• 콘크리트학회논문집
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• 제11권3호
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• pp.123-130
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• 1999

In a preceding study(1), the using method of garnet powder has been studies through the various investigation of basic material properties on garnet powder, industrial by-products generated in Yungju, Kyungpook. In this study, the various properties of concrete mixed with garnet powder are examined as following condition : Unit weight of water (170kg/㎥), water-binder ratio W/B (53, 55 and 58%), sand-aggregate ratio (S/A) (43, 45 and 48%), substitutional ratio of garnet powder of 0, 5, 10, 15 and 20%. Slump increased a little as the substitutional ratio of garnet increased. Air content decreased a little at the substitutional ratio of 10%. or more. Though there is a little difference in compressive strength according to the W/B and the substitutional ratio, compressive strength of concrete using garnet exceeded that of plain concrete a little in the range of the substitutional ration of 5 to 15%. Also, There is a similar tendency in the tensile and flexural strength. Therefore, the use of garnet powder with industrial by-products is expected to improve the workability and the strength of concrete.

• 자원리싸이클링
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• 제11권2호
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• pp.36-44
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• 2002

폐기처분되는 gamet 미분말의 재활용 측면에서 이를 적벽돌의 원료로 활용하는 방안에 관한 연구를 수행하였다. 적벽돌의 물리적 강도에 있어서 점토가 높은 $SiO_2$, $Al_2$$O_3$및 $Fe_2$$O_3$함량과 점성을 가지는 것은 매우 중요한 성질이다. 그러나 폐garnet 미분말의 경우 이들의 함량은 높지만 점성이 매우 작으므로, 점토를 대체할 수 없을 것으로 판단하여 모래의 대체제로 적용하고자 하였다. 점토의 화학성분 중 강도를 나타내는 함량이 폐garnet 미분말에서도 상당히 높은 것으로 파악되었으며, 이는 적벽돌의 강도에 긍정적인 영향을 주는 것으로 파악되었다. 적벽돌 제조시의 원료 배합은 {점토-모래}, {모래-폐gamet 미분말}, 그리고 {점토-모래-폐gamet 미분말} 조합을 무게 비율로 각각 조절하였으며, 적벽돌 공시체의 물리적 특성 실험은 압축강도.흡수율.수축율.비중에 대하여 실시하였다. 그 결과 최적의 원료 배합 조건은 무게를 기준으로 할 때 {점토50%+모래 30%+폐 gamet 미분말 20%}인 것으로 파악되었다. 본 연구의 결과 폐gamet 미분말을 재활용하여 제작한 적벽돌의 상업적 생산이 가능하며, 유효자원의 재이용 측면에서도 경제성을 가질 것으로 판단되었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.676-679
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• 2004

In this study, we considered the characteristic of drying shrinkage from age of high strength concrete with garnet minute powder to be industry by-product. The factors of experiment are unit water content$(160kg/m^3)$, water-binder ratio(30, $35\%$), fine aggregate ratio(40, 42, $44\%$), admixture replacement ratio(0, 10, $20\%$), admixture type(garnet minute powder, fly ash, blast-furnace slag). We make a comparative study of shrinkage about concrete with a passage of age(1, 3, 7, 14, 28, 56, 91 days). As a result of experiment, we reach a conclusion as follow. In the same mix condition, as unit water content and fine aggregate ratio go up, the drying shrinkage ratio increase. In the drying shrinkage ratio according to admixture replacement ratio, it goes up when admixture replacement Ratio increase in case of fly ash and blast-furnace slag. But, drying shrinkage ratio decrease when admixture replacement ratio increase in case of garnet minute powder.

• 한국세라믹학회지
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• 제33권6호
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• pp.693-699
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• 1996

YIG precursor powder was obtained by homogeneous precipitation in chloride salt solution by thermal decom-position of urea. It was found that ferric ions precipitated prior to yttrium ions. The precipitate was minute and spherical in shape. The precipitate formed consisted of the mixture of amorphous and ferric oxyhydroxide. Crystallization of YIG was proceeded by solid state reaction of intermediate YFeO3 and Fe2O3 in the temperature range of 85$0^{\circ}C$ to 140$0^{\circ}C$. Single phase of YIG was obtained by heat-treatment of the powder at 140$0^{\circ}C$ for 6 hrs in air. The powder calcined was molded into pellets and sintered in air. The maximum density of 4,92 g/cm3(95.1% of theoretical density) was obtainable for the pellet sintered at 145$0^{\circ}C$ using the powder calcined at 90$0^{\circ}C$.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 가을 학술발표회논문집(I)
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• pp.439-444
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• 2000

The purpose of this study is to investigate the possibility of Garnet powder as admixture of high strength concrete. The experiment condition is unit water content 160kg/㎥, W/B=30, 35%, S/A=40, 42, 44% and the cement was replaced with Garnet powder to 0, 10% of cement weight on making specimens. The mechanical properties of the fresh and hardened concrete were given as follows. As the time elapsed, the slump loss of 10% replaced concrete was considerably lower than that of 0% replaced concrete. In compressive strength, the 10% replacement case was nearly the same or somewhat high.

