronic and gas cooking houses were significantly different (p<0.05). Since each house has different life-style and house characteristics, sampling interval to measure the $NO_2$ levels was recommended above 7 days.

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Analysis of Operation Parameters of Pilot-Scale Packed-Absorption System for Airborne Methyl Ethyl Ketone Control (공기 중 메틸에틸케톤 제어를 위한 Pilot-Scale 흡수 시스템의 운영인자 분석)

  • Jo, Wan-Kuen;Kim, Wang-Tae
    • Journal of Environmental Science International
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    • v.20 no.4
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    • pp.501-509
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    • 2011
  • Unlike many laboratory-scale studies on absorption of organic compounds (VOCs), limited pilot-scale studies have been reported. Accordingly, the present study was carried out to examine operation parameters for the effective control of a hydrophilic VOC (methyl ethyl ketone, MEK) by applying a circular pilot-scale packed-absorption system (inside diameter 37 cm ${\times}$ height 167 cm). The absorption efficiencies of MEK were investigated for three major operation parameters: input concentration, water flow rate, and ratio of gas flow-rate to washing water amount (water-to-gas ratio). The experimental set-up comprised of the flow control system, generation system, recirculation system, packed-absorption system, and outlet system. For three MEK input concentrations (300, 350, and 750 ppm), absorption efficiencies approached near 95% and then, decreased gradually as the operation time increased, thereby suggesting a non-steady state condition. Under these conditions, higher absorption efficiencies were shown for lower input concentration conditions, which were consistent with those of laboratory-scale studies. However, a steady state condition occurred for two input concentration conditions (100 and 200 ppm), and the difference in absorption efficiencies between these two conditions were insignificant. As supported by an established gas-liquid absorption theory, a higher water flow rate exhibited a greater absorption efficiency. Moreover, as same with the laboratory-scale studies, the absorption efficiencies increased as water-to-gas ratios increased. Meanwhile, regardless of water flow rates or water-to-gas ratios, as the operation time of the absorption became longer, the pH of water increased, but the elevation extent was not substantial (maximum pH difference, 1.1).