• The Korean Journal of Ceramics
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• 제1권1호
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• pp.35-39
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• 1995

Yttrium aluminum garnet(YAG) powders were synthesized by spray-drying of the hydroxides coprecipitated from a mixture of aqueous solutions of $Al(NO_3)_3.9H_2O \;and\; Y(NO_3)_3.6H_2O$ Phase formation in the powders during heat treatments and their sintering charactristics were investigated. In the powder obtained by washing the hydroxides before spray-drying, a metastable yttrium aluminum hexagonal (YAH) phase was first crystallized and then transformed into YAG as temperature was increased. The formation of YAH was attributed to a deviation in compositions of the particles from the starting composition of YAG. However, the powder prepared without washing step contained a stable yttrium aluminum monoclinic(YAM) phase in addition to YAG due to a large deviation from the starting composition. A powder compact of a single phase YAG was pressureless-sintered for 4 hrs at $1700^{\circ}C$ and the density was 93% of the theoretical density.

• 한국세라믹학회지
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• 제54권4호
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• pp.278-284
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• 2017

In this work, Ta-substituted $Li_7La_3Zr_{2-x}O_{12}$ (LLZTO) powder and pellets with garnet cubic structure were fabricated and characterized by modified and optimized sol-gel synthesis. Ta-substituted LLZO powder with the smallest grain size and pure cubic structure with little pyrochlore phase was obtained by synthesis method in which Li and La sources in propanol solvent were mixed together with Zr and Ta sources in 2-methoxy ethanol. The LLZTO pellets made with the prepared powder showed cubic garnet structure for all conditions when the amount of Li addition was varied from 6.2 to 7.4 mol. All the X-ray peaks of the pyrochlore phase disappeared when the Li addition was increased above 7.0 mol. When the final sintering temperature was varied, the LLZTO pellet had a pyrochlore-mixed cubic phase above $1000^{\circ}C$. However, the surface morphology became much denser when the final sintering temperature was increased. The sol-gel-driven LLZTO pellet with a sintering temperature of $1100^{\circ}C$ showed a lithium ionic conductivity of 0.21 mS/cm when Au was adopted as electrode material for the blocking capacitor. The results of this study suggest that modified sol-gel synthesis is the optimum method to obtain cubic phase of LLZTO powder for highly dense and conductive solid electrolyte ceramics.

• 한국재료학회지
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• 제21권2호
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• pp.106-110
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• 2011

A high thermal conductive AlN composite coating is attractive in thermal management applications. In this study, AlN-YAG composite coatings were manufactured by atmospheric plasma spraying from two different powders: spray-dried and plasma-treated. The mixture of both AlN and YAG was first mechanically alloyed and then spray-dried to obtain an agglomerated powder. The spray-dried powder was primarily spherical in shape and composed of an agglomerate of primary particles. The decomposition of AlN was pronounced at elevated temperatures due to the porous nature of the spray-dried powder, and was completely eliminated in nitrogen environment. A highly spherical, dense AlN-YAG composite powder was synthesized by plasma alloying and spheroidization (PAS) in an inert gas environment. The AlN-YAG coatings consisted of irregular-shaped, crystalline AlN particles embedded in amorphous YAG phase, indicating solid deposition of AlN and liquid deposition of YAG. The PAS-processed powder produced a lower-porosity and higher-hardness AlN-YAG coating due to a greater degree of melting in the plasma jet, compared to that of the spray-dried powder. The amorphization of the YAG matrix was evidence of melting degree of feedstock powder in flight because a fully molten YAG droplet formed an amorphous phase during splat quenching.

• Journal of Magnetics
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• 제10권3호
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• pp.80-83
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• 2005

Cobalt ferrite and garnet powders were grown using a conventional ceramic method in two different ways for understanding the magnetic interaction between structurally different materials. Structures of these powders were investigated by using an X-ray diffractometer (XRD) and the magnetic interaction between iron ions and the magnetic properties of the powders were measured by a $M\ddot{o}ssbauer$ spectroscopy and a vibrating sample magnetometer (VSM), respectively. The result of the XRD measurement showed that the annealing temperature higher than $1200^{\circ}C$ was necessary to grow a $(CoFe_2O_4)_{0.5}(Y_3Fe_5O_{12})_{0.5}$ powder. $M\ddot{o}ssbauer$ spectra for the powders grown separately and mixed mechanically consisted of sub-spectra of cobalt ferrite and garnet, however, powders annealed together had an extra sub-spectrum, which was related with the magnetic interaction between the grain surface of cobalt ferrite and the one of the garnet. In case of annealing the powders at the temperature large enough to crystallize them, raw chemicals became fine cobalt ferrite and garnet particles at first and then these fine particles were aggregated and formed large grains of ferrite powders. The result of the VSM measurement showed that the powders prepared at $1200^{\circ}C$ had the similar saturation magnetization and the coercivity regardless of the preparation method.

• Journal of the Korean Physical Society
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• 제73권10호
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• pp.1535-1540
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• 2018

In this study, we prepared and characterized Nb-doped $Li_7La_3Zr_{2-x}O_{12}$ (LLZNO) powder and pellets with a cubic garnet structure by using a modified sol-gel synthesis and hot pressing. LLZNO powder with a very small grain size and cubic structure without secondary phases could be obtained by using a synthesis method in which Li and La sources in a propanol solvent were mixed together with Zr and Nb sources in 2-methoxy ethanol. A pure cubic phase LLZNO pellet could be fabricated from the prepared LLZNO and an additional 6-wt% of $Li_2CO_3$ powder by hot pressing at $1050^{\circ}C$ and 15.8 MPa. The hot-pressed LLZNO pellet with a relative density of 99% exhibited a very dense surface morphology. The total Li ionic conductivity of the hot-pressed LLZNO was $7.4{\times}10^{-4}S/cm$ at room temperature, which is very high level compared to other reported values. The activation energy for ionic conduction was estimated to be 0.40 eV.